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Assessment of the Efficacy of a Constructed Wetland to Reduce or Remove Wastewater Effluent Estrogenicity and Toxicity Using Biomarkers in Male Fathead Minnows (Pimephales Promelas Rafinesque, 1820)

Description: Vitellogenin in Pimephales promelas was used to assess estrogenicity of a local municipal effluent. Vitellogenin induction in male P. promelas increased in frequency and magnitude with increased exposure duration and was greater ("=0.05) than controls after 2 and 3 weeks of exposure. The level of vitellogenesis induced by effluent exposure was high compared to similar studies. A spring season evaluation followed. Biomarkers in P. promelas were used to assess the efficacy of a treatment wetland to remove toxicity and estrogenicity in final treated wastewater effluent. Comparisons were made with an effluent dominated stream and laboratory controls. Vitellogenin, GSIs (gonado-somatic indices), HSIs (hepato-somatic indices) and secondary sexual characteristics were biomarkers used in P. promelas models to assess aqueous estrogenicity. Biological indicators used to assess general fish health included hematocrit and condition factors. The estrogenic nature of the effluent was screened, concurrent with fish exposure, with GC/MS analysis for target estrogenic compounds including: 17-b estradiol, estrone, ethynylestradiol, Bisphenol A, nonylphenolic compounds, phthalates, and DDT. Plasma vitellogenin measured in P. promelas was significantly elevated (p < 0.0001) at the inflow site of the wetland and stream sites. GSIs for these exposures were less (a=0.001) at the wetland inflow site. At wetland sites closest to the inflow, secondary sexual charateristics, tubercle numbers and fat pad thickness, were less (a=0.0001). Hematocrit and condition factors were less (a=0.001) at sites closer to the wetland inflow. Seasonal variation was examined by repeating the effluent characterization in summer. Additionally, summer testing included exposure to an effluent dilution series. Fish condition heavily influenced interpretation of the results. Pre-acclimation exposure to spawning stresses may have altered many of the biological markers measured. Results are discussed relative to fish health and pre-exposure environment. Toxicity assessed with P. promelas biomarkers was compared with Ceriodaphnia dubia and Vibrio fischeri toxicty tests on this ...
Date: December 2000
Creator: Hemming, Jon M.

Bioaccumulation of Triclocarban, Triclosan, and Methyl-triclosan in a North Texas Wastewater Treatment Plant Receiving Stream and Effects of Triclosan on Algal Lipid Synthesis.

Description: Triclosan (TCS) and triclocarban (TCC), widely used antimicrobial agents found in numerous consumer products, are incompletely removed by wastewater treatment plant (WWTP) processing. Methyl-triclosan (M-TCS) is a more lipophilic metabolite of its parent compound, TCS. The focus of this study was to quantify bioaccumulation factors (BAFs) for TCS, M-TCS, and TCC in Pecan creek, the receiving stream for the City of Denton, Texas WWTP by using field samples mostly composed of the alga Cladophora sp. and the caged snail Helisoma trivolvis as test species. Additionally, TCS effects on E. coli and Arabidopsis have been shown to reduce fatty acid biosynthesis and total lipid content by inhibiting the trans-2 enoyl- ACP reductase. The lipid synthesis pathway effects of TCS on field samples of Cladophora spp. were also investigated in this study by using [2-14C]acetate radiolabeling procedures. Preliminary results indicate high TCS concentrations are toxic to lipid biosynthesis and reduce [2-14C]acetate incorporation into total lipids. These results have led to the concern that chronic exposure of algae in receiving streams to environmentally relevant TCS concentrations might affect their nutrient value. If consumer growth is limited, trophic cascade strength may be affected and serve to limit population growth and reproduction of herbivores in these riparian systems.
Date: August 2007
Creator: Coogan, Melinda Ann

Bioavailability and toxicity of 2,4,6-trinitrotoluene in sediment.

Description: TNT (2,4,6-trinitrotoluene) is a persistent contaminant at many military installations and poses a threat to aquatic ecosystems. Data from environmental fate and toxicity studies with TNT revealed that sediment toxicity test procedures required modification to accurately assess sediment TNT toxicity. Key modifications included aging TNT-spiked sediments 8-14 d, basing lethal dose on measured sediment concentrations of the molar sum of TNT and its main nitroaromatic (NA) transformation products (SNA), basing sublethal dose on average sediment SNA concentrations obtained from integration of sediment SNA transformation models, avoiding overlying water exchanges, and minimizing toxicity test durations. Solid phase microextraction fibers (SPMEs) were investigated as a biomimetic chemical measure of toxicity and bioavailability. Both organism and SPME concentrations provided measures of lethal dose independent of exposure scenario (TNT-spiked sediment or TNT-spiked water) for Tubifex tubifex. Among all benthic organisms tested (Chironomus tentans, Ceriodaphnia dubia, T. tubifex) and matrixes, median lethal dose (LC50) estimates based on SPME and organism concentrations ranged from 12.6 to 55.3 mmol SNA/ml polyacrylate and 83.4 to 172.3 nmol SNA/g tissue, ww, respectively. For Tubifex, LC50s (95% CI) based on SNA concentrations in sediment and SPMEs were 223 (209-238) nmol SNA/g, dw and 27.8 (26.0-29.8) mmol SNA/ml, respectively. Reproductive effects occurred at slightly lower exposures. Median effective dose (EC50) estimates (95% CI) for Tubifex cocoon production, based on sediment and SPME concentrations, were 118 (114-122) nmol SNA/g, dw and 21.8 (21.2-22.4) mmol SNA/ml, respectively. Bioconcentration experiments with Tubifex revealed that compound hydrophobicity predicted the toxicokinetics and bioconcentration of these compounds from water, however, there was a large discrepancy between the toxicokinetics of absorbed versus metabolically-generated aminodinitrotoluenes. A large portion of bioconcentrated, radiolabeled TNT transformation products could not be identified. In addition to their ability to provide matrix-independent measures of dose, SPME concentrations were more accurate indicators of bioavailable NAs than ...
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Date: May 2004
Creator: Conder, Jason M.

Characterizing Storm Water Runoff from Natural Gas Well Sites in Denton County, Texas

Description: In order to better understand runoff characteristics from natural gas well sites in north central Texas, the City of Denton, with assistance through an EPA funded 104b3 Water Quality Cooperative Agreement, monitored storm water runoff from local natural gas well sites. Storm water runoff was found to contain high concentrations of total suspended solids (TSS). Observed TSS concentrations resulted in sediment loading rates that are similar to those observed from typical construction activities. Petroleum hydrocarbons, in contrast, were rarely detected in runoff samples. Heavy metals were detected in concentrations similar to those observed in typical urban runoff. However, the concentrations observed at the gas well sites were higher than those measured at nearby reference sites. Storm water runoff data collected from these sites were used to evaluate the effectiveness of the water erosion prediction project (WEPP) model for predicting runoff and sediment from these sites. Runoff and sediment predictions were adequate; however, rainfall simulation experiments were used to further characterize the portion of the site where drilling and extraction operations are performed, referred to as the "pad site." These experiments were used to develop specific pad site erosion parameters for the WEPP model. Finally, version 2 of the revised universal soil loss equation (RUSLE 2.0) was used to evaluate the efficiency of best management practices (BMPs) for natural gas well sites. BMP efficiency ratings, which ranged from 52 to 93%, were also evaluated in the context of site management goals and implementation cost, demonstrating a practical approach for managing soil loss and understanding the importance of selecting appropriate site-specific BMPs.
Date: May 2008
Creator: Wachal, David J.

City of Denton Municipal Solid Waste Characterization and Management Strategies

Description: Due to concern about diminishing landfill space, the City of Denton contracted a municipal solid waste characterization study in 1999 that would identify materials for diversion. This paper describes the results of 5 1-week waste sorting events, a scale-house analysis, a recycling participation study, a recycler profile and a similar city study. The results of the characterization studies suggest that at least 50% of each waste stream is recyclable or divertible though paper products accounted for no more than 45% by weight of any waste stream. Curbside recycling participation rate was 71% during the 6-week study period though the average weekly set-out rate was 37%. Recycling participation rates varied significantly by zip code and by home value categories but not by gender. Denton is fairly progressive in its waste management approach when compared to demographically similar cities on a 15-question assessment though recommendations for improvement have been identified.
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Date: May 2004
Creator: Brady, Patricia D.

Comparison of Bare Root vs. Potted Plants, Species Selection, and Caging Types for Restoration of a Prairie Wetland, and Quantitative Analysis and Descriptive Survey of Plant Communities and Associations at Lewisville Lake Environmental Learning Area (LLELA), Lewisville, TX

Description: Lewisville Lake Environmental Learning Area (LLELA) is an 809-hectare property in Denton County, TX. A study of the vegetation community identified 466 species in 104 families, with 25% of the species from only two families, Asteraceae and Poaceae. The property demonstrates the characteristics of an early successional community, dominated by weedy species. Prairie communities are dominated by Johnson grass and ragweed, with climax tall grass prairie communities only in areas that have been planted with native grass seed. Forest communities are similarly in an early successional stage, dominated by the hackberry-elm-ash alliance, with small remnants of native Cross Timbers found in isolated patches. Species richness and diversity were highest in the forests and lowest in the wetlands; evenness, though not different across ecosystems, demonstrated a strong seasonal component. The species list was compared with previously reported lists for Denton County, and 256 species identified had not been previously reported for the county. A wetland restoration study was conducted to determine if there was a difference in survival and growth between potted transplants with intact root systems and bare-root transplants. Two different mesh sizes were used for protection, and the success of the different caging was evaluated. Of eight species, only four survived through the second growing season. There was no significant difference in the success of the propagule types for Sagittaria latifolia. The treatments planted with intact root systems showed significantly higher growth and reproduction than the bare-root treatments for Eleocharis quadrangulata, Heteranthera dubia, and Vallisneria americana. There was no survival recorded in the coarse mesh cages, likely due to the presence of crayfish that are able to get through the coarser mesh and feed on the transplants.
Date: May 2007
Creator: Buckallew, Robin R.

A Data Fusion Framework for Floodplain Analysis using GIS and Remotely Sensed Data

Description: Throughout history floods have been part of the human experience. They are recurring phenomena that form a necessary and enduring feature of all river basin and lowland coastal systems. In an average year, they benefit millions of people who depend on them. In the more developed countries, major floods can be the largest cause of economic losses from natural disasters, and are also a major cause of disaster-related deaths in the less developed countries. Flood disaster mitigation research was conducted to determine how remotely sensed data can effectively be used to produce accurate flood plain maps (FPMs), and to identify/quantify the sources of error associated with such data. Differences were analyzed between flood maps produced by an automated remote sensing analysis tailored to the available satellite remote sensing datasets (rFPM), the 100-year flooded areas "predicted" by the Flood Insurance Rate Maps, and FPMs based on DEM and hydrological data (aFPM). Landuse/landcover was also examined to determine its influence on rFPM errors. These errors were identified and the results were integrated in a GIS to minimize landuse / landcover effects. Two substantial flood events were analyzed. These events were selected because of their similar characteristics (i.e., the existence of FIRM or Q3 data; flood data which included flood peaks, rating curves, and flood profiles; and DEM and remote sensing imagery.) Automatic feature extraction was determined to be an important component for successful flood analysis. A process network, in conjunction with domain specific information, was used to map raw remotely sensed data onto a representation that is more compatible with a GIS data model. From a practical point of view, rFPM provides a way to automatically match existing data models to the type of remote sensing data available for each event under investigation. Overall, results showed how remote sensing could contribute to ...
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Date: August 2000
Creator: Necsoiu, Dorel Marius

Development of a Procedure to Evaluate Groundwater Quality and Potential Sources of Contamination in the East Texas Basin

Description: This study contributes a procedure, based on data analysis and geostatistical methods, to evaluate the distribution of chemical ratios and differentiate natural and anthropogenic contaminant sources of groundwater quality in the East Texas Basin. Four aquifers were studied, Sparta, Queen City, Carrizo and Wilcox. In this study, Carrizo- Wilcox is considered as one aquifer, and Sparta-Queen City as another. These aquifers were divided into depth categories, 0-150 feet for Sparta-Queen City and 300-600 feet and 600-900 feet for Carrizo-Wilcox in order to identify individual sources of contamination. Natural sources include aquifer mineral make up, salt domes and lignite beds. Major anthropogenic sources include lignite and salt dome mining and oil-gas production. Chemical ratios selected were Na/Cl, Ca/Cl, Mg/Cl, SO4/Cl, (Na+Cl)/TDS, SO4/Ca and (Ca+Mg)/(Na+K). Ratio distributions and their relationships were examined to evaluate physical-chemical processes occurring in the study area. Potential contaminant sources were used to divide the Basin into three areas: Area 1 to the east, Area 2 in the west and Area 3 in the center. Bivariate analysis was used to uncover differences between the areas. The waters in Area 1 are potentially impacted primarily from oil field waters. Sources present in Area 2 include lignite beds and oil field operations. Area 3 is the cap rock of salt domes that can contain gypsum and anhydrite. Based on the exploratory data analysis (Na+Cl)/TDS, (Ca+Mg)/(Na+K), and SO4/Ca ratios were chosen for geostatistical analysis. Chemical ratios that provided indications of cation exchange, salt domes and oil fields were (Na+Cl)/TDS, (Ca+Mg)/(Na+K) and SO4/Ca. In the Sparta-Queen City 150 zone the procedure did not provide a good method for differentiating between contaminant sources. However, the procedure was effective to indicate impacted ground water in the Carrizo-Wilcox 600 and 900 foot zones.
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Date: May 2001
Creator: Alderman, John H.

Development, Validation, and Evaluation of a Continuous, Real-time, Bivalve Biomonitoring System

Description: A biological monitoring tool to assess water quality using bivalve gape behavior was developed and demonstrated. The purpose of this work was to develop methodologies for screening water quality appropriate to the goals of the watershed paradigm. A model of bivalve gape behavior based on prediction of behavior using autoregressive techniques was the foundation of the bivalve biomonitoring system. Current technology was used in developing the system to provide bivalve gape state data in a continuous real-time manner. A laboratory version of the system, including data collection and analysis hardware and software, was developed for use as a toxicological assay for determination of effective concentrations of toxicant(s) or other types of stress on bivalve gape behavior. Corbicula fluminea was monitored and challenged with copper, zinc, and chlorpyrifos using the system. Effective concentrations of 176±23µg/L copper, 768±412µg/L zinc, and 68µg/L chlorpyrifos were observed using a natural water with high dissolved organic carbon concentrations. A rugged field version of the bivalve biomonitoring system was developed and deployed in two locations. The field systems were fitted with a photovoltaic array, a single board computer, and a CDPD telemetry modem for robust remote operation. Data were telemetered at a time relevant rate of once every ten minutes. One unit was deployed in Lake Lewisville, Denton County, TX in February 2000. Data were telemetered and archived at a 92% success rate. Bivalve gape data demonstrated significant behavioral deviations on average 5 times per month. A second unit was deployed in Pecan Creek, Denton, TX in June 2001. Data from this site were telemetered and archived at a 96% success rate. Over the months of June-August 2001, 16 significant behavioral deviations were observed, 63% of which were correlated with changes in physical/chemical parameters. This work demonstrated the relative sensitivity of bivalve gape as a toxicological endpoint ...
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Date: December 2002
Creator: Allen, H. Joel

Ecotoxicological Investigations in Effluent-Dominated Stream Mesocosms

Description: The University of North Texas Stream Research Facility (UNTSRF) was designed to examine contaminant impacts on effluent-dominated stream ecosystems. Stream mesocosms, fed municipal effluent from the City of Denton, TX, Pecan Creek Water Reclamation Plant (PCWRP), were treated with 0, 15 or 140 µg/L cadmium for a 10-day study in August 2000. Laboratory toxicity test and stream macroinvertebrate responses indicated that cadmium bioavailability was reduced by constituents of effluent-dominated streams. The Biotic Ligand Model (BLM) for Cd was used to predict a 48 hour Cd EC50 for Ceriodaphnia dubia of 280 µg/L in these effluent-dominated streams. This value is higher that an EC50 of 38.3 µg/L Cd and a 7-day reproduction effect level of 3.3 µg/L Cd generated for C. dubia in reconstituted laboratory hard water. These results support use of a cadmium BLM for establishing site-specific acute water quality criteria in effluent-dominated streams. Although not affected by 15 µg/L treatments, organisms accumulated Cd in 15 µg/L treated streams. Hence, over longer exposure periods, Cd accumulation may increase and a no effect level may be lower than the observed 10-day no effect level of 15 µg/L. A toxicity identification evaluation procedure was utilized with in vitro and in vivo bioassays to identify estrogenic compounds in PCWRP effluent, previously identified to seasonally induce vitellogenin (VTG) in male fathead minnows. Steroids, nonylphenol ethoxylate metabolites, and other unidentified compounds were identified as causative effluent estrogens. These findings suggest that in vivo VTG bioassays should be used to confirm in vitro Yeast Estrogen Screening assay activity when effluents are fractionated or screened for estrogenicity. A subsequent 90-day cadmium study was initiated to assess long-term effluent and cadmium effects on fish endocrine function. Juvenile fathead minnows were placed in UNTSRF pool sections of replicate streams treated with 0, 5, 20 or 80 µg/L Cd. Male ...
Date: December 2002
Creator: Brooks, Bryan W.

Effects on Survival, Reproduction and Growth of Ceriodaphnia dubia following Single Episodic Exposure to Copper or Cadmium

Description: Effects of episodic exposures have gained attention as the regulatory focus of the Clean Water Act has shifted away from continuous-flow effluents. Standardized laboratory toxicity tests require that exposure be held constant. However, this approach may not accurately predict organism responses in the field following episodic exposures such as those associated with rain-driven runoff events or accidental pollutant discharge. Using a modified version of the 7-day short-term chronic test recommended by the US Environmental Protection Agency, Ceriodaphnia dubia were exposed to copper or cadmium for durations ranging from 1 minute to 24 hours. In addition, adult reproductive recovery and effects on second generation individuals was assessed following select copper exposures. Finally, cadmium exposures were compared in reconstituted hard water (RHW) and municipal treated wastewater effluent (TWE). Following exposure, organisms were transferred to clean RHW or TWE and maintained for the remainder of the test. No- and lowest observed effect concentrations (NO- and LOECs) increased logarithmically with respect to logarithmic decreases in duration regardless of metal, endpoint or water type. Effective concentrations of cadmium however, were usually higher than those of copper, especially in TWE. LOECs for C. dubia survival following 24-hour and 5-minute exposures to copper were 116 and 417 µg/L, respectively. LOECs for fecundity were 58 and 374 µg/L, respectively. Neonate production of first generation adult C. dubia appeared to recover from pulsed copper exposure upon examination of individual broods. Cumulative mean neonate production however, showed almost no signs of recovery at exposure durations ≥3 hours. Pulse exposure to copper also resulted in diminished fecundity of unexposed second generation individuals. Such effects were pronounced following parental exposure for 24 hours but lacking after parental exposures ≤3 hours. LOECs for C. dubia survival following 24-hour and 5-minute exposures to cadmium in RHW were 44 and 9000 µg/L, respectively. LOECs for ...
Date: August 2005
Creator: Turner, Philip K.

Evaluation of the Economic, Social, and Biological Feasibility of Bioconverting Food Wastes with the Black Soldier Fly (Hermetia illucens)

Description: Food waste in the waste stream is becoming an important aspect of integrated waste management systems. Current efforts are composting and animal feeding. However, these food waste disposal practices rely on slow thermodynamic processes of composting or finding farmers with domestic animals capable of consuming the food wastes. Bioconversion, a potential alternative, is a waste management practice that converts food waste to insect larval biomass and organic residue. This project uses a native and common non-pest insect in Texas, the black soldier fly, which processes large quantities of food wastes, as well as animal wastes and sewage in its larval stage. The goal of this research is to facilitate the identification and development of the practical parameters of bioconversion methods at a large cafeteria. Three major factors were selected to evaluate the practicality of a bioconversion system: (1) the biological constraints on the species; (2) the economic costs and benefits for the local community; (3) the perception of and interaction between the public and management agencies with respect to the bioconversion process. Results indicate that bioconversion is feasible on all levels. Larvae tolerate and consume food waste as well as used cooking grease, reducing the overall waste volume by 30-70% in a series of experiments, with an average reduction of 50%. The economical benefits are reduced collection costs and profit from the sale of pupae as a feedstuff, which could amount to as much as $1,200 per month under optimal conditions. Social acceptance is possible, but requires education of the public, specifically targeting school children. Potential impediments to social acceptance include historical attitudes and ignorance, which could be overcome through effective educational efforts.
Date: August 2004
Creator: Barry, Tami

Geology as a Georegional Influence on Quercus Fagaceae Distribution in Denton and Coke Counties of Central and North Central Texas and Choctaw County of Southeastern Oklahoma, Using GIS as an Analytical Tool.

Description: This study elucidates the underlying relationships for the distribution of oak landcover on bedrock and soil orders in two counties in Texas and one in Oklahoma. ESRI's ArcGis and ArcMap was used to create surface maps for Denton and Coke Counties, Texas and Choctaw County, Oklahoma. Attribute tables generated in GIS were exported into a spreadsheet software program and frequency tables were created for every formation and soil order in the tri-county research area. The results were both a visual and numeric distribution of oaks in the transition area between the eastern hardwood forests and the Great Plains. Oak distributions are changing on this transition area of the South Central Plains. The sandy Woodbine and Antlers formations traditionally associated with the largest oak distribution are carrying oak coverage of approximately 31-32% in Choctaw and Denton Counties. The calcareous Blackland and Grand Prairies are traditionally associated with treeless grasslands, but are now carrying oak and other tree landcover up to 18.9%. Human intervention, including the establishment of artificial, political and social boundaries, urbanization, farming and fire control have altered the natural distribution of oaks and other landcover of this unique georegion.
Date: December 2007
Creator: Maxey, George F.

A geospatial tool for assessing potential wildland fire risk in central Texas.

Description: Wildland fires in the United States are not always confined to wilderness areas. The growth of population centers and housing developments in wilderness areas has blurred the boundaries between rural and urban. This merger of human development and natural landscape is known in the wildland fire community as the wildland urban interface or WUI, and it is within this interface that many wildland fires increasingly occur. As wildland fire intrusions in the WUI increase so too does the need for tools to assess potential impact to valuable assets contained within the interface. This study presents a methodology that combines real-time weather data, a wildland fire behavior model, satellite remote sensing and geospatial data in a geographic information system to assess potential risk to human developments and natural resources within the Austin metropolitan area and surrounding ten counties of central, Texas. The methodology uses readily available digital databases and satellite images within Texas, in combination with an industry standard fire behavior model to assist emergency and natural resource managers assess potential impacts from wildland fire. Results of the study will promote prevention of WUI fire disasters, facilitate watershed and habitat protection, and help direct efforts in post wildland fire mitigation and restoration.
Date: August 2005
Creator: Hunter, Bruce Allan

Influence of Sediment Exposure and Water Depth on Torpedograss Invasion of Lake Okeechobee, Florida

Description: Torpedograss (Panicum repens) was first observed in Lake Okeechobee in the 1970s and appears to have displaced an estimated 6,400 ha of native plants, such as spikerush (Eleocharis cellulosa), where inundation depths are often less than 50 cm. Two series of studies evaluated substrate exposure and water depth influences on torpedograss establishment and competitiveness. Results revealed that fragments remain buoyant for extended periods and so facilitate dispersal. Once anchored to exposed substrate fragments can readily root and establish. Subsequently, torpedograss thrives when subjected to inundations to 75 cm and survives prolonged exposure to depths greater than 1 m. These findings suggest that fluctuating water levels contribute to torpedograss dispersal and colonization patterns and that low water levels increase marsh area susceptible to invasion. The competition study found that spikerush grown in monoculture produces significantly more biomass when continually inundated to shallow depths (10 to 20 cm) than when subjected to drier conditions (-25 cm) or greater inundations (80 cm). In contrast, torpedograss establishes more readily on exposed substrate (-25 to 0 cm) compared to inundate substrates. During the first growing season biomass production increases as substrate exposure interval increases. However, during the second year, established torpedograss produces more biomass when grown on intermittently wet (0 cm) compared to permanently dry (-25 cm) or intermittently inundated (10 cm) substrates. No difference in production was observed between substrates permanently inundated (10 cm) and any other regime tested. During the first two years of torpedograss invasion, regardless of treatment, spikerush suppresses invasion and torpedograss had little effect on established spikerush, indicating that spikerush-dominated areas are capable of resisting torpedograss invasion. Even so, disturbances that might cause mortality of long hydroperiod species, such as spikerush, may create open gaps in the native vegetation and thus facilitate torpedograss establishment and expansion.
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Date: December 2006
Creator: Smith, Dian H.

Investigation of Lead Hydrolytic Polymerization and Interactions with Organic Ligands in the Soil/Sediment-Water Environment

Description: The objective of this research was to investigate lead speciation in the soil/sediment-water environment and to better understand how the species affect lead mobility under different environmental conditions. The research involved both field soil and sediment samples as well as standard lead solutions. Field samples were fully characterized and extracted by aqueous and organic solvents. The results were compared and evaluated with the metal speciation model, MINTEQA2. Hydrolytic polymerization and organic complexation studies were conducted with standard lead solutions under controlled experimental conditions. Results of the field samples showed that pH, dissolved cations, ionic strength, dissolved organic matter, and nature of the soil/sediment matrix play major roles in the distribution and mobility of lead (Pb) from contaminated sites. In the aqueous equilibration experiment, the magnitude of Pb2+ solubilization was in the order of pH4>pH7>pH9. The results were in good agreement with MINTEQA2 predictions. An important finding of the research is the detection of Pb polymerization species under controlled experimental conditions. At pH 5.22, Pb polymeric species were formed at rate of 0.03 per day. The role of Pb complexation with organic matter was evaluated in both field and standard samples. Different methodologies showed three types of organically bound Pb. A very small fraction of Pb, in the ppb range, was extractable from the contaminated soil by polar organic solvents. Sequential extractions show that 16.6±1.4 % of the Pb is organically complexed. Complexation of Pb with fulvic acid provided new information on the extent of Pb association with soluble organic matter. The overall results of this research have provided new and useful information regarding Pb speciation in environmental samples. The results, in several instances, have provided verification of MINTEQA2 model's prediction. They also revealed areas of disagreement between the models prediction and the experimental results. A positive note regarding the experimental ...
Date: December 2002
Creator: Sanmanee, Natdhera

Modeling of Land Use Change Effects on Storm Water Quantity and Quality in the City of Carrollton and the North Texas Area

Description: Development and population are rapidly increasing in urbanizing areas of North Texas and so is the need to understand changes in storm water runoff flow and its contamination by nutrients, sediment, pesticides and other toxicants. This study contributes to this understanding and has two primary components: first, development of a graphical user interface for a geographic information system and storm water management database, and second, performing a two-scale hydrological modeling approach (the US Corp of Engineers HEC-HMS model and the US Environmental Protection Agency SWMM model). Both primary components are used together as a toolkit to support the storm water management program of the City of Carrollton, located in North Texas. By focusing limited city resources, the toolkit helps storm water managers in the process of compliance with federal regulations, especially the National Pollution Discharge Elimination System permit, and provides guidance for reporting, planning and investigation. A planning example was conducted by modeling potential changes in storm water quality due to projections of land use based on the City of Carrollton's Comprehensive Plan. An additional component of this study is the evaluation of future changes in surface water quantity and quality in the North Central Texas area, specifically in a rural but rapidly urbanizing subbasin area of the greater Lake Lewisville watershed. This was accomplished using the US Corp of Engineers HEC-HMS hydrological model. Precipitation scenarios were derived from years of historically high, medium, and low annual precipitation. Development scenarios were derived from current land use in the Lake Lewisville sub basin, current land use in the city of Carrollton, and from Markov projections based on recent land use change calculated from satellite images of 1988 and 1999. This information is useful for future land use planning and management of water resources in North Texas.
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Date: December 2003
Creator: Duncan, Phillip Brent

On-Road Remote Sensing of Motor Vehicle Emissions: Associations between Exhaust Pollutant Levels and Vehicle Parameters for Arizona, California, Colorado, Illinois, Texas, and Utah

Description: On-road remote sensing has the ability to operate in real-time, and under real world conditions, making it an ideal candidate for detecting gross polluters on major freeways and thoroughfares. In this study, remote sensing was employed to detect carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxide (NO). On-road remote sensing data taken from measurements performed in six states, (Arizona, California, Colorado, Illinois, Texas, and Utah) were cleaned and analyzed. Data mining and exploration were first undertaken in order to search for relationships among variables such as make, year, engine type, vehicle weight, and location. Descriptive statistics were obtained for the three pollutants of interest. The data were found to have non-normal distributions. Applied transformations were ineffective, and nonparametric tests were applied. Due to the extremely large sample size of the dataset (508,617 records), nonparametric tests resulted in "p" values that demonstrated "significance." The general linear model was selected due to its ability to handle data with non-normal distributions. The general linear model was run on each pollutant with output producing descriptive statistics, profile plots, between-subjects effects, and estimated marginal means. Due to insufficient data within certain cells, results were not obtained for gross vehicle weight and engine type. The "year" variable was not directly analyzed in the GLM because "year" was employed in a weighted least squares transformation. "Year" was found to be a source of heteroscedasticity; and therefore, the basis of a least-squares transformation. Grouped-years were analyzed using medians, and the results were displayed graphically. Based on the GLM results and descriptives, Japanese vehicles typically had the lowest CO, HC, and NO emissions, while American vehicles ranked high for the three. Illinois, ranked lowest for CO, while Texas ranked highest. Illinois and Colorado were lowest for HC emissions, while Utah and California were highest. For NO, Colorado ranked highest ...
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Date: May 2003
Creator: Dohanich, Francis Albert

Organic carbon dynamics of the Neches River and its floodplain.

Description: A large river system typically derives the majority of its biomass from production within the floodplain. The Neches River in the Big Thicket National Preserve is a large blackwater river that has an extensive forested floodplain. Organic carbon was analyzed within the floodplain waters and the river (upstream and downstream of the floodplain) to determine the amount of organic carbon from the floodplain that is contributing to the nutrient dynamics in the river. Dissolved organic carbon was significantly higher at downstream river locations during high discharge. Higher organic carbon levels in the floodplain contributed to increases in organic carbon within the Neches River downstream of the floodplain when Neches River discharges exceeded 10,000 cfs. Hurricane Rita passed through the Big Thicket National Preserve in September 2005. Dissolved organic carbon concentrations recorded after Hurricane Rita in the Neches River downstream of the floodplain were significantly higher than upstream of the floodplain. Dissolved organic carbon was twice as high after the hurricane than levels prior to the hurricane, with floodplain concentrations exceeding 50 ppm C. The increase in organic carbon was likely due to nutrients leached from leaves, which were swept from the floodplain trees prior to normal abscission in the fall. A continuum of leaf breakdown rates was observed in three common floodplain species of trees: Sapium sebiferum, Acer rubrum, and Quercus laurifolia. Leaves collected from blowdown as a result of Hurricane Rita did not break down significantly faster than leaves collected prior to abscission in the fall. Processing coefficients for leaf breakdown in a continuously wet area of the floodplain were significantly higher than processing coefficients for leaf breakdown on the floodplain floor. The forested floodplain of the Neches River is the main contributor of organic carbon. When flow is greater than 10,000 csf, the floodplain transports organic carbon directly ...
Date: December 2007
Creator: Stamatis, Allison Davis

A paleozoological perspective on predator extermination and white-tailed deer (Odocoileus virginianus Boddaert) overabundance in central Texas.

Description: Archaeological and paleontological datasets are used in conservation to add time-depth to ecology. In central Texas several top carnivores including prehistoric Native American hunters have been extirpated or have had their historic ranges restricted, which has resulted in pest-level white-tailed deer (Odocoileus virginianus texana) populations in some areas. Predator extermination has dramatically reduced the average body size of members of the extant predator guild, and large carnivores most capable of hunting white-tailed deer are extirpated. Character release in the remaining “large” predatorsmesocarnivoresis a predicted outcome related to the adaptive vacuum at the top of the trophic hierarchy. Differences in body size of deer between prehistory and modernity are expected given that a lack of predation likely has increased intraspecific competition for forage among deer resulting in smaller body size today. In fact modern deer from settings without harvest pressure are significantly smaller than those from harvested areas and from prehistoric deer. From a natural history perspective, this research highlights potential evolutionary causes and effects of top-predator removal on deer populations and related components of biological communities in central Texas.
Date: May 2007
Creator: Wolverton, Steven J.

Phosphorus Retention and Fractionation in Masonry Sand and Light Weight Expanded Shale Used as Substrate in a Subsurface Flow Wetland

Description: Constructed wetlands are considered an inefficient technology for long-term phosphorus (P) removal. The P retention effectiveness of subsurface wetlands can be improved by using appropriate substrates. The objectives of this study were to: (i) use sorption isotherms to estimate the P sorption capacity of the two materials, masonry sand and light weight expanded shale; (ii) describe dissolved P removal in small (2.7 m3) subsurface flow wetlands; (iii) quantify the forms of P retained by the substrates in the pilot cells; and (iv) use resulting data to assess the technical and economic feasibility of the most promising system to remove P. The P sorption capacity of masonry sand and expanded shale, as determined with Langmuir isotherms, was 60 mg/kg and 971 mg/kg respectively. In the pilot cells receiving secondarily treated wastewater, cells containing expanded shale retained a greater proportion of the incoming P (50.8 percent) than cells containing masonry sand (14.5 percent). After a year of operation, samples were analyzed for total P (TP) and total inorganic P (TIP). Subsamples were fractionated into labile-P, Fe+Al-bound P, humic-P, Ca+Mg-bound P, and residual-P. Means and standard deviations of TP retained by the expanded shale and masonry sand were 349 + 169 and 11.9 + 18.6 mg/kg respectively. The largest forms of P retained by the expanded shale pilot cells were Fe+Al- bound P (108 mg/kg), followed by labile-P (46.7 mg/kg) and humic-P (39.8). Increases in the P forms of masonry sand were greatest in labile-P (7.5 mg/kg). The cost of an expanded shale wetland is within the range of costs conventional technologies for P removal. Accurate cost comparisons are dependent upon expansion capacity of the system under consideration. Materials with a high P sorption capacity also have potential for enhancing P removal in other constructed wetland applications such as stormwater wetlands and wetlands ...
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Date: August 2002
Creator: Forbes, Margaret G.

Removal of selected water disinfection byproducts, and MTBE in batch and continuous flow systems using alternative sorbents.

Description: A study was conducted to evaluate the sorption characteristics of six disinfection byproducts (DBPs) on four sorbents. To investigate sorption of volatile organic compounds (VOCs), specially designed experimental batch and continuous flow modules were developed. The investigated compounds included: chloroform, 1,2-dichloroethane (DCE), trichloroethylene (TCE), bromodichloromethane (BDCM), methyl tertiary butyl ether (MTBE), bromate and bromide ions. Sorbents used included light weight aggregate (LWA), an inorganic porous material with unique surface characteristics, Amberlite® XAD-16, a weakly basic anion exchange resin, Amberjet®, a strongly basic anion exchange resin, and granular activated carbon (GAC). Batch experiments were conducted on spiked Milli-Q® and lake water matrices. Results indicate considerable sorption of TCE (68.9%), slight sorption of bromate ions (19%) and no appreciable sorption for the other test compounds on LWA. The sorption of TCE increased to 75.3% in experiments utilizing smaller LWA particle size. LWA could be a viable medium for removal of TCE from contaminated surface or groundwater sites. Amberlite® was found unsuitable for use due to its physical characteristics, and its inability to efficiently remove any of the test compounds. Amberjet® showed an excellent ability to remove the inorganic anions (>99%), and BDCM (96.9%) from aqueous solutions but with considerable elevation of pH. Continuous flow experiments evaluated GAC and Amberjet® with spiked Milli-Q® and tap water matrices. The tested organic compounds were sorbed in the order of their hydrophobicity. Slight elevation of pH was observed during continuous flow experiments, making Amberjet® a viable option for removal of BDCM, bromate and bromide ions from water. The continuous flow experiments showed that GAC is an excellent medium for removal of the tested VOCs and bromate ion. Each of the test compounds showed different breakthrough and saturation points. The unique design of the continuous flow apparatus used in the study proved to be highly beneficial to ...
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Date: December 2002
Creator: Kadry, Ahmed Y.

Revisiting Aldo Leopold's "Perfect" Land Health: Conservation and Development in Mexico's Rio Gavilan

Description: The Rio Gavilan watershed, located in Mexico 's northern Sierra Madre Occidental , has significance in conservation history. Upon visiting the remote, largely un­developed watershed during two hunting trips in the 1930s, renowned conservationist Aldo Leopold thought it was the best picture of land health he had seen. His main indicators of healthy land were slow water runoff rates regulating erosion and historical predator-prey relationships. The visits confirmed Leopold's concept of land health, inspired many of his essays, and helped shape his land ethic. Leopold proposed the area as a control site to research healthy land throughout North America . The proposal never went forward and the area has since been more intensively logged and grazed. This dissertation research used extensive literature review, archives, oral histories, citizen surveys, and rapid assessment of forest, rangeland, riparian, and socioeconomic health to assess impacts of past cultures and update the area's land health status. Projects that could restore land health, such as linked eco-tourism, forest density reduction, and rotational grazing, were assessed for feasibility. Recent critiques of Leopold's land ethic were also reviewed. Results indicate most pre-1940s impacts were light, current land health status is moderate, and local interest exists in restoring land health. Many fish and wildlife populations are reduced, temporarily stabilized, but still at risk. Soil and riverbed erosion, service sector economics, and (at some ridge-top sites) forest density are the land health indicators in worst condition. Land health restoration projects are feasible.
Date: December 2004
Creator: Forbes, William

Riparian Forest Width and the Avian Community in a Greenbelt Corridor Setting

Description: The forest avian community of the Ray Roberts Greenbelt (Denton Co., Texas) was characterized for two years using point count station sampling, from fall 1998 to summer 2000. Richness data for both breeding seasons were correlated with two-spatial metrics: width of the riparian forest and distance to the nearest edge. There were significant correlations between forest interior species richness and both spatial metrics, for both breeding seasons. Based on these data, a minimum riparian forest width threshold of 400-meters is suggested to provide habitat for forest interior species, which have lost considerable habitat through forest fragmentation. Partners in Flight breeding bird priority concern scores were used to create a habitat priority index for the Trinity River bottomland hardwood forest system
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Date: May 2001
Creator: Hoffman, Karl W.