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Base Effects on the Thermal Decomposition of Sec-butyllithium Solutions

Description: The pyrolysis of sec-butyllithium in solution was studied in an attempt to understand the loss of stereo-specificity and the atypical kinetics that have been reported. Additionally, the effect of added lithium alkoxides was studied to determine their effects on the highly reactive sec-butyllithium substrate.
Date: June 1966
Creator: Adams, George Michael
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Naphth [2,3-d] Imidazoline-2,4,9-Triones

Description: The study of some acylurea derivatives of 2-amino-3-alkylamino- and -3-arylamino-1,4-naphthoquinones was undertaken to determine the course of reaction under conditions similar to those used by J. R. Hoover and A. R. Day to prepare 2-alkyl-1H-naphth[2,3-d] imidazole-4.9-diones from 2-acylamino-3-amino-1,4-naphthoquinones.
Date: August 1966
Creator: Witkowski, Joseph T.
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Organomagnesium Compounds in Benzene Solvent and Their Application in Synthesis of Organoberyllium Compounds

Description: The work reported by D. Bryce-Smith and G. F. Cox, along with several recent publications describing experimental results designed to elucidate the long disputed question of the structure of the Grignard reagent in ether stimulated the work reported here, in an effort to obtain additional evidence of the structure of the organomagnesium complex in benzene solvent. Since the primary objective of this work was to prepare organoberyllium compounds using the organomagnesium complexes in hydrocarbon… more
Date: January 1966
Creator: Selman, Charles M.
open access

Synthesis of Selected 2-imidazolines

Description: Since Djerassi and Scholz found that 2-(aryloxy-methyl)imidazolines and their hydrochloride salts exhibit vasoconstrictive properties, the 1,2-(I) 1,3-(II) and 1,4-bis-(2-imidazolinylmethoxy) benzene (III) analogs (Fig. 1, p.2) were chosen for synthesis in order to test them for their effective vasoconstrictive characteristics and for whatever other physiological properties they might exhibit.
Date: June 1966
Creator: Maurer, Larry Eugene
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