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The Electronic Spectrum of (-)-S-(pS)-2,5,3',6'-Tetrahydro-2.2-Paracyclophane-2-Carboxylic Acid

Description: A new, efficient route was used in the synthesis of [2.2]-paracyclophane-2-carboxylic acid. The acid as then resolved and the Birch reduction performed yielding one enantiomer of tetrahydro-[2.2]-paracyclophane-2-carboxylic acid. The ultraviolet spectrum of tetrahydro-[2.2]-paracyclophane- 2-carboxylic acid in isopenthane shows one absorption at 206 nm (Emax = 5,271). There are three bands observed in the circular dichroism spectrum in isopentane at 236 nm ([] = 1.8 X 104), 201 nm ([0] = -16 X 104) and a positive band indicated below 180 nm but not observed. The bands were assigned and possible reasons for the occurrence of a mr'r* transition at unexpectedly long wavelengths are discussed.
Date: May 1980
Creator: Hall, Lindsey

Electrostatic Effects in III-V Semiconductor Based Metal-optical Nanostructures

Description: The modification of the band edge or emission energy of semiconductor quantum well light emitters due to image charge induced phenomenon is an emerging field of study. This effect observed in quantum well light emitters is critical for all metal-optics based light emitters including plasmonics, or nanometallic electrode based light emitters. This dissertation presents, for the first time, a systematic study of the image charge effect on semiconductor–metal systems. the necessity of introducing the image charge interactions is demonstrated by experiments and mathematical methods for semiconductor-metal image charge interactions are introduced and developed.
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Date: May 2012
Creator: Gryczynski, Karol Grzegorz

Electrostatic Mechanism of Emission Enhancement in Hybrid Metal-semiconductor Light-emitting Heterostructures

Description: III-V nitrides have been put to use in a variety of applications including laser diodes for modern DVD devices and for solid-state white lighting. Plasmonics has come to the foreground over the past decade as a means for increasing the internal quantum efficiency (IQE) of devices through resonant interaction with surface plasmons which exist at metal/dielectric interfaces. Increases in emission intensity of an order of magnitude have been previously reported using silver thin-films on InGaN/GaN MQWs. the dependence on resonant interaction between the plasmons and the light emitter limits the applications of plasmonics for light emission. This dissertation presents a new non-resonant mechanism based on electrostatic interaction of carriers with induced image charges in a nearby metallic nanoparticle. Enhancement similar in strength to that of plasmonics is observed, without the restrictions imposed upon resonant interactions. in this work we demonstrate several key features of this new interaction, including intensity-dependent saturation, increase in the radiative recombination lifetime, and strongly inhomogeneous light emission. We also present a model for the interaction based on the aforementioned image charge interactions. Also discussed are results of work done in the course of this research resulting in the development of a novel technique for strain measurement in light-emitting structures. This technique makes use of a spectral fitting model to extract information about electron-phonon interactions in the sample which can then be related to strain using theoretical modeling.
Date: May 2012
Creator: Llopis, Antonio

Elementary Math Achievement in Texas: What is Working?

Description: Elementary math teachers (76) from selected Texas schools that included Grade 5 responded to an online self-report survey with respect to school-level factors that may be associated with student math achievement. Questions on the survey focused on school-level factors related to math, campus leadership, integration of technology in the math classroom, teacher expectations, utilization of student data in decision-making and professional development. The schools included in the study were rated as Acceptable or Exemplary schools by the Texas Education Agency for three-consecutive years (2007-2010). Logistic regression techniques were used to analyze the data and 11 questions out of 45 were analyzed to determine the odds ratio. Factors that were correlated with being an Exemplary campus were teacher certification routes, not benchmarking student progress, implementation of response to intervention (RTI), classroom management focus (equally divided between student and teacher centered) within the classroom, and technology integration. The results indicated that at the .05 level of probability, the only factor that met that level of significance was full implementation of RTI.
Date: May 2011
Creator: Moore, Linda H.

Elementary music teachers instructing English language learners: Reflection on practice.

Description: This qualitative study investigated four monolingual, English-only speaking Caucasian elementary music teachers and their reflections regarding instruction of English language learners (ELL). The purpose of this multiple case study was to investigate the teaching practice and curricular decisions of elementary music teachers who instruct Hispanic ELL students. The investigation was conducted during a nine-week period, and data collection included classroom observations, phenomenological interviewing, and teacher audio journals. None of the teachers had prior education or pre-service preparation in teaching music to ELL students. The major theoretical base from which the study was developed was the reflective teaching theory of Donald Schön (1983). The main research question was: "What are the participating teachers' reflections about their curricular and pedagogical decisions when teaching ELL students?" Following a description of the elementary music teachers' reflections on practice with ELL students, the study revealed that the majority of elementary music teachers had a lack of preparation and ELL music curriculum, and negative perceptions of the placement program for ESL students. Despite these factors, the teachers made attempts to include ELL students in all music activities. This study showed that while one teacher accommodated specifically for the ELL students' learning, three out of four teachers did not. This study also suggests that music is a subject by which strong interactions between peers, opportunity for language expansion, and other factors occur which have positive correspondence to recommended ELL instructional strategies. A cross-case analysis revealed that the life history and experience of the elementary music teachers had an influence on the teachers' awareness of ELL students. The analysis suggests a relationship between teacher awareness and accommodation. The study also recognized the need for further inquiry regarding ELL students and issues related to their school placement. This study has implications for music education research including suggestions for music ...
Date: December 2005
Creator: Scherler, Kathy L.

Elementary Pre-service Teachers’ Perceptions and Experiences of Mathematics Intervention and Response to Intervention Practices

Description: Response to intervention has become a widely implemented early intervention and pre-referral program in many schools due to the reauthorization of the 2004 Individuals with Disabilities Education Act. Limited studies exist that validate how teacher preparation programs are preparing the next generation of teachers to assess students, apply early academic interventions, monitor progress, and make educational decisions for students with learning difficulties as part of an RTI program. The purpose of this study was to examine elementary pre-service teachers’ perceptions and experiences in a mathematics intervention project (MIP), as part of a university mathematics methods course as related to RTI practices. Data were collected from multiple sources, including: Seidman’s three-step interview series with pre-service participants and course instructors, document analysis of the Mathematics Interactions Project (MIP) students’ responses, mathematics methods course syllabi, and observations of the mathematics methods course instruction. Haskell’s transfer theory was used as the framework from which to analyze the data. It was assumed that if a majority of the 11 principles of meaningful transfer were addressed, higher levels of transfer from university instruction to intervention instruction would be observed during the MIP. Findings indicate differences in RTI understanding according to elementary education degree plan. Candidates in the English as a Second Language (ESL) program did not demonstrate a strong foundational understanding of RTI, evidenced by a lower level of transfer about RTI. Alternately, pre-service teachers in the special education degree plan had a stronger foundational knowledge of RTI, discussed how RTI learning was supported, and had more experiences to implement RTI (principles 1, 7, and 9). Pre-service teachers in the Special Education (SPED) certification degree plan demonstrated a higher level of transfer since more of the principles were met; this was foundational in Haskell’s transfer theory. Implications are that elementary education programs, and particularly projects such ...
Date: August 2015
Creator: Hurlbut, Amanda Renee

Elementary School Climate Factors and Personality and Status Variables Associated with School Library Media Specialists Chosen by Classroom Teachers for Cooperation on Instructional Problems

Description: This study investigated relationships between the extent to which elementary classroom teachers tend to choose school library media specialists for cooperation on instructional problems and several school climate and faculty related characteristics including the general academic effectiveness of the school, the overall cohesion and cooperativeness of the teaching faculty on instructional matters, and the propensity of the group and individual faculty to seek cooperation to solve instructional problems. The instructional choice status of the school library media specialist was also studied in relation to various individual personality factors, as measured by Cattell's 16 Personality Factor Questionnaire, as well as school media specialist status variables including degreed or non-degreed status, total years of experience as a school library media specialist, years of experience on campus as a school library media specialist, and total number of years of experience in the field of education. The instructional status of the school library media specialist was also examined in relationship to the size of the school served. The study included 1,079 elementary classroom teachers and thirty-nine school library media specialists from thirty-nine Texas elementary schools similar in important wealth, size, and student demographic characteristics. Twenty of the schools ranked in the bottom 25% of all schools in the state as to how well their students performed on the 1988 Texas Educational Assessment of Minimum Skills (TEAMS) test. Nineteen schools ranked among the top 25%of all schools in the state in academic effectiveness. As compared to the low academic schools, the high academic schools were found to be significantly more instructionally cohesive, and classroom teachers in those schools were significantly more disposed to choose the school library media specialist to cooperate with them on instructional problems. No significant relationships were discovered between the instructional choice status of the school media specialist and his or her ...
Date: December 1990
Creator: Bell, Michael David, 1943-

Elementary Students' Critical Examination of Characters in Children's Literature Depicting Social Justice

Description: Despite the ruling of Brown vs. The Board of Education of Topeka, segregation in schools is still quite visible with suburban schools educating a student body of more than 70% White and urban schools comprised of mostly Black, Hispanic, and Asian students. Ideally, a school should dispel social and structural inequities through curriculum and quality resources, but fallibly, schools continue to be the vehicles to maintaining the status quo. Students who develop critical awareness and cultivate a critical literacy stance can become agents of change toward a more democratic society. In the current study, urban upper-elementary-age students were asked to engage in a critical literacy event by critically examining the power positions of characters in books that depict historical social injustice. The six female participants met in several sessions to read books and a newspaper article, use a critical reader response tool, and then engage in critical conversations about the books' characters. Their dialogue was recorded and analyzed using a critical discourse qualitative methodology. The findings show that older elementary students are capable of seeing multiple perspectives of an issue and can explain characters' power from born from privilege and fueled by fear and how a shift in power may occur through solidarity. The findings suggest school curriculum enhanced by media narrows the students' view of discrimination as being targeted mostly towards African-Americans, but those experiences through literature have the potential to expand the students' views to include other cultural groups. Subsequently, there is a need for broader teacher preparation using books that enhance students' views of social injustice.
Date: August 2016
Creator: Paiva, Deanne

Elementary Teacher Attrition and Factors of Organizational Climate

Description: As the United States faces a critical teacher shortage, it is important to examine all factors that may contribute to the revolving door of teacher attrition. This study explored the climate of elementary schools to determine if there was a correlation between teacher attrition and school organizational climate. Three basic research questions were addressed: 1) Is there a relationship between school organizational climate and teacher attrition? 2) Is a change in campus leadership related to school organizational climate? 3) Is there a relationship between a change in campus leadership and teacher attrition? Thirty-seven elementary schools were examined in terms of their individual teacher attrition rates and their climate survey scores. The data utilized in this study came from one school district's climate survey and teacher attrition rates for the 2000-2001 school year. The findings of this study indicate that factors of organizational climate may predict teacher attrition rates. Specifically, instructiona support may be related to teacher attrition. Major components of instructional support include principal behaviors, respect for teaching and learning, and communication with administrators. Teacher attrition was not related to principal experience. Also, principal experience was not related to factors of school organizational climate.
Access: This item is restricted to the UNT Community Members at a UNT Libraries Location.
Date: May 2003
Creator: Cotten, Virginia E.

Elements of a Succession Plan

Description: Poster presented at the 2011 ALA Learning Roundtable Conference. This poster presents information about succession plans. It covers succession plan strategies, competencies for key positions, candidates' skills, and development plans.
Date: 2011
Creator: Brannon, Sian

The Elements of Jazz Harmony and Analysis

Description: This study develops a method for analyzing jazz piano music, primarily focusing on the era 1935-1950. The method is based on axiomatic concepts of jazz harmony, such as the circle of fifths and root position harmonies. 7-10 motion between root and chordal seventh seems to be the driving force in jazz motion. The concept of tritone substitution leads to the idea of a harmonic level, i.e., a harmony's distance from the tonic. With this method in hand, various works of music are analyzed, illustrating that all harmonic motion can be labelled into one of three categories. The ultimate goal of this analytic method is to illustrate the fundamental harmonic line which serves as the harmonic framework from which the jazz composer builds.
Date: August 1986
Creator: Mahoney, J. Jeffrey

The Elements of Lesson Design, Elementary Public School Students' Mastery of Mathematics Objectives, Accrued Teaching Experience, and Teacher Inservice Training

Description: The purpose of this study was to investigate the relationship among the teachers' use of the individual elements of lesson design, students' mastery of mathematics objectives, the hours of inservice training completed by the teachers and the teachers' years of experience. The individual elements of lesson design are defined by Madeline Hunter and are anticipatory set, objective and purpose, input, modeling, checking for understanding, guided practice, and independent practice.
Date: May 1987
Creator: Smith, James A. (James Arthur) 1945-

Elements of Shamanic Mythology in E. T. A. Hoffman's Romantic Conception of Music

Description: The musicians in E. T. A. Hoffmann's tales and essays demonstrate traits remarkably similar to those of shamans. Hoffmann uses the same imagery to describe the journey of the composer into the "realm of dreams," where he receives inspiration, as the shaman uses to describe the spirit world to which he journeys via music. Hoffmann was a major force in changing the 18th-century view of music as an "innocent luxury" to the 19th-century idea of music as a higher art. As a German Romantic,author, he subscribed to the idea championed by the Schlegels that true poetry is based on myth. In this thesis, Hoffmann's writings are compared with shamanic mythology to demonstrate a similarity beyond mere coincidence, without drawing conclusions about influence.
Date: December 1993
Creator: Miller, Harry A. W. (Harry Alfred Werner)

Elements of Verismo in Selected Operas of Giuseppe Verdi

Description: In music, the term verismo usually refers to a realistic or naturalistic movement in Italian operas of the late nineteenth century. From the dawn of Italian opera four features have been manifested--umanita (humanism), sincerity (sincerity), passione (passion), effetto (not only theatrical effect but the supreme dramatic moment). The elements of verismo are among the characteristics present in the operas of Giuseppe Verdi where they reached a zenith of development. It is upon these veristic aspects, as identified in the second chapter, that the operas Cavalleria Rusticana and Pagliacci were based. Rigoletto, Il Trovatore, and La Traviata richly exhibit these elements of verismo which have been identified in the fourth chapter.
Date: August 1968
Creator: Morgan, Ann Shands

Eliasch Report: Carbon absorption and storage

Description: This report provides details about carbon sequestration in the wood and soils of different types of forest (tropical, boreal, temperate) and states the policy implications that apply to the energy and forestry sectors. The report includes recommendations for the relationship between carbon sequestration and sustainable forestry.
Date: unknown
Creator: Franco, Miguel