Studies of spin alignment in ferrocenylsilane compounds and in regiospecific oxidation reactions of 1,9-dimethylpentacyclo [5.4.0.02,6.03,10.05,9]undecane-8,11-dione.
Description:
Part I. The syntheses of a series of stable ferrocenylsilane compounds and their corresponding polyradical cations are reported. Electron spin properties of these molecules were investigated by cyclic voltammetry, ESR, and magnetic susceptibility measurements. All the compounds presented, showed significant electronic communication (>100 mV) between the redox centers by CV.
Part II. Baeyer-Villiger oxidation of (1,9-dimethyl-PCU-8,11-dione) was performed using m-chloroperoxybenzoic acid i…
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Date:
August 2006
Creator:
Atim, Silvia