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Substitution chemistry of the cobalt complexes RCCo3(CO)9 (R = H, CHO) with the diphosphine ligand: 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses, X-ray structures and reactivity.

Description: The reaction between the tetrahedrane cluster RCCo3(CO)9{R = CHO (1), H (3)} and the redox-active diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3- dione (bpcd) leads to the replacement of two CO groups and formation of RCCo3(CO)7(bpcd) {R = CHO (2), H (4)}. Clusters 2 and 4 are thermally unstable and readily transform into the new P-C bond cleavage cluster 5. All three clusters 2, 4, and 5 have been isolated and fully characterized in solution by IR and 31P NMR spectroscopy. VT 31P NMR data indicate that the bpcd ligand in RCCo3(CO)7(bpcd) is fluxional at 187 K in THF. Clusters 2, 4, and 5 have been structurally characterized by X-ray diffraction analyses.
Date: December 2001
Creator: Liu, Jie

The Relationship Between Body Dissatisfaction and Eating Disorder Symptomatology: An Examination of Moderating Variables

Description: The purpose of this study was to examine whether Psychological Well-Being (comprised of self-esteem, optimism, satisfaction with life, and self-determination), perfectionism, body surveillance, and neuroticism moderated the relationship between body dissatisfaction and bulimic symptoms after controlling for social desirability and actual physical size. 847 female undergraduate students participated in the study. Participants completed an online questionnaire packet. An exploratory factor analysis determined that self-determination, optimism, self-esteem, and satisfaction with life loaded on to one factor representing Psychological Well-Being. Hierarchical moderated regression (HMR) was used to control for the influences of social desirability and body mass index on bulimic symptoms and then determine the main and interactive effects of body dissatisfaction and each moderator. Four variables (neuroticism, body surveillance, concern over mistakes, and doubts about actions) strengthened the relationship between body dissatisfaction and bulimic symptomatology, whereas Psychological Well-Being weakened the relationship. Parental expectations, parental criticism, and personal standards did not moderate the relationship between body dissatisfaction and bulimic symptomatology.
Date: August 2010
Creator: Brannan, Megan E.

The Keyboard Music of Peter Philips

Description: The keyboard works of the English virginalist Peter Philips have been little studied in comparison with his more famous contemporaries, William Byrd, John Bull and Jan Pieterszoon Sweelinck. While Philips left comparatively fewer keyboard works than these composers, his music contains very unique attributes. This study compiles the latest research of Philips' life as well as an analysis of representative works showing many of the individual and uncommon features to be found in Philips' works for keyboard. Pieces from all genres of Philips' keyboard output are represented and discussed, including Pavanes and Galliards, Fantasias and Intabulations of madrigals. Musical examples of each of these works are provided. A description of the instruments needed for the performance of the music and an illustration of the rare type of keyboard instrument required in the Pavana and Galliarda Dolorosa is included. A discussion of Philips' style, particularly regarding ornamentation, is included with a comparison to the works of his contemporaries.
Date: August 2010
Creator: Bennight, Bradley J.

Soldier Boys of Texas: The Seventh Texas Infantry in World War I

Description: This study first offers a political, social, and economic overview of Texas during the first two decades of the twentieth century, including reaction in the Lone Star state to the declaration of war against Germany in April, 1917; the fear of saboteurs and foreign-born citizens; and the debate on raising a wartime army through a draft or by volunteerism. Then, focusing in-depth on northwest Texas, the study examines the Texas National Guard unit recruited there, the Seventh Texas Infantry Regiment. Using primarily the selective service registration cards of a sample of 1,096 members of the regiment, this study presents a portrait of the officers and enlisted soldiers of the Seventh Texas based on age, occupation, marital status, dependents and other criteria, something that has not been done in studies of World War I soldiers. Next, the regiment's training at Camp Bowie, near Fort Worth, Texas, is described, including the combining of the Seventh Texas with the First Oklahoma Infantry to form the 142nd Infantry Regiment of the Thirty-Sixth Division. After traveling to France and undergoing nearly two months of training, the regiment was assigned to the French Fourth Army in the Champagne region and went into combat for the first time. The study examines the combat experiences of these soldiers from northwest Texas and how they described and expressed their experiences to their families and friends after the armistice of November 11, 1918. The study concludes with an examination of how the local communities of northwest Texas celebrated the armistice, and how they welcomed home their "soldier boys" in the summer of 1919. This study also charts the changing nature of the Armistice Day celebrations and veteran reunions in Texas as time passed, as well as the later lives of some of the officers and men who served with the ...
Date: August 2010
Creator: Ball, Gregory W.

An examination of computer anxiety related to achievement on paper-and-pencil and computer-based aircraft maintenance knowledge testing of United States Air Force technical training students.

Description: The purpose of this study was to determine whether varying levels of computer anxiety have an effect on computer-based testing of United States Air Force technical training students. The first chapter presents an overview of computer-based testing, defines key terms, and identifies questions addressed in the research. The rationale for conducting this study was that little research had been done in this area. The second chapter contains a review of the pertinent literature related to computer-based testing, computer anxiety, test reliability, validity, and gender differences in computer use. Due to the lack understanding concerning any effects of computer anxiety on computer-based testing, this has been a worthwhile topic to explore, and it makes a significant contribution to the training field. The third chapter describes the qualitative research methodology used to conduct the study. The primary methodology was an analysis of variance comparison for groups of individuals who displayed high or low computer anxiety to their respective mean computer-based or paper-based aircraft maintenance knowledge testing scores. The research population consisted of United States Air Force aircraft maintenance craftsmen students attending training at Sheppard Air Force Base, Texas. The fourth chapter details the findings of the study. The findings indicate that there was no significant difference between the groups of students rated with high computer anxiety and low computer anxiety while testing with computers. Additionally, no significant differences were detected while testing alternative hypotheses covering differences between groups of students rated with high computer anxiety and low computer anxiety testing by traditional paper-and pencil methods. Finally, a reference section identifying the literature used in the preparation of this dissertation is also included.
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Date: May 2002
Creator: McVay, Richard B.

The Green Horizon: An (Environmental) Hermeneutics of Identification with Nature through Literature

Description: This thesis is an examination of transformative effects of literature on environmental identity. The work begins by examining and expanding the Deep Ecology concept of identification-with-nature. The potential problems with identification through direct encounters are used to argue for the relevance of the possibility of identification-through-literature. Identification-through-literature is then argued for using the hermeneutic and narrative theories of Hans-Georg Gadamer and Paul Ricoeur, as well as various examples of nature writing and fiction.
Date: August 2010
Creator: Bell, Nathan M.

A Spatially Explicit Environmental Health Surveillance Framework for Tick-Borne Diseases

Description: In this paper, I will show how applying a spatially explicit context to an existing environmental health surveillance framework is vital for more complete surveillance of disease, and for disease prevention and intervention strategies. As a case study to test the viability of a spatial approach to this existing framework, the risk of human exposure to Lyme disease will be estimated. This spatially explicit framework divides the surveillance process into three components: hazard surveillance, exposure surveillance, and outcome surveillance. The components will be used both collectively and individually, to assess exposure risk to infected ticks. By utilizing all surveillance components, I will identify different areas of risk which would not have been identified otherwise. Hazard surveillance uses maximum entropy modeling and geographically weighted regression analysis to create spatial models that predict the geographic distribution of ticks in Texas. Exposure surveillance uses GIS methods to estimate the risk of human exposures to infected ticks, resulting in a map that predicts the likelihood of human-tick interactions across Texas, using LandScan 2008TM population data. Lastly, outcome surveillance uses kernel density estimation-based methods to describe and analyze the spatial patterns of tick-borne diseases, which results in a continuous map that reflects disease rates based on population location. Data for this study was obtained from the Texas Department of Health Services and the University of North Texas Health Science Center. The data includes disease data on Lyme disease from 2004-2008, and the tick distribution estimates are based on field collections across Texas from 2004-2008.
Date: August 2010
Creator: Aviña, Aldo

Family Sex Talk: Analyzing the Influence of Family Communication Patterns on Parent and Late Adolescent's Sex Conversations

Description: Family communication has the potential to affect a variety of youth behavioral outcomes including adolescent sexual risk behavior. Within chapter 1, I present past literature on adolescent sexual risk behaviors, family communication patterns, and the gaps associated with those areas. In chapter 2, I review previous literature on adolescent sexual risk behavior, parent-child communication and family communication patterns. In chapter 3, I present the method which includes a description of the participants, procedures, measures, and data analysis used. In Chapter 4, I present the results of the study. According to the results of the study, father-child communication is not a better predictor of adolescent sexual risk behavior. A higher quantity of parent-child communication does not lead to less adolescent sexual risk behavior. Participants with a pluralistic family type do significantly differ from laissez-faire and protective family types in regards to levels of parent-child communication. Participants with a consensual family type do have significantly higher levels of parent-child communication in comparison to laissez-faire family types, but not protective family types. Finally, in chapter 5, I present the discussion with a review of previous research (consistent or inconsistent with the current findings), limitations and conclusions for the current study.
Date: August 2010
Creator: Allen, Evette L.

An Analysis of Performance Differences Between Self-Directed and Teacher-Directed Alternative Education Campuses in Texas

Description: This study was conducted to analyze the performance differences between alternative education campuses in Texas that used teacher-directed strategies and those that used self-directed strategies. The study was also conducted to inform educators of the results these two strategies had achieved with at-risk students during the three years of 2006-2008. The study used the results from the Texas Assessment of Knowledge and Skills test as reported in the AEIS annual reports from the Texas Education Agency. Alternative education schools were grouped according to the strategy used to educate at-risk students. The results of the statistical tests showed the two strategies had similar performance results and there was no statistical difference between the two. The results offered several implications concerning the ability of at-risk students to achieve in alternative education schools including possible reasons why students who were previously unsuccessful became successful in alternative settings. The report also addressed the number of students who continued to be unsuccessful even when placed on an alternative education campus. Possible reasons for this continued inability to succeed are discussed. Recommendations for further research were listed at the conclusion of the study.
Date: May 2010
Creator: Wimberley, Alan

Molecular systematics of Baird's pocket gopher (Geomys breviceps)

Description: Baird's pocket gopher (Geomys breviceps) is found in eastern Texas, eastern Oklahoma, central and western Arkansas, and western Louisiana. The cytochrome-b gene was sequenced and analyzed for 16 pocket gophers from throughout the range of the species. Similar phylogenetic trees were obtained using maximum-parsimony, maximum-likelihood, neighbor-joining, and Bayesian analyses. Two major clades were formed with northern individuals belonging to clade I and southern individuals belonging to clade II. G. b. sagittalis was paraphyletic in relation to G. b. breviceps in all analyses. Based on inconsistencies between the taxonomic classification and systematic relationships within Baird's pocket gopher, a taxonomic restructuring appears warranted.
Date: August 2010
Creator: Bodine, Deanna Martinez

Do College Students with ADHD have Expressive Writing Difficulties as Do Children with ADHD?

Description: This study analyzed the expressive writing of college students. Twenty-two ADHD students and 22 controls were asked to write a story based on a picture story and a personal challenge. The texts were compared based on several qualitative and quantitative parameters. The results show that students in both groups presented similar text quality. Out of six qualitative parameters only one was statistically different between the two groups: ADHD students performed worse in adequacy, but only in the picture task. Students writings were also investigated using corpus based analysis. This analysis showed that ADHD students used less unusually frequent words in the picture story but more in the challenge task. Taken together the findings indicate no significant difference in expressive writing between ADHD and non ADHD college students. An explanation to this result is that college students with ADHD may have passed the filter of prior education.
Date: August 2010
Creator: Mantecon, Hripsime Der-Galustian

Development of a Pre-Impact Environmental Site Characterization for the Bryan Mound, Texas Strategic Petroleum Reserve

Description: This thesis presents a model for developing site-specific contingency plans to be used during spill response, remediation, and post-spill monitoring using the Strategic Petroleum Reserve's Bryan Mound site as a case study. Bird and vegetation observations provide baseline data for biological conditions, and sediment sampling for total petroleum hydrocarbons serves as a chemical component of the model. Results demonstrate previously unknown conditions that would hinder remediation and affect the persistence of petroleum contaminants. Results also established previously unmapped dominant bird and vegetation types likely to be impacted by a spill at the site. This model points to a reconsideration of individual facilities' responsibilities when planning for large-scale disasters and protecting the sensitive ecosystems surrounding their sites.
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Date: December 2001
Creator: Hernandez, Sylvia A.

Eye of the beholder: Children respond to beauty in art.

Description: The purpose of this study was to determine if beauty was important to elementary age children when exploring and making aesthetic judgements about works of art and to determine the criteria elementary students used in judging beauty in works of art. This study also explored beauty as a concept that could be used as an organizing idea for designing a thematic unit with the purpose of introducing elementary students to postmodern art and issues. One hundred and sixty first grade and fourth grade students looked at 20 pairs of art reproductions and picked the artwork they considered the most beautiful. The criteria elementary students use for determining beauty in artworks was found to be color, realism, subject matter and physical appearance of the subject of the work of art.
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Date: May 2002
Creator: Meli, Alisa A.

The preparation and characterization of thermo-sensitive colored hydrogel film and surfactant-free porous polystyrene three-dimensional network.

Description: Polymer hydrogel films change their properties in response to environmental change. This remarkable phenomenon results in many potential applications of polymer hydrogel films. In this thesis colored thermo-sensitive poly(N-isopropylacrylamide) (PNIPAAm) hydrogel film was prepared by firstly synthesizing polymer latex and secondarily crosslinking the nanoparticles and casting the polymers onto glass. The shape-memory effect has been observed when changing the environmental temperature. The temperature-dependent of turbidity of polymer hydrogel film was measured by HP UVVisible spectrophotometer. This intelligent hydrogel might be used in chemomechanical systems and separation devices as well as sensors. Polymer adsorption plays an important role in many products and processes. In this thesis, surfactant-free three-dimensional polystyrene (PS) nanoparticle network has been prepared. The infrared spectroscopy and solubility experiment are performed to prove the crosslinking mechanism, also the BET method was used to measure the adsorption and desorption of polystyrene network. The BET constant (C) is calculated (C=6.32). The chemically bonded polymer nanoparticle network might have potential applications as catalyst or used for chromatographic columns.
Date: December 2001
Creator: Zhou, Bo

Self-Objectification, Body Image, Eating Behaviors, and Exercise Dependence among College Females

Description: The purposes of this study were to examine the associations between (a) self-objectification, (b) body shame, (c) appearance anxiety, and (d) exercise dependence. Participants (N = 155) completed a demographic questionnaire and a survey packet including the Body Surveillance subscale and Body Shame subscale of the Objectified Body Consciousness Scale, Appearance Anxiety Scale, Eating Attitudes Test 26, and the Exercise Dependence Scale. Correlations were conducted revealing associations between self-objectification, body shame, appearance anxiety, and eating attitudes. Associations were also found between body shame and exercise dependence. Partial correlations were conducting revealing body shame and appearance anxiety mediated the relationship between self-objectification and eating attitudes. Body shame also mediated the relationship between self-objectification and exercise dependence.
Date: August 2010
Creator: Kessler, Kelly L.

Effects of a Near-Death Experience Learning Module on Grief

Description: The researcher examined the effectiveness of a near-death experience (NDE) learning module on reducing distressing aspects and enhancing a growth aspect of grief among bereaved adults. Participants were 22 females and 2 males; 2 identified as African American, 3 as Asian, 2 as Latina/o, and 17 as White; aged 20 to 71 years with mean age 35.3 years. In this experimental design, the researcher randomly assigned 12 participants to the experimental group and 12 participants to the waitlist no treatment control group. Participants in the experimental group received the NDE learning module intervention, which consisted of 3 sessions over consecutive weeks. Six research questions were explored. A two-factor repeated measures analysis of variance was performed on five dependent variables to determine if the two groups performed differently across time according to the pretest and posttest results of the Despair, Panic Behavior, Personal Growth, Detachment, and Disorganization subscales of the Hogan Grief Reaction Checklist (HGRC). A one-way analysis of covariance was performed on one dependent variable to determine if the groups were statistically different according to the posttest results of the Blame and Anger subscale of the HGRC. Additionally, univariate eta squared was hand calculated to determine practical significance. Findings indicated that bereaved adults who participated in the NDE learning module showed small effect size for interaction on Panic Behavior (&#951;2 = .05) and Personal Growth (&#951;2 = .05), large effect size for interaction on Detachment (&#951;2 = .15), large effect size for treatment type on Blame and Anger (&#951;2 = .15), and negligible effect size for interaction on Despair (&#951;2 < .01) and Disorganization (&#951;2 < .01). Although no statistically significant results were found for any of the dependent variables (p > .05), effect size findings indicated modest to substantial benefits of the NDE learning module intervention for bereaved adults ...
Date: August 2010
Creator: Foster, Ryan D.

Effects of Adult Romantic Attachment and Social Support on Resilience and Depression in Patients with Acquired Disabilities

Description: The acquirement of a disability (e.g., spinal cord injury, traumatic brain injury, amputation, multi trauma) is a risk factor for psychological disturbance (e.g., depression). Research has established that social support and secure attachment are protective factors against psychological disturbance. Attachment patterns have also been associated with differences in perceived social support. Secure attachment and higher perceived social support have been implicated in greater levels of resilience but need to be validated with a population of individuals who have acquired a disability. The Experiences in Close Relationships, Social Provisions Scale, Connor-Davidson Resilience Scale, Personal Health Questionnaire - 9 Depression Scale, and a Demographic were administered to 102 adult inpatients at a rehabilitation hospital undergoing an individualized rehabilitation program. Two MANOVAs were conducted to examine the direct associations of attachment classifications with the major dependent variables, as well as the various social support subscales. Path analysis tested two mediational models suggested by literature. Model 1 assessed the mediating role of attachment anxiety and attachment avoidance on the effect of social support on depression and resilience. Model 2 assessed the mediating role of social support on the effect of attachment anxiety or attachment avoidance on depression and resilience. Partial support was obtained for both models based on fit indices. A small but significant difference in the fit of the models was found, favoring Model 1. Clinical and research implications for this population and the limitations of the study are discussed.
Date: August 2010
Creator: Dodd, Zane

The Influence of Income, Ethnicity, and Parenting on Child Health

Description: Children in low-income and ethnic minority families are more likely to be in poor health, which may impact physical and economic well-being in adulthood. This study explored how maternal depression and parenting efficacy were associated with child health outcomes in a sample of low-income African American and Latino families. Results demonstrated that children in optimal health were more likely to have mothers with high parenting efficacy and fewer depressive symptoms. Differences between African American and Latino families illustrated the importance of considering both socioeconomic and racial and ethnic disparities in child health simultaneously. Parent characteristics may be opportune targets for addressing child health disparities, and future research should focus on understanding these associations and identifying parent behaviors associated with child health.
Date: August 2010
Creator: Dier, Shannon E.

Wind Energy-related Wildlife Impacts: Analysis and Potential Implications for Rare, Threatened and Endangered Species of Birds and Bats in Texas

Description: Texas currently maintains the highest installed nameplate capacity and does not require publicly available post-construction monitoring studies that examine the impacts of wind energy production on surrounding fauna. This thesis examines potential wind energy impacts on avian and bat species in Texas through a three-part objective. The first two objectives synthesize literature on variables attractive to species within wind development areas and estimate impacted ranges outside of Texas, based on studies examining wind energy's environmental impacts. The third objective focuses on Texas wind development potential for interaction with rare, threatened and endangered species of birds and bats using GIS analysis with a potential hazard index (PHI) model, which addresses broad-spectrum, high risk variables examined within the first two objectives. Assuming areas with higher wind speeds have potential for wind development, PHI values were calculated for 31 avian and ten bat species, based on an analysis of species range data obtained from the Texas Parks and Wildlife Department and wind data obtained from the National Renewable Energy Laboratory. Results indicate one avian species, Tympanuchus pallidicinctus, is at high risk for wind development interaction on an annual basis, with 20 species of birds and nine species of bats at higher risk during the spring season. This macro-scale approach for identifying high risk species in Texas could be used as a model to apply to other conterminous states' preliminary evaluation of wind energy impacts.
Date: August 2010
Creator: Graham, Tara L.

The Reasons for the Divergence of IPO Lockup Agreements

Description: Most initial public offerings (IPOs) feature share lockup agreements, which prohibit insiders from selling their shares for a specified period of time following the IPO. However, some IPO firms agree to have a much longer lockup period than other IPO firms, and some are willing to lockup a much larger proportion of shares. Thus, the primary research question for this study is: "What are the reasons for the divergence of the lockup agreements?" The two main hypotheses that this dissertation investigates are the signaling hypothesis based on information asymmetry, and the commitment hypothesis based on agency theory. This study uses methods that have not been applied by previous studies in the literature relating to IPO lockups. First, I directly use IPO firms operating performance as a proxy for firm quality. The results show neither a negative nor a strong positive relationship between lockup length and firm operating performance. Thus, based on operating performance, the evidence does not support the agency hypothesis while showing weak support for the signaling hypothesis. I then examine the long-run returns for IPO firms with different lockup lengths. I find that firms with short lockup lengths have much better long-run returns than firms with long lockup lengths. Therefore, the results reject the signaling hypothesis while supporting the agency hypothesis. This dissertation further contributes to the IPO long-run underperformance literature by showing that firms with a high agency problem have much worse long-run returns than those with a low agency problem. Finally, I investigate the short-term stock returns around lockup expiry. Generally, I find that firms with short lockup periods experience better stock returns around lockup expiry than firms with long lockup periods, though the returns are not significantly different from one another. Overall, I conclude that the results reject the signaling hypothesis while partially supporting the ...
Date: August 2010
Creator: Gao, Fei

Factors Affecting Revictimization in Survivors of Childhood Sexual Abuse

Description: Structural equation modeling was used to examine how childhood sexual abuse (and other associated variables, such as family functioning and experiencing multiple forms of abuse) relates to revictimization and psychological distress. Participants were women who participated in Project HOW: Health Outcomes of Women interviews, a longitudinal study that spanned six waves of interviews. Only women with a history of childhood sexual abuse were included in the present study (n=178). Experiencing nonsexual child maltreatment in addition to childhood sexual abuse appears directly related to adult sexual and physical revictimization and indirectly related to psychological distress. Childhood sexual abuse alone was not predictive of revictimization or psychological abuse. This suggests that other mediating factors may explain the relation between CSA and revictimization found in other research. Clinical implications based on the results of the present study emphasize the importance of identifying children who have experienced multiple forms of abuse as particularly at risk for future victimization. In addition, providing interventions with a focus on education and empowerment might decrease risk for future violence and subsequent emotional maladjustment. Potential future research could examine the treatment outcomes and efficacy of these interventions as well as identify those mediating factors that increase the risk for adult revictimization for those individuals who experience only childhood sexual abuse.
Date: August 2010
Creator: Ericksen, Stephanie J.

Service Matters: The Influence of Military Service on Political Behavior, Ideology and Attitudes

Description: The objective of this research is to explore the influence of military service on political behaviors and attitudes. Existing studies of the military have long recognized the existence of a predominantly conservative political ideology with a resulting propensity for strong Republican Party support within the military community, but have failed to explain the likely causal mechanism for this. Drawing on multiple sources of data from the 2008 Presidential election cycle, I utilized a descriptive analysis of campaign contribution data and bivariate and multivariate analyses of data from the 2008 Military Times Survey and the 2008 American National Election Survey. Much of the data also permitted me to analyze the effect of an individual's service branch on their attitudes as well. I examined the behavior and attitudes of the military across several dimensions, including candidate support and positions on policies of particular relevance to the military, including the wars in Iraq and Afghanistan. This analysis found that people who serve in the military tend to be conservative but in many ways their political attitudes are reflective of those of the general population. An individual's race, ethnicity and gender appear to have more influence than military factors, with the exception of service in the Marine Corps, on ideology, partisan identification and policy preferences.
Date: August 2010
Creator: Johnson, Catherine L.