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Ab Initio and Density Functional Investigation of the Conformer Manifold of Melatonin and a Proposal for a Simple Dft-based Diagnostic for Nondynamical Correlation
In this work we address two problems in computational chemistry relevant to biomolecular modeling. In the first project, we consider the conformer space of melatonin as a a representative example of “real-life” flexible biomolecules. Geometries for all 52 unique conformers are optimized using spin-component scaled MP2, and then relative energies are obtained at the CCSD (T) level near the complete basis set limit. These are then used to validate a variety of DFT methods with and without empirical dispersion corrections, as well as some lower-level ab initio methods. Basis set convergence is found to be relatively slow due to internal C-H…O and C-H…N contacts. Absent dispersion corrections, many DFT functionals will transpose the two lowest conformers. Dispersion corrections resolve the problem for most functionals. Double hybrids yield particularly good performance, as does MP2.5. In the second project, we propose a simple DFT-based diagnostic for nondynamical correlation effects. Aλ= (1-TAE [ΧλC]/TAE[XC])/λ where TAE is the total atomization energy, XC the “pure” DFT exchange-correlation functional, and ΧλC the corresponding hybrid with 100λ% HF-type exchange. The diagnostic is a good predictor for sensitivity of energetics to the level of theory, unlike most of the wavefunction-based diagnostics. For GGA functionals, Aλ values approaching unity indicate severe non-dynamical correlation. The diagnostic is only weakly sensitive to the basis set (beyond polarized double zeta) and can be applied to problems beyond practical reach of wavefunction ab-initio methods required for other diagnostics.
The Academic Steroid: Nonmedical Use of Prescription Stimulants at a North Texas University
The goal of this study was to determine the extent, motivations, and justifications of nonmedical prescription stimulant use among the population at a large public university in the North Texas region. Participants consisted of 526 undergraduate students enrolled at the studied university during the spring and summer 2014 semesters. The findings of the study suggest that the nonmedical use by students was higher than the findings in much of the current literature, but was within the parameters established in the literature. The primary motivation for nonmedical use was academic in nature and was justified by moderation of nonmedical use to strategic academic times.
Accelerated Corrosion Test with Operation Simulation of All-Aluminum Microchannel Heat Exchangers
The HVAC&R industry is looking to transition from copper-aluminum heat exchangers to all-aluminum microchannel technology. The want for the transition stemmed from seeing the performance improvement of all-aluminum microchannel radiators in the automotive industry. Applications differ between the two industries; therefore, applying this technology for HVAC&R use must be validated. Research towards operating modes of an all-aluminum heat exchanger in a defined corrosive environment will provide the industry with a better understanding of heat exchanger design and heat exchanger material selection. The worth in this is preventing overdesign and producing more efficient heat exchangers. Furthermore, ASHRAE members and the corrosion community will find value in a defined corrosion system and corrosion test procedure. The information gained through past research has progressed assessment of material performance; however, the methods improperly simulate and expedite natural weathering. The most common method being used is the ASTM (American Society of Testing Materials) Sea Water Acetic Acid Test. The research discussed in this paper was focused on improving a standard corrosion system by implementing system modifications to simulate heat exchanger operation while performing a modified wet-dry cyclic test (e.g. ASTM G85 Annex 5). The goal is to produce results that are more representative of natural corrosion behavior and its forms. Current results were gathered from five of ten samples that underwent initial testing. Finally, possible improvements towards the chamber system and the test method, including the salt solution, are discussed.
Accuracy of Self-Reported Height, Weight, and Calculated BMI and Resulting FITNESSGRAM® Healthy Fitness Zone Classification
The determination of adiposity in adolescents is often assessed with calculations of body mass indices (BMI). Researchers often obtain these measurements from self-reported (SR) values. The purpose of this study was to determine the accuracy of SR height, weight, and calculated BMI (from height and weight). SR and actual measured (ME) BMI values were compared with standards from the FITNESSGRAM® Healthy Fitness Zone (HFZ) classifications. SR height and calculated BMI were found to be accurate while SR weight was, on average, underreported by 4.77 lbs. Because of these errors in SR height and weight, accuracy of classification into the FITNESSGRAM® HFZ was compromised. Consequently, it is important that researchers ascertain actual values of height and weight when measuring adolescents rather than use those from self-reports.
Accuracy Variations in Human Facial Identification Based on Time of Exposure.
This study examined the relationship between time of exposure to the human face and accurate subsequent photo line-up identification. A volunteer group of 124 undergraduate students was divided into three approximately equal sized subgroups. The three groups were then exposed to a video or a portion of a video depicting a theft. Exposure times ranged from two minutes to 30 seconds. The subjects were then given a questionnaire and shown a photo line-up of the mock perpetrator and five foils. Subjects were asked to identify the perpetrator and mark that identification on the questionnaire. Results of the experiment indicated that the longer a subject was exposed the greater the possibility of an accurate identification.
Acute Effects of the Antibiotic Streptomycin on Neural Network Activity and Pharmacological Responses
The purpose of this study is to find out that if antibiotic streptomycin decreases neuronal network activity or affects the pharmacological responses. The experiments in this study were conducted via MEA (multi-electrode array) technology which records neuronal activity from devices that have multiple small electrodes, serve as neural interfaces connecting neurons to electronic circuitry. The result of this study shows that streptomycin lowered the spike production of neuronal network, and also, sensitization was seen when neuronal network pre-exposed to streptomycin.
Adhesion and Surface Energy Profiles of Large-area Atomic Layers of Two-dimensional MoS2 on Rigid Substrates by Facile Methods
Two-dimensional (2D) transition metal dichalcogenides (TMDs) show great potential for the future electronics, optoelectronics and energy applications. But, the studies unveiling their interactions with the host substrates are sparse and limits their practical use for real device applications. We report the facile nano-scratch method to determine the adhesion energy of the wafer scale MoS2 atomic layers attached to the SiO2/Si and sapphire substrates. The practical adhesion energy of monolayer MoS2 on the SiO2/Si substrate is 7.78 J/m2. The practical adhesion energy was found to be an increasing function of the MoS2 thickness. Unlike SiO2/Si substrates, MoS2 films grown on the sapphire possess higher bonding energy, which is attributed to the defect-free growth and less number of grain boundaries, as well as less stress and strain stored at the interface owing to the similarity of Thermal Expansion Coefficient (TEC) between MoS2 films and sapphire substrate. Furthermore, we calculated the surface free energy of 2D MoS2 by the facile contact angle measurements and Neumann model fitting. A surface free energy ~85.3 mJ/m2 in few layers thick MoS2 manifests the hydrophilic nature of 2D MoS2. The high surface energy of MoS2 helps explain the good bonding strength at MoS2/substrate interface. This simple adhesion energy and surface energy measurement methodology could further apply to other TMDs for their widespread use.
Adolescent Insomnia as a Predictor of Early Adulthood Outcomes
Recent research found insomnia is a risk factor for psychiatric disorders in adults. To see if the same would be true in adolescents, the current study re-analyzed data from a national longitudinal study collected by ADDHealth that evaluated health behaviors in 4552 adolescents (mean age 14.9 years [SD 1.7]) at baseline and again 7-8 years later (n = 3489) during young adulthood. Insomnia was reported by 9.2% of the adolescents. Cross-sectionally, adolescent insomnia was associated with alcohol, cannabis, non-cannabis drugs, and tobacco use, and depression after controlling for gender and ethnicity. Prospectively, adolescent insomnia was a significant risk factor for depression diagnosis, suicidal ideation, and the use of depression and stress prescription medications in young adulthood after controlling for gender, ethnicity, and significant baseline variable. In addition, a trend was noted for suicidal attempts.
An Analysis of Major American Riots: Issues in Riots and Riot Control
By conducting sound research to understand the concepts surrounding rioting and efficient riot response tactics, professionals, especially whose main job is to ensure the tranquility in the society, will be better prepared to deal with all kinds of civil movements. The purpose of this study, consequently, is to meet the growing need for educational materials in this area and to provide riot response case studies, which demonstrate the numerous administrative challenges faced by law enforcement decision makers. In this study, seven major riots from throughout the United States are discussed including the Hay Market Riot of 1886, the Watts Riot of 1965, and Los Angeles Riots of 1992. Each riot case is studied in five different and independent stages: the setting and pre-disturbance situation, basic causes of the event, the disturbance situation, the response to the riot, and the aftermath of the incident. The study of all of these stages is intended to help police administrators acquire a general perspective on collective violence, and help them prevent future occurrences in their jurisdictions. In this thesis a special reference is given to the deficiencies of American riot policing and some recommendations were formed accordingly. Therefore, the study concludes with a list of general recommendations, which are crucially important for concerned officials to pay attention before, during, and after a riot.
An Analysis of Motivational Cues in Virtual Environments.
Guiding navigation in virtual environments (VEs) is a challenging task. A key issue in the navigation of a virtual environment is to be able to strike a balance between the user's need to explore the environment freely and the designer's need to ensure that the user experiences all the important events in the VE. This thesis reports on a study aimed at comparing the effectiveness of various navigation cues that are used to motivate users towards a specific target location. The results of this study indicate some significant differences in how users responded to the various cues.
An Analysis of the Composition Process of Bartók's Eight Improvisations on Hungarian Peasant Songs, Op. 20
This is a study of Bartók's compositional process as it relates to the Improvisations, Op. 20. The study, which focuses on the analysis of the draft manuscript 50PS1, compares the draft and other relevant sources with the final composition. Bartók's framework for the entire Improvisations is based on a compositional strategy of pairing individual improvisations combined with systematic revision of the draft copy by the introduction of tritones as tonal equivalents and movement by fifths from semitones, to achieve structural coherence in the individual improvisations. The tonic-dominant relationship is used to rearrange the individual improvisations in the draft and tritones as tonal equivalents are used to propel the movement between the improvisations to produce a coherent whole.
Anchor Nodes Placement for Effective Passive Localization
Wireless sensor networks are composed of sensor nodes, which can monitor an environment and observe events of interest. These networks are applied in various fields including but not limited to environmental, industrial and habitat monitoring. In many applications, the exact location of the sensor nodes is unknown after deployment. Localization is a process used to find sensor node's positional coordinates, which is vital information. The localization is generally assisted by anchor nodes that are also sensor nodes but with known locations. Anchor nodes generally are expensive and need to be optimally placed for effective localization. Passive localization is one of the localization techniques where the sensor nodes silently listen to the global events like thunder sounds, seismic waves, lighting, etc. According to previous studies, the ideal location to place anchor nodes was on the perimeter of the sensor network. This may not be the case in passive localization, since the function of anchor nodes here is different than the anchor nodes used in other localization systems. I do extensive studies on positioning anchor nodes for effective localization. Several simulations are run in dense and sparse networks for proper positioning of anchor nodes. I show that, for effective passive localization, the optimal placement of the anchor nodes is at the center of the network in such a way that no three anchor nodes share linearity. The more the non-linearity, the better the localization. The localization for our network design proves better when I place anchor nodes at right angles.
'...and one of time.': A Composition for Full Orchestra with Narration
‘...and one of time.' is a reinterpretation of a small musical moment from Philip Glass' opera, Einstein on the Beach, centered around the phrase "Berne, Switzerland 1905." This reinterpretation is realized through the use of several different compositional techniques including spectral composition, micropolyphony and dodecaphony, as well as the application of extra-musical models developed by Alan Lightman, John Gardner, Italo Calvino and Albert Einstein.
Angular Analysis of a Wide-Band Energy Harvester based on Mutually Perpendicular Vibrating Piezoelectric Beams
The recent advancements in electronics and the advents of small scaled instruments has increased the attachment of life and functionality of devices to electrical power sources but at the same time granted the engineers and companies the ability to use smaller sources of power and batteries. Therefore, many scientists have tried to come up with new solutions for a power alternatives. Piezoelectric is a promising material which can readily produce continuous electric power from mechanical inputs. However, their power output is dependent upon several factors such as, system natural frequency, their position in the system, the direction of vibration and many other internal and external factors. In this research the working bandwidth of the system is increased through utilizing of two different piezoelectric beam in different directions. The dependency of output power with respect to rotation angle and also the frequency shift due to the rotation angle is studied.
“The Angular Degrees of Freedom” and Other Stories
The preface, " Performing Brain Surgery: The Problematic Nature of Endings in Short Fiction," deals with the many and varied difficulties short story writers encounter when attempting to craft endings. Beginning with Raymond Carver and Flannery O’Connor and moving to my own work, I discuss some of the obscure criteria used to designate a successful ending, as well as the more concrete idea of the ending as a unifying element. Five short stories make up the remainder of this thesis: "In-between Girls," "Crocodile Man," "Surprising Things, Sometimes Amusing," "Good Jewelry," and "The Angular Degrees of Freedom."
Animals That Die
The thesis has two parts. Part I is a critical essay entitled "Lessons Under the Amfalula." Part II is the collection of poems entitled "Animals That Die."
The Apologist Tradition: A Transitional Period in Southern Proslavery Thought, 1831-1845
Early antebellum defenders of slavery acknowledged that slavery created problems for southern society. They contended, however, that slave society was better and more natural than other forms of social organization. Thomas R. Dew, William Harper, and James Henry Hammond each expressed a social philosophy in which slavery had a crucial role in preserving social order. They argued from the basis of social organicism, the idea that society should have an elite that controlled the masses. For all three men, slavery represented a system of order that helped balance the dangers of democracy. Significantly, however, all three men recognized that the slave system was not perfect, and despite their defense of slavery, argued that it was a human institution and therefore corruptible.
The Application of a Health Service Utilization Model to a Low Income, Ethnically Diverse Sample of Women
A model for health care utilization was applied to a sample of low income women. Demographic Predisposing, Psychosocial Predisposing, Illness Level, and Enabling indicators were examined separately for African American (n = 266), Anglo American (n = 200), and Mexican American (n = 210) women. Structural Equation Modeling revealed that for African American and Anglo American women, Illness Level, the only significant path to Utilization, had a mediating effect on Psychosocial Predisposing indicators. The model for Mexican Americans was the most complex with Enabling indicators affecting Illness Level and Utilization. Psychosocial Predisposing indicators were mediated by Illness Level and Enabling indicators which both directly affected Utilization. Implications of the results for future research are addressed.
Application of Cyclic Polarization of Aluminum 3003 Used in All-Aluminum Microchannel Heat Exchangers
All-aluminum microchannel heat exchangers are designed to significantly reduce refrigerant charge requirements, weight, reduced brazed joints, and decreased potential for leakage by increasing reliability. Al 3003 alloy is corrosion resistant and can be formed, welded, and brazed but the issue with all-aluminum heat exchangers is localized corrosion (pitting) in corrosive environments. Currently, there is no universally accepted corrosion test that all coil manufacturers use to characterize their products. Electrochemical testing method of cyclic polarization was employed in this investigation and relevant parameters including electrolyte corrosive agent and its concentration, electrolyte pH, and applied potential scan rate was varied to find an optimal set of parameters. Results of cyclic polarization of Al 3003 in electrolytes containing various concentrations of NaCl were compared with those of the tests in Sea Water Acidified Accelerated Test (SWAAT) electrolyte and it is shown the SWAAT electrolyte (4.2% sea salt acidified to pH of 2.9) is by far stronger (in terms of corrosivity) than typical 3.5% NaCl solution used in most corrosion testing. Corrosion rates (g/m2yr) of Al 3003 measured in this investigation were comparable to those provided by ISO 9223 standard corresponding to C1 through CX categories. Duration of cyclic polarization test is much shorter than that of SWAAT and results obtained in this test is more reproducible compared to those of SWAAT. Scanning electron microscopy micrographs show typical pit depths of about 50 μm.
Application of Thermomechanical Characterization Techniques to Bismuth Telluride Based Thermoelectric Materials
The thermoelectric properties of bismuth telluride based thermoelectric (TE) materials are well-characterized, but comparatively little has been published on the thermomechanical properties. In this paper, dynamic mechanical analysis (DMA) and differential scanning calorimetry data for bismuth telluride based TE materials is presented. The TE materials' tan delta values, indicative of viscoelastic energy dissipation modes, approached that of glassy or crystalline polymers, were greater than ten times the tan delta of structural metals, and reflected the anisotropic nature of TE materials. DMA thermal scans showed changes in mechanical properties versus temperature with clear hysteresis effects. These results showed that the application of DMA techniques are useful for evaluation of thermophysical and thermomechanical properties of these TE materials.
Art Criticism and the Gendering of Lee Bontecou's Art, ca. 1959 - 1964
This thesis identifies and analyzes gendering in the art writing devoted to Lee Bontecou's metal and canvas sculptures made from the 1959 - 1964. Through a careful reading of reviews and articles written about Bontecou's constructions, this thesis reconstructs the context of the art world in the United States at mid-century and investigates how cultural expectations regarding gender directed the reception of Bontecou's art, beginning in 1959 and continuing through mid-1960s. Incorporating a description of the contemporaneous cultural context with description of the constructions and an analysis of examples of primary writing, the thesis chronologically follows the evolution of a tendency in art writing to associate gender-specific motivation and interpretation to one recurring feature of Bontecou's works.
Asserting Identity in Wagner's Shadow: The Case of Engelbert Humperdinck's Königskinder (1897)
Engelbert Humperdinck (1854-1921), who was considered a Wagnerian due to to his past work in Bayreuth and the Wagnerian traits of his Hänsel und Gretel, seems to have believed that to define himself as a composer, he had to engage somehow with that designation, whether through orthodox Wagner imitation or an assertion of his independence from Wagner's musical legacy. The latter kind of engagement can be seen in Humperdinck's Königskinder (1897), in which he developed a new kind of declamatory notation within the context of melodrama, thus fulfilling Wagnerian ideals as well as progressing beyond them. The effectiveness of Humperdinck's effort is seen in the ensuing critical reception, in which the realities of being heard as a Wagnerian composer are clarified.
Assessing Optimal Sibling Training Conditions: An Empirical Approach.
The purpose of the study was to investigate the effects of play materials on the interactions between a child with autism and her sibling. Three conditions were assessed: open choice, materials chosen by the child with autism, and materials chosen by the typically developing sibling. Within each activity, measures of social interactions were assessed. Results of the assessment showed that more interactions occurred with a material chosen by the child with autism. After sibling training (targeting specific teaching skills), social interactions remained highest in the condition with materials chosen by the child with autism. The results are discussed in terms of a material assessment to optimize sibling training conditions and the importance of sibling relationships.
Assessing the Potential Effects of Climate Variability on Reservoir Water Volume in North-Central Texas Using GIS and Models: A Case Study of Ray Roberts Lake.
Assessing the impact of climate variability on water resources is one of the difficult tasks in planning the future growth of North-Central Texas. This study defined twelve extreme climate scenarios. Data from each scenario was input to a hydrological model (HEC-HMS) to calculate watershed runoff to Lake Ray Roberts. Model parameters are determined using Geographic Information System (GIS). The water balance was calculated for current and future water demand and resulting change in the volume and level of this reservoir. The results indicate certain climate scenarios decrease in volume. Thus, local governments should plan alternative water management strategies during droughts.
Automated Defense Against Worm Propagation.
Worms have caused significant destruction over the last few years. Network security elements such as firewalls, IDS, etc have been ineffective against worms. Some worms are so fast that a manual intervention is not possible. This brings in the need for a stronger security architecture which can automatically react to stop worm propagation. The method has to be signature independent so that it can stop new worms. In this thesis, an automated defense system (ADS) is developed to automate defense against worms and contain the worm to a level where manual intervention is possible. This is accomplished with a two level architecture with feedback at each level. The inner loop is based on control system theory and uses the properties of PID (proportional, integral and differential controller). The outer loop works at the network level and stops the worm to reach its spread saturation point. In our lab setup, we verified that with only inner loop active the worm was delayed, and with both loops active we were able to restrict the propagation to 10% of the targeted hosts. One concern for deployment of a worm containment mechanism was degradation of throughput for legitimate traffic. We found that with proper intelligent algorithm we can minimize the degradation to an acceptable level.
Baeyer-Villiger Oxidation of 1,7- & 1,9-dibromopentacyclo[,6.03,10.05,9]undecane-8,11-dione
Baeyer-Villiger oxidation of 1,9-dibromopentacyclo[,6.03,10.05,9]undecane-8,11-dione (1,9-dibromo-PCU-8,11-dione) was performed by using an excess amount of m-chloroperbenzoic acid (3 equivalents) and resulted in the formation of the corresponding monolactone. The reaction would not proceed to the dilactone stage. The structure of the reaction product was established unequivocally via single crystal X-ray diffraction. Baeyer-Villiger oxidation of 1,9-dibromo-PCU-8,11-dione using ceric ammonium nitrate (CAN) was also performed and afforded a mixture of lactones. Only one of these lactones, which also contained an alkene functionality, could be isolated and characterized. 1,7-dibromo-PCU-8,11-dione was also reacted with CAN, yielding the mono-lactone, which has also been characterized.
Barriers Limiting Access to Hospice Care for Elderly African Americans in Amarillo, Texas
This study examines barriers limiting access to hospice care for elderly African Americans. Ethnic background plays a critical role in the development of attitudes, beliefs and expectations related to death and issues surrounding hospice care. The purpose of this study was to identify barriers that may limit access to hospice care for African Americans. A questionnaire was administered to 56 elderly African Americans in three religious settings and an African American senior citizens center. The questionnaire was designed to obtain information concerning African Americans' attitudes toward death and dying; religious beliefs; health beliefs; familiarity with hospice and prospective use of hospice. The results of the study indicate a number of barriers in access to hospice care for African Americans including: hospice knowledge barriers; education/outreach barriers; cultural knowledge barriers related to death/dying values; family/social support barriers; hospice organizational/provider barriers; health care organizational/provider barriers; and reimbursement barriers.
"The Barroom Girls" and Other Stories
This creative thesis is comprised of five original short stories and a critical preface. The preface discusses the changing cultural, sociopolitical, and socioeconomic landscape of the modern American South and the effects-positive, negative, and neutral-these changes have had on the region's contemporary literature, including the short stories contained within.
Between the Waves: Truth-Telling, Feminism, and Silence in the Modernist Era Poetics of Laura Riding Jackson and Muriel Rukeyser
This paper presents the lives and early feminist works of two modernist era poets, Laura Riding Jackson and Muriel Rukeyser. Despite differences of style, the two poets shared a common theme of essentialist feminism before its popularization by 1950s and 60s second wave feminists. The two poets also endured periods of poetic silence or self censorship which can be attributed to modernism, McCarthyism, and rising conservatism. Analysis of their poems helps to remedy their exclusion from the common canon.
Bioinspired and biocompatible coatings of poly(butylene adipate-co-terephthalate) and layer double hydroxide composites for corrosion resistance
Hierarchical arrangement of biological composites such as nacre and bone containing high filler (ceramic) content results in high strength and toughness of the natural material. In this study we mimic the design of layered bone microstructure and fabricate an optimal multifunctional bio-nanocomposite having strength, toughness and corrosion resistance. Poly (butylene adipate-co-terephthalate) (PBAT), a biodegradable polymer was used as a substrate material with the reinforcement of LDH (Layered double hydroxide) as a nanofiller in different concentrations to achieve enhancement in mechanical properties as well as processing related thermostability. Corrosion resistance was increased by mimicking a layered structured which incorporated a tortuous diffusion path.
Bird Bones and a Hatched Egg
A fifty page manuscript of poetry and a critical introduction detailing the poet's aesthetics. Using the idea of the double-image and eroticism, the poet places her work in the category of the surreal. She describes the process of writing poetry born of fragmentary elements as a feminist emergence of agency. The manuscript is composed of four sections, each an element in the inevitable breakdown of a love relationship: meeting, love-making, birth of a child, death. Quotes from various authors of anthropological and fictional texts begin each section to reinforce thematic structure in a process of unveiling the agency of the narrator. The poems are organized as a series, beginning and ending with sequence poems.
Bounded Dynamic Source Routing in Mobile Ad Hoc Networks
A mobile ad hoc network (MANET) is a collection of mobile platforms or nodes that come together to form a network capable of communicating with each other, without the help of a central controller. To avail the maximum potential of a MANET, it is of great importance to devise a routing scheme, which will optimize upon the performance of a MANET, given the high rate of random mobility of the nodes. In a MANET individual nodes perform the routing functions like route discovery, route maintenance and delivery of packets from one node to the other. Existing routing protocols flood the network with broadcasts of route discovery messages, while attempting to establish a route. This characteristic is instrumental in deteriorating the performance of a MANET, as resource overhead triggered by broadcasts is directly proportional to the size of the network. Bounded-dynamic source routing (B-DSR), is proposed to curb this multitude of superfluous broadcasts, thus enabling to reserve valuable resources like bandwidth and battery power. B-DSR establishes a bounded region in the network, only within which, transmissions of route discovery messages are processed and validated for establishing a route. All route discovery messages reaching outside of this bounded region are dropped, thus preventing the network from being flooded. In addition B-DSR also guarantees loop-free routing and is robust for a rapid recovery when routes in the network change.
The Break-up of the Confederate Trans-Mississippi Army, 1865
Unlike other Confederate armies at the conclusion of the Civil War, General Edmund Kirby Smith's Trans-Mississippi Army disbanded, often without orders, rather than surrender formally. Despite entreaties from military and civilian leaders to fight on, for Confederate soldiers west of the Mississippi River, the surrender of armies led by Generals Robert E. Lee and Joseph E. Johnston ended the war. After a significant decline in morale and discipline throughout the spring of 1865, soldiers of the Confederate Trans-Mississippi Department chose to break-up and return home. As compensation for months of unpaid service, soldiers seized both public and private property. Civilians joined the soldiers to create disorder that swept many Texas communities until the arrival of Federal troops in late June.
Breaking Through: A Composition for Symphony Orchestra
Breaking Through is a single-movement composition for symphony orchestra based on a fourteen-note melody. Every harmonic and melodic figure except the bass line is derived from this source melody. The structure of the work is based on a number of musical dichotomies that work on both local and large-scale levels. The local dichotomies contrast consonance with dissonance and ambiguity with clarity (in respect to texture and rhythm). The dichotomy of two-part form versus three-part form and the dichotomy of simplicity versus complexity operate on the large scale. The unity lended by the single source melody coupled with the contrasts furnished by the aforementioned dichotomies allow Breaking Through to be both coherent and interesting.
Burn and Sow: The Ethical Implications of Ecological Restoration
Ecological restoration is quickly becoming a major approach to how humans interact with the natural world. Some view restoration as another land management technique on par with conservation and preservation. Others view it as a way to make reparations for our misdeeds and to reincorporate humans into the natural world. Ideas regarding restoration from key academics and restorationists are evaluated here. Their views have set the stage for the contemporary paradigm. Values that may be attributed to restoration and received from it are evaluated. I discuss my own reservations regarding potential problems with the product and practice of restoration. What is at stake regarding the involvement of people in restoration is examined, focusing on the different impacts volunteers and paid workers have on the value of the practice and outcome of the product.
Can Observing Behavior Predict Performance in Conditional Discriminations?
Prompts are implemented often in training procedures, to include conditional discriminations, and this can lead to prompt dependency. The current study extends a prior study that suggested that the effectiveness of supplementary visual stimuli displaying the sample and comparison was dependent on the timing in relation to the selection task, presented as a prompt or feedback, in a match-to-sample procedure. The current research examines if the differences in that effectiveness were due to differences in observing behavior in those two conditions. Measures of observing behavior were determined by making access to the individual visual stimuli contingent on clicking on the visual stimulus and keeping the cursor located on the stimulus. Participants viewed the sample comparison much less than the comparison stimulus in both the prompt and feedback conditions. Latency to select the comparison stimulus was much shorter for the prompt condition suggesting that the participants might have interacted differently with the selection task in the two conditions.
A Case Study of Leftist Terrorism in Turkey
Change in government has characterized the development of most nations. Sometimes this change has been marked by continued evolution, in a peaceful attempt to move forward. Other times, change has been fraught with violent revolution and terrorism. This process has been the subject of much debate by political scientists and economic philosophers. Today, Turkey suffers from continued threats to its government through violent acts of terrorism conducted by various groups, expressing ideologies of leftist and rightist organizations, as well as ethnic and religious extremists. This thesis examines DHKP/C as the primary leftist revolutionary group effecting Turkey, exploring its historical background in Europe and the Middle East, as well as its philosophical link to Marxism. Further, this treatise discusses the implication of revolution and terrorism expressed by DHKP/C; and explores innovative and peaceful solutions, strategies, and techniques to be used by the police forces of Turkey in combating this group
The Castle/Nikki Heat Phenomenon: A Detailed Examination of Female Representation in Entertainment Media
As entertainment reflects a culture's ideology, it is important for researchers to study its messages and subsequently its potential meanings. Entertainment has the power to inform and persuade, creating models for behavior with which the public interacts. The entertainment texts for the purpose of this study are the Castle television series and the Nikki Heat novels. Together, they create a unique multi-layer fictional world. By using postmodern, feminist, communication, and entertainment theories, the results of this study provide a tightly focused lens which views a narrow aspect of entertainment media. Each text was thoroughly examined using textual analysis, Feminist Poststructuralist Discourse Analysis, and conversation analysis. Contrary to expectations, the results indicated that the Castle and Nikki Heat texts support hegemonic ideology, particularly through the use of exaggerated stereotypes, strict gender roles, imagery, and narrative choices that help perpetuate rape culture. The discussion outlines how these results can be interpreted through the dominant messages presented in the texts. This research is intended to serve as a foundation for future research regarding entertainment media.
A Catalog of Extinctions
The preface describes the construction of a book-length, interwoven sequence of poems. This type of sequence differs from other types of poetry collections in its use of an overarching narrative, repeated images, and recurring characters. Three interwoven sequences are used as examples of how to construct such a sequence.
Challenge the Silence
This collection of personal essays about incest, abuse, and depression explores the lasting effects of an invisible childhood. The essays follow the protagonist from the age of five to her early twenties. Her brother, at a young age, becomes sexually abusive of her and her sisters, and her parents fail to protect their daughters. The family is divided as the older girls strive to defend their little sisters, while their parents attempt to excuse their son. When her brother is finally sent away, the protagonist is left to salvage what remains of her relationships with her parents.
Challenges Encountered During Law Enforcement Investigations of Terrorist Use of Information Technology.
The late 20th and early 21st centuries have seen a phenomenal growth in society's use of information technology. Criminals, including terrorists and terrorist organizations, have also adopted information technologies. Information technologies are used to enhance the efficiency, productivity, and effectiveness of terrorist activities and offenses. Investigating terrorist use of information technologies creates a number of challenges for law enforcement officials. While some of the challenges are encountered during conventional criminal investigations, terrorist investigations also present unique challenges. Through content and typological analysis, this study examined open source information to identify, categorize and propose a model of these challenges. Four primary categories were identified: technology, methodology, legal, and administration and human resources challenges.
Changing Privacy Concerns in the Internet Era.
Privacy has always been a respected value regardless of national borders, cultural differences, and time in every society throughout history. This study focuses on the unprecedented changes in the traditional forms of privacy and consequent concerns with regard to invasion of privacy along with the recent emergence and wide use of the Internet. Government intrusion into private domains through the Internet is examined as a major concern. Privacy invasions by Web marketers, hacker threats against privacy, and employer invasion of employee privacy at the workplace are discussed respectively. Then a set of possible solutions to solve the current problems and alleviate the concerns in this field is offered. Legal remedies that need to be performed by the government are presented as the initial solution. Then encryption is introduced as a strong technical method that may be helpful. Finally, a set of individual measures emphasized as complementary practical necessities. Nevertheless, this study indicates that technology will keep making further changes in the form and concerns of privacy that possibly may outdate these findings in the near future, however, privacy itself will always remain as a cherished social value as it has always been so far.
Characterization of Iron Oxide Deposits Formed at Comanche Peak Steam Electric Station
The presence of deposits leading to corrosion of the steam generator (SG) systems is a major contributor to operation and maintenance cost of pressurized water reactor (PWR) plants. Formation and transport of corrosion products formed due to the presence of impurities, metallic oxides and cations in the secondary side of the SG units result in formation of deposits. This research deals with the characterization of deposit samples collected from the two SG units (unit 1 and unit 2) at Comanche Peak Steam Electric Station (CPSES). X-ray diffraction (XRD), Fourier transform infrared spectrophotometry (FTIR), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) techniques have been used for studying the compositional and structural properties of iron oxides formed in the secondary side of unit 1 and unit 2. Magnetite (Fe3O4) was found to be predominant in samples from unit 1 and maghemite (g-Fe2O3) was found to be the dominant phase in case of unit 2. An attempt has been made to customize FTIR technique for analyzing different iron oxide phases present in the deposits of PWR-SG systems.
Characterization of Moraxella bovis Aspartate Transcarbamoylase
Aspartate transcarbamoylase (ATCase) catalyzes the first committed step in the pyrimidine biosynthetic pathway. Bacterial ATCases have been divided into three classes, class A, B, and C, based on their molecular weight, holoenzyme architecture, and enzyme kinetics. Moraxella bovis is a fastidious organism, the etiologic agent of infectious bovine keratoconjunctivitis (IBK). The M. bovis ATCase was purified and characterized for the first time. It is a class A enzyme with a molecular mass of 480 to 520 kDa. It has a pH optimum of 9.5 and is stable at high temperatures. The ATCase holoenzyme is inhibited by CTP > ATP > UTP. The Km for aspartate is 1.8 mM and the Vmax 1.04 µmol per min, where the Km for carbamoylphosphate is 1.05 mM and the Vmax 1.74 µmol per min.
Characterizaton of Triethoxyfluorosilane and Tetraethoxysilane Based Aerogels
Aerogels are highly porous, low dielectric constant (low k) materials being considered by the semiconductor industry as an interlayer dielectric. Low k materials are needed to overcome capacitance problems that limit device feature sizes. Precursors triethoxyfluorosilane (TEFS) and tetraethoxysilane (TEOS) were used to prepare bulk aerogels. Samples were prepared by sol-gel methods, and then carbon dioxide supercritically-dried. Effects of varying the water to precursor ratio were studied with respect to aerogel properties and microstructure. Methods of analysis for this study include FTIR-ATR, TEM, RBS, EDS, SEM, dielectric constant determination by impedance and surface area by gas adsorption. Si-F bonds were determined to be present in both acid- and base-catalyzed TEFS as well as HF-catalyzed TEOS. Fluorine promotes a fractal network microstructure as opposed to a particle-like microstructure. Surface area and dielectric constant were determined to increase slightly with increases in the water to precursor ratio.
Characterizing the Municipal Solid Waste Stream in Denton, Texas
Forty-two commercially collected dumpsters from Denton’s Municipal Solid Waste Stream were emptied, sorted and weighed to characterize the material types and make preliminary recycling policy recommendations. The general composition of Denton’s solid waste stream was not significantly different from the composition of the nation’s solid waste stream. Fifty-eight percent of the observed waste stream was recyclable. Paper made up the largest portion of recyclable materials and the "grocery" source category had more paper than any of the other five categories. Based on these findings, an incrementally aggressive approach is recommended to reduce certain types of wastes observed in the waste stream. This would include a Pay-As-You-Throw Program followed by an Intermediate Processing Center that can be converted to a Materials Recovery Facility.
Chemotactic Response of Lumbricus terrestris Coelomocytes to Larval and Adult Stages of Rhabditis pellio
Experiments were performed to assess the suitability of Rhabditis pellio, a nematode found in earthworms, as a challenge organism for use in development of a biomarker assay to determine the potential of chemicals to suppress the immunocompetence of the non-specific immune system. To accomplish this goal, information on the life cycle of R. pellio was determined; including effects of incubation time and temperature on growth rates; along with information on the immune response elicited in the earthworm, Lumbricus terrestris. Immune parameters measured were coelomocyte migration toward and attachment to R. pellio larvae and adults. Preliminary background information showed that R. pellio has potential as a challenge organism for development of a biomarker assay.
A Chorus of Trees
This two-part thesis includes a critical preface and a collection of my poems. Using three poems-Louise Glück's "Lullaby," Bob Hicok's "Poem for My Mother's Hysterectomy," and Nick Flynn's "Memento Mori"-the critical preface examines how, in poetry, the transformation of a body negotiates trauma and triggers a conceptual shift, the creation and revision of identity, and the release of the duende's inspirational force. The collection of poetry that follows seeks to transfigure the body as a way to explore the nuanced traumas of human experience.
El Cine De Terror Español Como Espejo De La Cultura Española
This study traces the history and culture of Spain as seen through the lens of the nation´s production of horror cinema. Starting from the boom of Spanish horror film in the early 1960s, the thesis compares and contrasts the political and social aspects of Spanish society throughout three distinct eras of the 20th century: 1962 – 1975 (the boom of Spanish horror film through the Franco dictatorship), 1975 – 1999 (the transition to democracy through the end of the 20th century) and 2000 – present (the 21st century). Movies as diverse as Gritos en la noche (1962, Jesús Franco), ¿Quién puede matar a un niño? (1976, Narciso Ibáñez Serrador) and Angustia (1987, Bigas Luna) are framed by culturally-related anectodes as well as correlations to their respective social environments. Special attention has been paid to the production and release of each film, especially in regards to censorship during the Franco dictatorship. The results show that Spanish horror cinema has acted as a true mirror to culture, society and politics in its native country throughout the 20th century and that this trend will likely extend in to the future.
Claremont Connections
Claremont Connections is a collection of fictional short stories about the relationships between the generations of women in one family and their friends.