Studies of Solvent Displacement from Solvated Metal Carbonyl Complexes of Chromium, Molybdenum, and Tungsten
Description:
Flash photolysis techniques were applied to studies of solvent displacement by Lewis bases (L) from solvated metal carbonyl complexes of Cr, Mo, and W. On the basis of extensive studies of the reaction rate laws, activation parameters , and linear-free-energy-relationships, it was concluded that the mechanisms of solvent displacement reactions depend on the electronic and steric properties of the solvents and L, as well as the identities of the metal atoms. The strengths of solvent-metal bondin…
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Date:
August 1990
Creator:
Zhang, Shulin