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Corrosion Protection of Low Carbon Steel By Cation Substituted Magnetite

Description: Surfaces of low carbon steel sheet were modified by exposure to highly caustic aqueous solutions containing either chromium or aluminum cations. Corrosion resistances of such surfaces were compared with that of steel surfaces exposed to plain caustic aqueous solution. In all cases a highly uniform, black coating having a spinel structure similar to magnetite (Fe3O4) was obtained. The coated steel surfaces were characterized using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and Fourier transform infrared spectrophotometry (FTIR). Polarization resistances (Rp) of modified steel surfaces were measured and compared with that of bare steel surfaces. Results indicate that chromium (Fe2+ Fe3+x Cr3+1-x) or aluminum (Fe2+ Fe3+x Al3+1-x) substituted spinel phases formed on steel surfaces showed higher Rp values compared to only magnetite (Fe2+ 2Fe3+O4) phase formed in the absence of either chromium or aluminum cations. Average Rp values for steel surfaces with chromium containing spinel phase were much higher (21.8 k?) as compared to 1.7 k? for bare steel surfaces. Steel surfaces with aluminum containing spinel phase and steels with plain magnetite coated samples showed average Rp values of 3.3 k? and 2.5 k? respectively. XPS and EDS analysis confirmed presence of cations of chromium and aluminum in Fe3O4 in cation substituted samples. FTIR results showed all coating phases were of spinel form with major absorption bands centered at either 570 cm-1 or 600 cm-1 assigned to Fe3O4 and ?-Fe2O3 respectively.
Date: May 2013
Creator: Phadnis, Ameya

Ota-quadrotor: An Object-tracking Autonomous Quadrotor for Real-time Detection and Recognition

Description: The field of robotics and mechatronics is advancing at an ever-increasing rate and we are starting to see robots making the transition from the factories to the workplace and homes as cost is reduced and they become more useful. In recent years quadrotors have become a popular unmanned air vehicle (UAV) platform. These UAVs or micro air vehicles (MAV) are being used for many new and exciting applications such as aerial monitoring of wildlife, disaster sites, riots and protests. They are also being used in the film industry, as they are significantly cheaper means of getting aerial footage. While quadrotors are not extremely expensive a good system can cost in the range of $3000 - $8000 and thus too costly as a research platform for many. There are a number of cheaper open source platforms. The ArduCopter is under constant development, has the largest community and is inexpensive making it an ideal platform to work with. The goal of this thesis was to implement video processing on a ground control station allowing for the ArduCopter to track moving objects. This was achieved by using the OpenCV video-processing library to implement object tracking and the MAVLink communication protocol, available on the ArduCopter platform, for communication.
Date: May 2012
Creator: Coelho, Gavin