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A Classical Theory of the Dielectric Susceptibility of Anharmonic Crystals

Description: An expression for the dielectric susceptibility tensor of a cubic ionic crystal has been derived using the classical Liouville operator. The effect of cubic anharmonic forces is included as a perturbation on the harmonic crystal solution, and a series expansion for the dielectric susceptibility is developed. The most important terms in the series are identified and summed, yielding an expression for the complex susceptibility with an anharmonic contribution which is linearly dependent on temper… more
Date: May 1976
Creator: Kennedy, Howard V.
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L X-Ray Production in the Rare Earths by 0.33-2.66-MeV/amu Carbon- and 0.50-2.25-MeV/amu Oxygen-Ion Bombardment

Description: Experimentally measured L-shell x-ray production cross sections are presented for 8-36-MeV oxygen-ion bombardment of Ce, Pr, Sm, Eu, Dy, and Ho; for 4-32-MeV carbon-ion bombardment of La and Yb; for 6-32-MeV carbon-ion bombardment of Pr, Nd, Sm, and Dy; and for ll-29-MeV carbon-ion bombardment of Ce, Eu, Gd, and Ho. Theoretical predictions via the plane wave Born approximation (PWBA) with corrections for increased binding of target electrons and Coulomb deflection of the incident projectile ten… more
Date: August 1975
Creator: Pepper, George H.
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Collision Broadening in the Microwave Rotational Spectrum of Gaseous Monomeric Formaldehyde

Description: A source-modulation microwave spectrograph was utilized to measure line width parameters for several spectral lines in the pure rotational spectrum of formaldehyde (H₂CO). The spectrograph featured high-gain ac amplification and phase-sensitive detection, and was capable of measuring microwave lines having absorption coefficients as small as 10⁻⁷ cm⁻¹ with a frequency resolution on the order of 30 kHz. Center frequencies of the measured lines varied from 4,830 MHz to 72,838 MHz; hence, most of … more
Date: December 1973
Creator: Rogers, David Valmore
open access

Proton-Induced L-shell X-Rays of Pr, Sm, Eu, Gd, and Dy

Description: Characteristic L-shell x rays of the five rare earths Pr, Sm, Eu, Gd, and Dy were studied in this work. The x rays were produced by ionization from 0.3 to 2.0 MeV protons from the 2.0 MV Van de Graaff at North Texas State University. Total L-shell ionization and x-ray production cross sections were measured for Sm and compared to the BEA, CBEA and PWBA theories. Total L-shell ionization cross sections were measured for Pr, Eu, Gd, and Dy and compared to the BEA, CBEA, and PWBA. The CBEA and PW… more
Date: August 1974
Creator: Abrath, Frederick G.
open access

Effects of Quantum Coherence and Interference

Description: Quantum coherence and interference (QCI) is a phenomenon that takes place in all multi-level atomic systems interacting with multiple lasers. In this work QCI is used to create several interesting effects like lasing without inversion (LWI), controlling group velocity of light to extreme values, controlling the direction of propagation through non-linear phase matching condition and for controlling the correlations in field fluctuations. Controlling group velocity of light is very interesting b… more
Date: August 2013
Creator: Davuluri, Subrahmanya Bhima Sankar
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An Electro- Magneto-static Field for Confinement of Charged Particle Beams and Plasmas

Description: A system is presented that is capable of confining an ion beam or plasma within a region that is essentially free of applied fields. An Artificially Structured Boundary (ASB) produces a spatially periodic set of magnetic field cusps that provides charged particle confinement. Electrostatic plugging of the magnetic field cusps enhances confinement. An ASB that has a small spatial period, compared to the dimensions of a confined plasma, generates electro- magneto-static fields with a short range.… more
Date: May 2014
Creator: Pacheco, Josè L.
open access

The Effects of Residual Gases on the Field Emission Properties of ZnO, GaN, ZnS Nanostructures, and the Effects of Light on the Resistivity of Graphene

Description: In this dissertation, I present that at a vacuum of 3×10-7 Torr, residual O2, CO2, H2 and Ar exposure do not significantly degrade the field emission (FE) properties of ZnO nanorods, but N2 exposure significantly does. I propose that this could be due to the dissociation of N2 into atomic nitrogen species and the reaction of such species with ZnO. I also present the effects of O2, CO2, H2O, N2, H2, and Ar residual gas exposure on the FE properties of GaN and ZnS nanostructure. A brief review of… more
Date: May 2014
Creator: Mo, Yudong
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Synthesis, Characterization, Structural, and Optical Properties of Zinc Oxide Nanostructures Embedded in Silicon Based Substrates

Description: Structural and optical properties of ZnO nanostructures synthesized by low energy ion implantation technique were examined. ZnO molecular ions were implanted into Si/SiO2 substrates at room temperature and then furnace annealed under different temperatures and environments. In all as-implanted samples only Zn nanostructures with varying diameters distributed into the Si/SiO2 matrices were observed. No trace of ZnO was found. The distributions of Zn nanostructures in Si/SiO2 closely matched resu… more
Date: May 2014
Creator: Pandey, Bimal
open access

Synthesis Strategies and a Study of Properties of Narrow and Wide Band Gap Nanowires

Description: Various techniques to synthesize nanowires and nanotubes as a function of growth temperature and time were investigated. These include growth of nanowires by a chemical vapor deposition (CVD) system using vapor-liquid-solid (VLS) growth mechanism and electro-chemical synthesis of nanowires and nanotubes. Narrow band gap InSb Eg = 0.17 eV at room temp) nanowires were successively synthesized. Using a phase diagram, the transition of the nanowire from metallic- semiconducting- semi-metallic phase… more
Date: May 2014
Creator: Sapkota, Gopal
open access

How Cooperative Systems Respond to External Forces

Description: Cooperative interactions permeate through nature, bringing about emergent behavior and complexity. Using a simple cooperative model, I illustrate the mean field dynamics that occur at the critical point of a second order phase transition in the framework of Langevin equations. Through this formalism I discuss the response, both linear and nonlinear, to external forces. Emphasis is placed on how information is transferred from one individual to another in order to facilitate the collective resp… more
Date: May 2014
Creator: Svenkeson, Adam
open access

Novel Semi-Conductor Material Systems: Molecular Beam Epitaxial Growth and Characterization

Description: Semi-conductor industry relies heavily on silicon (Si). However, Si is not a direct-band gap semi-conductor. Consequently, Si does not possess great versatility for multi-functional applications in comparison with the direct band-gap III-V semi-conductors such as GaAs. To bridge this gap, what is ideally required is a semi-conductor material system that is based on silicon, but has significantly greater versatility. While sparsely studied, the semi-conducting silicides material systems offer gr… more
Date: December 2013
Creator: Elmarhoumi, Nader M.
open access

Nonlinear Optical Properties of GaAs at 1.06 micron, picosecond Pulse Investigation and Applications

Description: The author explores absorptive and refractive optical nonlinearities at 1.06 [mu]m in bulk, semi-insulating, undoped GaAs with a particular emphasis on the influence of the native deep-level defect known as EL2. Picosecond pump-probe experimental technique is used to study the speed, magnitude, and origin of the absorptive and refractive optical nonlinearities and to characterize the dynamics of the optical excitation of EL2 in three distinctly different undoped, semi-insulating GaAs samples. I… more
Date: August 1992
Creator: Cui, A.G. (Aiguo G.)
open access

Development and Application of a Nonlinear Optical Characterization Technique

Description: This dissertation reports a sensitive single beam experimental technique for measuring nonlinear refraction and nonlinear absorption in a wide variety of materials. The experimental setup is described and a comprehensive theoretical analysis including cases where nonlinear refraction and nonlinear absorption are also presented.
Date: August 1991
Creator: Said, Ali A. (Ali Ahmad)
open access

Computer Simulations of Mechanical Behavior of Polymer Liquid Crystals

Description: In this dissertation molecular dynamics simulations of behavior of polymer liquid crystals (PLC's) under tensile deformation have been performed. PLC's composed of random or block copolymers of rigid and flexible segments have been studies. Systems of fully flexible chains have been simulated for comparison. Stress-strain relations and fracture mechanics have been investigated.
Date: December 1991
Creator: Blonski, Slawomir
open access

A New Method for Measuring the Nuclear Hexadecapole Interaction in Some Solids

Description: A new method for measuring the nuclear hexadecapole interaction (HDI) in solids based on NMR quadrupole echoes is described. Theoretical values of the shifts of the quadrupole echo times caused by the HDI are given for two pulse and three pulse echoes in a nuclear spin 5/2 system. The method is applied to 1271 in an almost strain free crystal of KI and a hexadecapole coupling frequency (e2M16m16/h) of 630 Hz was found. Here e is the electronic charge, em16 is the fourth gradient of the external… more
Date: August 1991
Creator: Ni, QingWen
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Coherent Resonant Interaction and Harmonic Generation in Atomic Vapors

Description: This work examines the use of higher order multiphoton resonances in higher harmonic generation together with judicious exploitation of coherent interaction properties to achieve efficient harmonic generation. A detailed experimental study on third harmonic generation in two photon resonant coherent interaction and a theoretical study on four photon resonant coherent interaction have been conducted. Two photon resonant coheren propagation in lithium vapor (2S-4S and 2S-3D interaction) has been … more
Date: August 1987
Creator: Mukherjee, Nandini
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Picosecond Measurement of Interband Saturation, Intervalence Band Absorption, and Surface Recombination in Germanium

Description: The picosecond optical response of five thin germanium samples was measured following intense optical excitation using two variations of the excitation and probe technique. Seven-picosecond laser pulses of wavelength 1.054 um were used to measure the optical transmission of the samples for a variety of probe delays, excitation fluences, and sample temperatures. These parametric experiments were performed in an effort to determine if carrier cooling, carrier diffusion, or carrier recombination d… more
Date: August 1984
Creator: Perryman, Gary Paul
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Carbon K-Shell X-Ray and Auger-Electron Cross Sections and Fluorescence Yields for Selected Molecular Gases by 0.6 To 2 .0 MeV Proton Impact

Description: Absolute K-shell x-ray cross sections and Auger-electron cross sections are measured for carbon for 0.6 to 2.0 MeV proton incident on CH₄, n-C₄H₁₀ (n-Butane), i-C₄H₁₀ (isobutane), C₆H₆ (Benzene), C₂H₂ (Acetylene), CO and CO₂. Carbon K-shell fluorescence yields are calculated from the measurements of x-ray and Auger-electron cross sections. X-ray cross sections are measured using a variable geometry end window proportional counter. An alternate method is described for the measurement of the tran… more
Date: August 1986
Creator: Bhalla, Raj P. (Raj Pal), 1948
open access

Optical Nonlinearities in Semiconductors for Limiting

Description: I have conducted detailed experimental and theoretical studies of the nonlinear optical properties of semiconductor materials useful for optical limiting. I have constructed optical limiters utilizing two-photon absorption along with photogenerated carrier defocusing as well as the bound electronic nonlinearity using the semiconducting material ZnSe. I have optimized the focusing geometry to achieve a large dynamic range while maintaining a low limiting energy for the device. The ZnSe monolithi… more
Date: May 1990
Creator: Wu, Yuan-Yen
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Microwave Spectra of ¹³C Isotopic Species of Methyl Cyanide in the Ground, v₈=1 and v₈=2 Vibrational States

Description: The problem of the quadrupole interaction occurring in a vibrating-rotating C₃v symmetric top molecule has been studied in detail. The quadrupole interaction has been treated as another perturbation term to a general frequency expression accounting for the vibrating-rotating interaction of the molecule so that a complete frequency formula is obtained for both interactions, and from which hyperfine spectral components are predicted and measured. The hyperfine transitions in the ground, and v₈=1 … more
Date: May 1988
Creator: Tam, Hungsze
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A Comprehensive Model for the Rotational Spectra of Propyne CH₃CCH in the Ground and V₁₀=1,2,3,4,5 Vibrational States

Description: The energy states of C₃ᵥ symmetric top polyatomic molecules were studied. Both classical and quantum mechanical methods have been used to introduce the energy states of polyatomic molecules. Also, it is shown that the vibration-rotation spectra of polyatomic molecules in the ground and excited vibrational states can be predicted by group theory. A comprehensive model for predicting rotational frequency components in various v₁₀ vibrational levels of propyne was developed by using perturbation t… more
Date: December 1986
Creator: Rhee, Won Myung
open access

The Rotational Spectra of Propyne in the Ground, V₁₀=1, V₁₀=2, and V₉=1 Vibrational States

Description: The problem of a vibrating-rotating polyatomic molecule is treated, with emphasis given to the case of molecules with C_3v symmetry. It is shown that several of the gross features of the rotational spectra of polyatomic molecules in excited vibrational states can be predicted by group theoretical considerations. Expressions for the rotational transition frequencies of molecules of C_3v symmetry in the ground vibrational state, singly excited degenerate vibrational states, and doubly excited deg… more
Date: August 1985
Creator: Ware, John Matthew
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Infrared-Microwave Double Resonance Probing of the Population-Depopulation of Rotational States in the NO₂ and the SO₂ Molecules

Description: A 10.6 ym C02 laser operating a power range S P 200 watts was used to pump some select vibrational transitions in the NO2 molecule while monitoring the rotational transitions (91/9—'100/10), (232f 22 ~~"*242,23> ' (402,38 "393,37) in the (0, 0, 0) vibrational level and the (8q,8—*"^1,7) rotational transition in the (0, 1, 0) vibrational level. These rotational transitions were monitored by microwave probing to determine how the population of states in the rotational manifolds were being altered… more
Date: December 1982
Creator: Khoobehi, Bahram
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