UNT Libraries - 3 Matching Results

Search Results

Results: 1 - 3
open access

The Chlorination of Amino Acid in Municipal Waste Effluents

Description: In model reaction systems to test amino acids in chlorinated waste effluents, several amino acids were chlorinated at high chlorine doses. (2000-4000 mg/1). Amino acids present in municipal waste effluents before and after chlorination were concentrated and purified using cation exchange and Chelex resins. After concentration and cleanup of the samples, the amino acids were derivatized by esterification of the acid functional groups and acylation of the amine groups. Identification and quantifi… more
Date: July 1977
Creator: Burleson, Jimmie L.
Item Type: Refine your search to only Thesis or Dissertation
open access

Organometallic Precursors to Cyclic Organosilanes

Description: This investigation deals with the preparations of cyclic organosilanes via two different types of organometallic precursors: borane adducts to chlorovinylsilanes and tertbutyllithium adducts to chlorovinylsilanes. The regiospecificity of the hydroboration of various types of boranes to chlorovinylsilanes was studied by three different methods. It was found that, by using bulky hydroborating agents, about 80% isomerically pure terminal borane adducts to chlorovinylsilanes could be obtained. Whil… more
Date: May 1977
Creator: Lim, Thomas Fay-Oy
Item Type: Refine your search to only Thesis or Dissertation
open access

Studies of the Mechanisms of Reactions of Binary Metal Carbonyls

Description: A kinetic study of the reactions of Group VI-B hexacarbonyls with primary amine and halide ligands was undertaken in order to determine the possible mechanisms of these reactions. As well as the expected dissociative pathway, the reactions with the primary amines were seen to proceed by a concurrent pathway which was dependent upon the ligand concentration. Since nitrogen donor ligands are expected to be poor donor ligands, the mechanism proposed was a "dissociative interchange" mechanism which… more
Date: May 1977
Creator: Pardue, Jerry E.
Item Type: Refine your search to only Thesis or Dissertation
Back to Top of Screen