Search Results

(4+2)-Cycloaddition Reactions of Ketenes; Pyranones
This study deals with the (4+2)-cycloaddition reactions of 4-π electron compounds with ketenes. Chloroketenes were generated in situ from the corresponding chlorinated acid chlorides in the presence of the ketenophiles. Chloro-, dichloro- and diphenylketenes reacted with 1-methoxy-3-trimethylsiloxy-l,3-butadiene, and 2,4-bis(trimethylsiloxy)-1,3-pentadiene to yield the corresponding dihydropyrans. The dihydropyrans yielded substituted 4-pyranones on hydrolysis.
"The '91 Roos"
The ‘91 Roos is a sports documentary focused in Killeen, Texas. exploring the 1991 Killeen Kangaroos high school football team and their journey to their city's one and only state championship in football. Killeen is a small central Texas town that is directly adjacent and provides support to Ft Hood, one of the world's largest military bases. With the Persian Gulf War raging in 1991, soldiers that lived in Killeen were being sent off to fight, leaving the city almost like a ghost town. In October 1991, the Luby's Massacre occurred in Killeen, bringing the already depleted city further down by tragedy. At the time, this was the worst mass shooting in US history. This high school football team went on a fairy tale type of run during their 1991 season, resulting in winning a state title and bringing big hope back to a small town in need. Using direct interviews, narration and archival footage, this film provides an emotional yet inspirational look at a small town football team and their improbable season.
The 1896 Vienna Tonkünstler-verein Competition: the Three Award-winning Works and Seven Anonymous Submissions with Clarinet
The Vienna Tonkünstler-Verein (1885-1929) was established for the sole purpose of providing extensive support to the music and musicians of Vienna. The society became renowned in Vienna for its outstanding performances of chamber music and counted among its members many of the city’s foremost musicians and composers. Johannes Brahms had a significant influence on the society as its honorary president and assisted in establishing its composition competitions, aimed at promoting and reviving under-developed chamber genres. Of particular interest to clarinetists is the Verein’s competition of 1896, which aspired to promote chamber music literature for wind instruments. Brahms’s recently completed chamber works for clarinet were clearly influential in fin-de-siècle Vienna; for of the twelve works chosen as finalists in the competition, ten included the clarinet in the chamber combination.The purpose of this document is to provide an English-language history of the Vienna Tonkünstler-Verein and a thorough account of its1896 competition based on my study of the society’s annual reports. In addition, this document will provide the first published account of the anonymous submissions for the 1896 competition. It is my hope that this paper will serve as a springboard for future endeavors aimed at uncovering the identities of the anonymous finalists for this competition.
The 1948 States' Rights Democratic Movement in Texas
The purpose of this paper is to examine, from a local perspective, the reaction of the southern conservative wing of the Democratic party to the liberal changes which occurred in that organization as a result of the transitional decades of the 1930s and 1940s. In particular, the study focuses on the growing sense of alienation and the eventual withdrawal of a handful of Texas Democrats from affiliation with the national body and their subsequent realignment with other dissident Dixie Democrats in the short-lived States' Rights party of 1948. This work is based essentially on the personal recollections of Texans who participated in the States' Rights movement and on those papers of the party's leaders which have survived until today.
The 1986 National Endowment for the Arts Commission: An Introspective Analysis of Two Marimba Works
The marimba is rapidly achieving greater importance as a solo percussion instrument. Solo compositions for the marimba have been commissioned and performed only in the last sixty years. The 1986 National Endowment for the Arts Solo Marimba Commission is considered one of the most important commissioning projects in the history of marimba literature. Two compositions created through this project, Velocities by Joseph Schwantner and Reflections on the Nature of Water by Jacob Druckman have become two of the most influential works in contemporary marimba music. This thesis will focus on a historical perspective of the project, as well as theoretical aspects and performance issues related to these two compositions. The National Endowment for the Arts (NEA) issued a consortium commissioning grant through the Percussive Arts Society (PAS) in 1986 to three internationally renowned marimbists, William Moersch, Leigh Howard Stevens and Gordon Stout. Three Pulitzer Prize winners were brought together to compose three new works for the marimba. The resulting pieces were: Reflections on the Nature of Water by Jacob Druckman, Velocities by Joseph Schwantner, and Islands from Archipelago: Autumn Island by Roger Reynolds. A brief history of the classical concert marimba and the development of solo marimba literature is provided in the second chapter. The fourth and fifth chapters provide individual information about the pieces, including concise biographical information about the composers and an analysis of the two compositions.
2D and 3D Fabrication Devices: Can They Improve Spatial Reasoning Skills in Children?
The purpose of this study is to evaluate the potential benefit of two hours of activities involving 2D and 3D fabricators on the spatial reasoning skills of children in Grades 4 and 5, ages 9 to 10, from a private school in Southeast Texas. Can the introduction to hands-on activities with products created with these devices and learning about how these devices operate improve spatial reasoning skills? The research also evaluates the use of the Shapes Test as a valid measure of the spatial reasoning skills of children. The Cube Design and Spatial Memory subtests of the UNIT (Universal Nonverbal Intelligence Tests) were used for evaluating the spatial reasoning skills of the participants, based on their respected validity, along with a Shapes Test that is in development. Discussion regarding gender, language, and experiential theories of spatial reasoning skill development are included in the literature review.
3Dhotbed
Presented at the 2017 Code4Lib South Central Conference. This presentation provides an overview of the 3Dhobed project, including the process of 3D scanning, modeling, and printing hand moulds for book history instruction.
The a Cappella Choral Music of Benjamin Britten
The twentieth century has witnessed a renaissance in the composition of choral music. Not since the Baroque, has choral writing held the prominent position with composers that it has today. At the same time, English composers have regained a stature and influence they have not held since the time of Purcell. It was not until the time of Edward Elgar, Gustave Holst, and Ralph Vaughn-Williams that English music began to recover from the decline of the nineteenth century. Benjamin Britten has played a large role in both the choral renaissance and the recovery of English music.
D. A. Kolb’s Theory of Experiential Learning: Implications for the Development of Music Theory Instructional Material
This research project evaluates the effectiveness of specific music theory instructional strategies in terms of D. A. Kolb’s theory of experiential learning and Kolb’s typology of individual learning style. The project provides an original methodology for the adaptation of music theory instructional material to the individual learning style types described in Kolb’s typology. The study compares the relative effectiveness of two music theory instructional sequences, one of which is adapted for all of the learning style modalities described in Kolb’s typology, and the other adapted for only a limited number of Kolb’s learning style types. In order to compare the potential “learning outcomes” produced by these instructional sequences, a detailed study is proposed, in which computer based instruction (CBI) will deliver the instructional sequences to research participants and electronically record the participants’ responses. The current study demonstrates the effective aspects of the original methodology and suggests methods for the successful adaptation of music theory instructional material to individual student learning styles.
Aaron Copland's Concerto for Clarinet: A Lecture Recital, Together with Three Recitals of Music by Mozart, Rossini, Schumann, Brahms, and Contemporary European and American Composers
The dissertation consists of four recitals: one chamber music recital, two solo recitals, and one lecture recital. The repertoire of these programs was chosen with the intention of demonstrating the capability of the performer to deal with problems arising in works of varying types and of different historical periods. The lecture recital, Aaron Copland's Concerto for Clarinet, begins with biographical information, followed by a discussion of various other works of the composer and of important stylistic traits that are contained therein. After thus setting the Concerto in perspective to other major works, an investigation is made into various aspects of form and style which make the Concerto atypical in some respects to the composer t total body of works. Particular emphasis is given to rhythmic and melodic characteristics of the piece which are related to jazz and Latin-American popular music. The formal and stylistic analysis is followed by a discussion of problems involved in performing the Concerto with a piano reduction of the orchestral part, and the lecture concludes with a survey of interpretative problems posed by the work. At the conclusion of the lecture portion of the presentation, the Concerto was performed.
Aaron Copland's Piano fantasy, a lecture recital, together with three recitals of selected works
The lecture recital was given June 20, 1977, Copland's treatment of the fantasy concept was discussed along with compositional techniques used in the Piano Fantasy. The Piano Fantasy was performed.
Aaron Copland's Symphonic Use of Brass Instruments
Traditions in orchestration can be described by relating the practices of most of the important composers of a particular time. This was done with great success by two composers of the nineteenth century, Hector Berlioz and Nicolai Rimsky-Korsakov, in their books on orchestration. These texts are the basis for the traditional uses of brass instruments appearing in the chapter.
Ab Initio and Density Functional Investigation of the Conformer Manifold of Melatonin and a Proposal for a Simple Dft-based Diagnostic for Nondynamical Correlation
In this work we address two problems in computational chemistry relevant to biomolecular modeling. In the first project, we consider the conformer space of melatonin as a a representative example of “real-life” flexible biomolecules. Geometries for all 52 unique conformers are optimized using spin-component scaled MP2, and then relative energies are obtained at the CCSD (T) level near the complete basis set limit. These are then used to validate a variety of DFT methods with and without empirical dispersion corrections, as well as some lower-level ab initio methods. Basis set convergence is found to be relatively slow due to internal C-H…O and C-H…N contacts. Absent dispersion corrections, many DFT functionals will transpose the two lowest conformers. Dispersion corrections resolve the problem for most functionals. Double hybrids yield particularly good performance, as does MP2.5. In the second project, we propose a simple DFT-based diagnostic for nondynamical correlation effects. Aλ= (1-TAE [ΧλC]/TAE[XC])/λ where TAE is the total atomization energy, XC the “pure” DFT exchange-correlation functional, and ΧλC the corresponding hybrid with 100λ% HF-type exchange. The diagnostic is a good predictor for sensitivity of energetics to the level of theory, unlike most of the wavefunction-based diagnostics. For GGA functionals, Aλ values approaching unity indicate severe non-dynamical correlation. The diagnostic is only weakly sensitive to the basis set (beyond polarized double zeta) and can be applied to problems beyond practical reach of wavefunction ab-initio methods required for other diagnostics.
Ability Grouping in Secondary English
This thesis discusses the pros and cons of grouping by ability in secondary English.
Ability of Offenders with Psychopathic Traits to Simulate Cognitive and Affective Empathy
The accurate assessment of psychopathy constitutes a critical component of forensic assessments addressing offender populations. Among the core characteristics of psychopathy, the interpersonal component of deception and empathic deficits are prominently observed in offenders with psychopathic traits. Given the negative consequences of being classified as a psychopath, offenders may be likely to minimize their psychopathic traits. In particular, no research has investigated whether offenders with psychopathic traits are able to simulate empathy in an effort to mask their cognitive or affective empathy deficits (e.g., lack of remorse about offenses). The present study aims to contribute to the literature with regard to the simulation of empathy. Using a mixed between- and within-subjects design, 81 male detainees were placed into (a) a low psychopathy group, (b) a moderate psychopathy group, or (c) a high psychopathy group based on the Psychopathy Checklist – Revised. For the within-subjects component, all offenders answered empathy questionnaires under genuine and simulation conditions. Results indicate the sample possessed cognitive empathy, but did not display affective empathy under genuine instructions. Under simulation instructions, participants significantly increased their scores on several empathy measures. The implications of simulated empathy and comparisons between groups regarding simulation abilities are discussed.
Absalom, Absalom! A Study of Structure
The conclusion drawn from this study is that the arrangement of material in Absalom, Absalom! is unified and purposeful. The structure evokes that despair that is the common denominator of mankind. It reveals both the bond between men and the separation of men; and though some of the most dramatic episodes in the novel picture the union of men in brotherly love, most of the material and certainly the arrangement of the material emphasize the estrangement of men. In addition, by juxtaposing chapters, each separated from the others by its own structural and thematic qualities, Faulkner places a burden of interpretation on the reader suggestive of the burden of despair that overwhelms the protagonists of the novel.
Abstract Vector Spaces and Certain Related Systems
The purpose of this paper is to make a detailed study of vector spaces and a certain vector-like system.
The Abuse of Confidence as a Major Theme in the Novels of Henry James
All of the aforementioned factors--love, money, the abuse of confidence, the guilt growing out of it, the response of the victim--contribute to the moral view constantly evolving towards an ultimate statement in the three novels of James's maturity. This thesis will attempt to explicate in full that statement. For James's theme of abuse of confidence, together with all of its elements, was in itself only the vehicle of a finely attuned moral awareness.
Academic Achievement Among Language-Impaired Children as a Function of Intensive Preschool Language Intervention
Parents and professionals are concerned about the long-term effects of language problems on later academic, communicative and behavioral functioning of children. The purpose of this study was to examine the relationship of level of language impairment with type of class placement, reading achievement, and social emotional functioning. Subjects were 19 children, aged 4 years, 10 months through 10 years, 4 months, who had previously been enrolled in a preschool language development program. Statistical analyses were performed on data from the Kaufman Assessment Battery for Children (K-ABC), Test of Early Reading Ability (TERA), and the Achenbach Child Behavior Checklist (CBC). Results do not support a relationship between level of language impairment and academic or social/emotional functioning.
Academic Achievement and the Ability of Post-Secondary Students to Read Assigned Materials
This study provides a rationale for adopting course materials. It demonstrates the relationship between ability to read assigned materials and academic achievement, and that selection of materials creates two groups having different probabilities of success. The sample was selected from a population of all students enrolled in Principles of Economics courses at North Texas State University in the spring semester of 1986. The Nelson-Denny Reading Test was used to determine reading ability. Assigned materials were analyzed for readability. A frustration level was determined and used to divide the sample: the group of interest, those with reading abilities below the frustration level who underwent the treatment of reading materials written above their ability to comprehend; and the comparison group, those with reading abilities above the frustration level who did not undergo the treatment.
Academic Achievement: Effects of Congruency, Consistency, Differentiation, and Modal Personality Types
This investigation explored relationships between four determinants of first-semester undergraduate academic achievement derived from Holland's (1973) theory of vocational development. Groups of 438 male and 468 female students completed the Strong-Campbell Interest Inventory and were categorized in terms of congruency, consistency, differentiation, and modal personality type. Undergraduates with congruent college-major choices enjoyed greater academic success than students with incongruent choices. Students with high- and low-consistency personal orientation codes outperformed students with moderately consistent codes. Freshman with clearly differentiated personality profiles outperformed students with nondifferentiated profiles. The order of mean gradepoint averages for the modal personality types was not significantly correlated with Holland's predicted ordering.
Academic Achievement: Examining the Impact of Community Type at a Small Liberal Arts College in Texas
Hierarchical regression was used to determine if high school community type is an effective predictor of academic success when controlling for demographics, prior academic achievement, socioeconomic status, and current commitment or work habits for students entering Austin College in 1992,1993, and 1994 . Findings revealed that there is a relationship between attending high school in community types of rural and independent town controlling for the effects of SAT scores, high school rank, sex, and late application deposit on first semester grade point average.
Academic Achievement of National Social Fraternity Pledges Compared to Non-Fraternity Students
This study examined the academic achievement of national social fraternity pledges compared to non-fraternity students at the University of Texas at Arlington. It was done to determine whether significant differences existed between the grade point averages of pledges of social fraternities and those of students who did not pledge a social fraternity, and to determine whether significant differences existed among fraternities when compared with each other with respect to academic achievement. This study was meant to provide a research design that could be used by other colleges and universities with fraternities to conduct the same comparison of academic performance. In the fall semester of 1989, 164 pledges were selected as the population for the study to be matched with non-fraternity students based on Scholastic Aptitude Test (SAT) scores, age, sex, classification, academic major, and number of hours attempted. A T-test of like groups was performed on the entire population with no significant difference found at the .05 level between all the fraternity pledges and all the matched pairs. A T-test of like groups was performed on the pledges from each separate organization and there was a significant difference among three of the fraternities. Two of the fraternities had significantly higher grade point averages than those of their matched pairs, and one group of matched pairs had a significantly higher grade point average than the fraternity. Of the 17 fraternities, 12 had higher grade point averages than their matched pairs and five of the matched pairs had higher grade point averages than the fraternities. The results of this study show that objective data can be collected to address the issue of academic excellence comparing fraternity and non-fraternity populations. It is recommended that further study be conducted in this area to establish longitudinal data, with specific examination of the scholarship programs of …
Academic, Behavioral, and Social Competency Characteristics of Non-Handicapped, Learning Disabled, and Emotionally/Behaviorally Disordered Adjudicated Juveniles
The juvenile justice system is society's response to juvenile misconduct. In spite of numerous federal, state, and local programs, the problem of juvenile delinquency persists. An increasing number of juveniles are being taken into custody and placed in institutional settings. Although juvenile delinquents share a number of common general characteristics (e.g., sex, minority, lower socioeconomic status, a history of school failure), they are not a homogeneous group. Effective educational interventions with delinquent juveniles can meet their unique academic, vocational, and social skills deficits. Handicapped juveniles are disproportionately represented among juvenile correctional facility populations. The identification of handicapped juveniles among delinquent populations is compounded as they share many of the same general characteristics. Federal statutes require individualized educational programs for all handicapped juveniles. This research investigated academic, behavioral, and social competencies of non-handicapped and handicapped adjudicated youth. Specifically, this investigation assessed measures of academic performance, classroom behavior, self-esteem, and social behavior. ANOVA indicated statistically significant differences between non-handicapped, learning disabled, and emotionally/behaviorally disordered adjudicated juveniles in reading achievement, mathematics achievement, and teacher generated measures of classroom behavior.
Academic excellence and instructional expenditures in Texas.
Public school per pupil costs and demands for better performance have increased over the past several decades. While the overall per pupil expenditures have increased, the percent of the educational dollar directed toward instructional activities has remained at approximately 60%. A grass-roots movement known as the "65% Solution" caught national attention by claiming that schools are not efficiently allocating resources into areas that have the greatest link to student achievement, such as instruction. Proponents of the 65% Solution claim that per pupil expenditures can be increased by shifting funds from areas considered non-instructional to areas that directly impact student instruction, such as teachers and instructional materials. The purpose of this study was to determine the relationship between district Panel Recommended and Commended Performance TAKS Reading/ELA and Math results and three measurements of instructional expenditures, Instructional Staff Percent; TEA Instructional Expenditure Ratio; and the NCES Instructional Expenditure Ratio (65% Solution), in Texas public schools. Data was collected from the 2003-2004 AEIS report. Multiple regression was used to conduct the analyses. In most instances, there was little, if any, relationship between TAKS Reading/ELA and TAKS Math, and the Instructional Staff Percent (ISP), TEA Instructional Expenditure Ratio (TIER), and NCES Instructional Expenditure Ratio (NIER). However, a low to moderate relationship was discovered in the comparison of TAKS Reading/ELA, and the ISP and TIER. This result was the same for both the Panel Recommended and Commended Performance. In every instance, the ISP and TIER showed positive, statistically significant, relationships to TAKS results. The NIER, or 65% Solution, had the lowest correlation and was statistically insignificant in three out of four analyses.
Academic Librarians Creating Value through Commercialization Partnerships
This paper focuses on how the University of North Texas (UNT) Libraries was able to develop a successful partnership with the UNT Office of Innovation and Commercialization (OIC) and move outside the Libraries’ normal sphere of influence to help create a patent internship program for students. The paper is published in the Texas Library Journal Special Edition for Summer 2020, and it was a contributed paper at the Texas Library Association 2020 Virtual Summer of Learning conference.
Academic Lineage and Student Performance in Medical School
This research investigated the association between academic lineage and student performance in medical school. The purposes of the study were to: (1) determine whether the Carnegie classifications of medical school applicants' institutions of origin are associated with academic performance in medical school; (2) consider the relationship between the admission selectivity of the schools of origin and the academic performance of medical school students; (3) compare the performance of medical students from institutions under public governing control with students from privately controlled institutions; and (4) establish a model by which the relative academic strengths of applicants from a variety of undergraduate institutions can be understood more clearly based on the previous performance of medical students from schools with similar institutional characteristics. A review of the literature on medical school admissions was completed and used to develop this research. Medical students from the University of Texas Southwestern Medical Center at Dallas who enrolled between the years 1990 and 1994 and graduated or were dismissed between the years 1994 and 1998 were selected as the sample for the study (n=933). The undergraduate institution of origin for each student was coded based on its Carnegie classification, admissions selectivity group, and whether its governing control was public or private. Because the sample was not randomly selected and the data likely would not meet the assumptions of equal means and variance with the population, nonparametric analyses of variance and multiple comparison tests were completed to compare the groups of the independent variables over each dependent variable. The analyses revealed that for the sample of medical students selected for this study there was an association between academic lineage and student performance in medical school. Differences were found among Carnegie classifications on the dependent variables of cumulative medical school grade point average, class rank, failure rate, and score …
Academic Self-efficacy of Adult First-generation Students Enrolled in Online Undergraduate Courses
This study examined differences between adult first-generation (AFG) and adult-continuing generation (ACG) students’ academic self-efficacy with regard to the online courses in which they were currently enrolled. The study used an online survey methodology to collect self-reported quantitative data from 1,768 undergraduate students enrolled in an online course at a mid-sized, four-year public university in the southwestern United States; 325 cases were usable for the study. The t-tests revealed no statistically significant differences between the academic self-efficacy of the AFG and ACG students. Parents’ level of educational attainment was unrelated to adult students’ academic self-efficacy with online courses. Ordinary least-squares analysis was used to evaluate student characteristics that might be associated with academic self-efficacy in the online environment. A combination of gender, GPA, age, race/ethnicity (White, Black, Hispanic, and other), and number of previous online courses predicted a statistically significant 12% of the variance in academic self-efficacy in an online environment (p < .001). Age (p < .001) and self-efficacy were positively correlated, meaning that adult students reported greater academic self-efficacy than did younger students; and number of previous online courses (p < .001) was also positively correlated to academic self-efficacy, indicating that students with greater experience with online courses reported a greater sense of academic self-efficacy in that environment than students who had completed fewer online courses. This study has implications of providing additional insight for higher education practitioners working with adult learners. Identifying additional factors influencing adult learners’ academic self-efficacy in an online academic environment may be useful when building effective strategies to improve online retention and completion rates for these students. Future research should examine a wider variety of variables beyond demographic characteristics. External and internal factors, along with existing theories of behaviors should be investigated to help explain adult persistence and retention online and in face-to-face …
Academic, Social and Emotional Functioning of College Students with Attention-Deficit/Hyperactivity Disorder (ADHD)
Attention deficit/hyperactivity disorder (ADHD) is frequently associated with negative occupational, social and psychological outcomes among community samples of adults; as such, it is expected that college students with ADHD face similar struggles. The research targeting this group of individuals, however, is sparse and tempered by significant limitations. The current study aimed to address methodological limitations in the current literature by including instruments to formally diagnosis ADHD and comorbid disorders, utilizing psychometrically sound instruments and comparing functioning of college students with ADHD across gender and subtype. It was hypothesized that participants with ADHD would report lower GPAs, higher levels of emotional distress and negative relationship characteristics than participants without ADHD. It was also hypothesized that participants with ADHD-combined type (ADHD-C) would report higher levels of substance and alcohol use than participants with ADHD-predominately inattentive type (ADHD-I), and that participants with ADHD-I would report higher levels of anxiety and depression than participants with ADHD-C. Women diagnosed with ADHD were expected to report higher levels of anxiety and depression than men diagnosed with ADHD; whereas, men diagnosed with ADHD were expected to report higher levels of substance and alcohol use than women. MANOVA, ANOVA and Mann-Whitney U tests were conducted to test hypotheses. Results revealed no significant differences between the ADHD and comparison group on GPA and relationship characteristics. Participants diagnosed with ADHD did report significantly higher emotional distress than participants in the comparison group. No differences in GPA or relationship characteristics were found across ADHD subtype or gender. Overall, these findings provide evidence to suggest that college students with ADHD are functioning relatively well compared to their non-ADHD peers.
Accelerated EMG Biofeedback Relaxation Training and Tension Headache: The Effects of Home Practice and Headache Presence During Training
This study investigated the value of headache presence during elecromyographic (EMG) feedback relaxation training and the contribution made by home relaxation practice in the elimination of tension headache. Eighteen participants, mainly coeds in their twenties, recorded headache and medication data for two baseline weeks, and were assigned to one of three training groups. Group A received EMG feedback training with headache presence during the session and home relaxation practice. Group B received EMG feedback without headache Presence and home practice. Group C received only home relaxation practice. Statistically significant treatment differences were not found, but declining trends of headache activity and medication use tend to support the efficacy of EMG training with headache presence.
Acceptor-sensitizers for Nanostructured Oxide Semiconductor in Excitonic Solar Cells
Organic dyes are examined in photoelectrochemical systems wherein they engage in thermal (rather than photoexcited) electron donation into metal oxide semiconductors. These studies are intended to elucidate fundamental parameters of electron transfer in photoelectrochemical cells. Development of novel methods for the structure/property tuning of electroactive dyes and the preparation of nanostructured semiconductors have also been discovered in the course of the presented work. Acceptor sensitized polymer oxide solar cell devices were assembled and the impact of the acceptor dyes were studied. The optoelectronic tuning of boron-chelated azadipyrromethene dyes has been explored by the substitution of carbon substituents in place of fluoride atoms at boron. Stability of singlet exited state and level of reduction potential of these series of aza-BODIPY coumpounds were studied in order to employ them as electron-accepting sensitizers in solid state dye sensitized solar cells.
"Access Points"
Access Points explores the different relationships that humans have to land, focusing on the various ways that the area known as the Wichita Mountains Wildlife Refuge is used, appreciated, and preserved by disparate groups. The natural beauty of this Wildlife Refuge and its striking appearance amidst encircling plains makes it a popular destination for many groups of people, including the local rock-climbing community and generations of indigenous peoples whose connection with this land is as deep as it is longstanding. While climbing organizations have long had to negotiate access and rules regarding climbing within the park, members of the Kiowa community negotiate a much different relationship to a natural area that is now managed by the United States government. These disparate voices, identities, and ways of thinking about land all impact the modern-day Wildlife Refuge in terms of its appearance, individuals' access to the land, and the conservation efforts happening there.
Accessing the Power of Aesthetics in Human-computer Interaction
In information systems design there are two schools of thought about what factors are necessary to create a successful information system. The first, conventional view holds that system performance is a key, so that efficiency characteristics such as system usability and task completion time are primary concerns of system designers. The second, emerging view holds that the visual design is also the key, so that visual interface characteristics such as visual appeal, in addition to efficiency characteristics, are critical concerns of designers. This view contends that visual design enhances system use. Thus, this work examines the effects of visual design on computer systems. Visual design exerts its influence on systems through two mechanisms: it evokes affective responses from IT users, such as arousal and pleasure and it influences individuals’ cognitive assessments of systems. Given that both affective and cognitive reactions are significant antecedents of user behaviors in the IT realm, it is no surprise that visual design plays a critical role in information system success. Human-computer-interaction literature indicates that visual aesthetics positively influences such information success factors as usability, online trust, user satisfaction, flow experience, and so on. Although academic research has introduced visual design into the Information Systems (IS) field and validated its effects, visual design is still very limited in three contexts: product aesthetics in e-commerce, mobile applications and commercial emails. This dissertation presents three studies to help fill these theoretical gaps respectively.
Accident versus Essence: Investigating the Relationship Among Information Systems Development and Requirements Capabilities and Perceptions of Enterprise Architecture
Information systems (IS) are indelibly linked to the global economy and are indispensable to society and organizations. Despite the decisive function of IS in organizations today, IS development problems continue to plague organizations. The failure to get the system requirements right is considered to be one of the primary, if not the most significant, reasons for this high IS failure rate. Getting requirements right is most notably identified with Frederick Brooks' contention that requirements are the essence of what IT professionals do, all the rest being accidents or risk management. However, enterprise architecture (EA) may also provide the discipline to bridge the gap between effective requirements, organizational objectives, and the actual IS implementations. The intent of this research is to examine the relationship between IS development capabilities and requirements analysis and design capabilities within the context of enterprise architecture. To accomplish this, a survey of IT professionals within the Society for Information Management (SIM) was conducted. Results indicate support for the hypothesized relationship between IS development and requirements capabilities. The hypothesized relationships with the organizational demographics were not supported nor was the hypothesized positive relationship between requirements capabilities and EA perceptions. However, the nature of the relationship of requirements and EA provided important insight into the relationship leading to several explanations as to its meaning and contributions to research and practice. This research contributes to IS development knowledge by providing evidence of the essential role of requirements in IS development capabilities and in IS development maturity. Furthermore, contributions to the nascent field of EA research and practice include key insight into EA maturity, EA implementation success, and the role of IT professionals in EA teams. Moreover, these results provide a template and research plan of action to pursue further EA research in exploring EA maturity models and critical success factors, …
The Accompanied Solo Song of the Fifteenth and Sixteenth Centuries
The purpose of this thesis is to discuss the changes and developments of the accompanied solo song throughout the fifteenth and sixteenth centuries, including instrument usage and song types.
Accountability in Schools: a Study of High School Accountability Ratings and College Success
The purpose of this study was to determine the relationship between high school campus accountability ratings, college readiness indicators, and the percent of students who achieved first year college success. Correlation and multiple regression analyses were used to analyze the relationship between the variables. Data was analyzed for two-year and four-year postsecondary educational institutions which were divided by eight school district types. Regression analysis of the relationship between high school campus accountability ratings and the percent of students who achieved first year college success for four- year post secondary educational institutions revealed statistically significant results ranging from R2 =.179 to R2 = .220. Similar results were found for two-year post secondary educational institutions with statistically significant results ranging from R2 = .049 to R2 = .218. The results indicated negligible to small relationships between the variables. Regression results of the analysis for the relationship between college readiness indicators and the percent of students who achieved first year college success revealed statistically significant results for 2 - year post secondary educational institutions ranging from R2 = .077 to R2 = .596 and for 4 -year post secondary educational institutions ranging from R2 = .048 to R2 = .304. These results indicated small to moderate relationships between college readiness indicators and the percent of students who achieve first year college success.
Accounting for Self-Insurance--Theory and Practice
This study is an investigation of the theoretical accounting viewpoints and the accounting procedures used in business practice for the origination and administration of a self-insurance program. The purpose of this study is to compare the correct theoretical accounting procedures for self-insurance planning with those used in practice today.
Accounting Regulation and Information Asymmetry in the Capital Markets: An Empirical Study of Accounting Standard SFAS no 87
This study uses both basic and self-selection regression models to test three hypotheses about the effect of SFAS 87 disclosures on information asymmetry during 1985- 1987. Both types of models test the hypotheses after controlling for changes in the inventory holding and order processing costs of the spread, while the self-selection models also control for potential self-selection bias.
Acculturation and Depression in Older Mexican American Adults: the Role of Social Support
Despite socioeconomic disadvantages, less acculturated Mexican Americans tend to exhibit better mental health than their more acculturated counterparts. However, in the case of older Mexican American adults, research has demonstrated the opposite to be true (Gonzalez, Haan, & Hinton, 2001). A variable of interest potentially responsible for this difference is social support. Thus, the current study proposed to investigate the mediation and moderation effects that social support has on the relationship between acculturation and depression in older Mexican American adults age 60 or older. Data from the Health and Retirement Study (HRS) was analyzed. Results showed that the mediating effect of contact with one’s children (-.109*) and the moderating effect of total social support and contact with one’s children (-.127*; -.103*) were statistically significant in the relationship between acculturation and depression. Although these effects are small they may still hold important implications for better understanding this population.
Acculturation and Feminist Endorsement on Control of Health and Health Behaviors in Hispanic Females
Hispanic women are the fastest growing population in the United States. Thus, it is important to explore health disparities that affect this population and better understand potential causes. Several explanations have been proposed for disparities that exist including turning to cultural alternatives rather than conventional medicine, low numbers of health insurance enrollments among Hispanics, and acculturation. However, little attention has been given to explanations that take into account the unique experiences of Hispanic women. The present study explored these experiences through investigation of endorsement of feminist attitudes (e.g., gender role adherence and beliefs that men and women should be treated equally in society) and level of acculturation. Undergraduate Hispanic women (18-24 years of age, M = 20.25, SD = 1.51) at the University of North Texas completed measures including the Multidimensional Health Questionnaire, the Acculturation Rating Scale for Mexican Americans-II, and the Liberal Feminist Attitude and Ideology Scale. Although results indicate that acculturation was not significant in the sample, feminist endorsement was found to be positively correlated with health-esteem, health-efficacy, and internal-health locus of control. Limitations and recommended directions for future research are explored.
Acculturation in African American College Women and Correlates of Eating Disorders
Although eating disorders have been the focus of much research, the inclusion of minority populations has been minimal. A recent review of the literature by Dolan (1991) has found that eating disorders were most likely to be present in non-White women who were exposed to Western societies and cultures. Thus, the purpose of this study was to examine personality, physical, and cultural correlates of bulimic symptomatology in a sample of African American college women. The Bulimia Test Revised (BULIT-R) was used to assess bulimia symptoms. The African American Acculturation Scale (AAAS), the Beliefs about Attractiveness Scale Revised (BAAR factors 1 and 2), the Rosenberg Self-Esteem Scale (SES), the Centers for Epidemiological Depression Scale (CES-D), Body Parts Satisfaction Scale (BPSS), and body mass were the independent variables hypothesized to predict bulimic symptoms. Hierarchical regression analysis revealed that body mass, depression, and low self-esteem were the best predictors of bulimic symptomatology, together accounting for 38% of the variance. Beliefs about attractiveness and body satisfaction were related to bulimic symptoms but not when considered simultaneously with the other variables. Acculturation was not predictive of bulimic symptoms. 0-ordered correlations revealed that beliefs about attractiveness and body satisfaction were correlated with bulimic symptoms. Acculturation was not related to any variables except depression. Implications for counseling interventions as well as directions for future research are discussed.
Acculturation Level, Generational Status and Gender: Their Role in Acculturative Stress in Young Adolescent Mexican Americans
The purpose of this study was to determine relationships between acculturation level, generational status, and gender with acculturative stress. Acculturation level was determined by the Acculturation Rating Scale for Mexican Americans-II (ARSMA-II) and acculturative stress was determined by the Societal, Attitudinal, Familial and Environmental Acculturative Stress Scale-Children's Version (SAFE-C). Subjects included 1268 Hispanic children ages 11-15. In order to validate the usefulness of the ARSMA-II with this sample, analyses were conducted between acculturation level and generational status. The Pearson product moment correlation (r=.44) and the ANOVA between the mean acculturation score and generational status were significant. However, the mean acculturation score from this study was considerably lower than the ARSMA-II score; therefore, new acculturation levels were developed to establish local adolescent norms for the ARSMA-II. All analyses involving acculturation levels were conducted using both the ARSMA-II and new acculturation levels because 300 subjects were reclassified with the new norms. Significant results were similar using both acculturation levels; however, there were more between group differences using the new acculturation levels. It was hypothesized that as acculturation level increased toward the Anglo culture, acculturative stress would decrease. The one-way ANOVA confirmed this relationship. It was also hypothesized that as generational status increased, acculturative stress would decrease. A one-way ANOVA also supported this hypothesis. In order to replicate previous findings on gender, a one-way ANOVA was conducted with acculturative stress and acculturation level. Results for both were non-significant. Overall findings indicate that generational status and acculturation level have a significant impact on acculturative stress in Hispanic children; however, gender does not seem to be a factor. Findings emphasize the importance of addressing cultural issues in the assessment, intervention, and treatment of acculturating Hispanic children. Furthermore, the ARSMA-II appears to be a useful instrument in assessing acculturation level in young adolescent Hispanics though new …
The accumulated earnings tax: an empirical analysis of the Tax Court's implementation of Congressional intent
Taxpayers have traditionally assessed personal vulnerability to particular taxes through a study of past litigated cases. One of the premises of the study was that useful information concerning the enforcement of the accumulated earnings tax could be obtained through a statistical analysis of such cases.
Accuracy and Efficiency in Computational Chemistry: The Correlation Consistent Composite Approach
One of the central concerns of computational chemistry is that of efficiency (i.e. the development of methodologies which will yield increased accuracy of prediction without requiring additional computational resources – RAM, disk space, computing time). Though the equations of quantum mechanics are known, the solutions to these equations often require a great deal of computing power. This dissertation primarily concerns the theme of improved computational efficiency (i.e. the achievement of greater accuracy with reduced computational cost). Improvements in the efficiency of computational chemistry are explored first in terms of the correlation consistent composite approach (ccCA). The ccCA methodology was modified and this enhanced ccCA methodology was tested against the diverse G3/05 set of 454 energetic properties. As computational efficiency improves, molecules of increasing size may be studied and this dissertation explored the issues (differential correlation and size extensivity effects) associated with obtaining chemically accurate (within 1 kcal mol-1) enthalpies of formation for hydrocarbon molecules of escalating size. Two applied projects are also described; these projects concerned the theoretical prediction of a novel rare gas compound, FKrOH, and the mechanism of human glutathione synthetase’s (hGS) negative cooperativity. The final work examined the prospect for the parameterization of the modified embedded atom method (MEAM) potential using first principles calculations of dimer and trimer energies of nickel and carbon systems. This method of parameterization holds promise for increasing the accuracy of simulations for bulk properties within the field of materials science.
Accuracy and Interpretability Testing of Text Mining Methods
Extracting meaningful information from large collections of text data is problematic because of the sheer size of the database. However, automated analytic methods capable of processing such data have emerged. These methods, collectively called text mining first began to appear in 1988. A number of additional text mining methods quickly developed in independent research silos with each based on unique mathematical algorithms. How good each of these methods are at analyzing text is unclear. Method development typically evolves from some research silo centric requirement with the success of the method measured by a custom requirement-based metric. Results of the new method are then compared to another method that was similarly developed. The proposed research introduces an experimentally designed testing method to text mining that eliminates research silo bias and simultaneously evaluates methods from all of the major context-region text mining method families. The proposed research method follows a random block factorial design with two treatments consisting of three and five levels (RBF-35) with repeated measures. Contribution of the research is threefold. First, the users perceived a difference in the effectiveness of the various methods. Second, while still not clear, there are characteristics with in the text collection that affect the algorithms ability to extract meaningful results. Third, this research develops an experimental design process for testing the algorithms that is adaptable into other areas of software development and algorithm testing. This design eliminates the bias based practices historically employed by algorithm developers.
Accuracy of Eyewitness Memory Under Leading Questioning: The Effects of Hypnosis and Anxiety
Hypnosis has gained substantial support in the psychological community, as well as related health professions. The intense renewal of interest in hypnosis has also affected our legal-judicial system. Many police investigators trained in hypnosis operate from an exactcopy memory theory. They claim eyewitness eyewitness retrieve veridically stored memory traces from long-term memory, if questioned under hypnosis. Conversely, other researchers ascribe to a reconstructive memory theory. They believe hypnosis increases the likelihood of eliciting erroneous memories from eyewitnesses, especially under leading questioning. The purpose of the present investigation was to test the effects of hypnotic induction and anxiety on the accuracy of subjects' memory for eyewitnessed events when questioned with leading, non-leading, and embedded misinformation questions.
Accuracy of Partner Perception and Relationship Satisfaction: Investigating Masturbatory Habits
An individual's perceptions of various aspects of one's romantic relationship (irrespective of whether or not the perceptions align with reality) often play a critical role in romantic relationship satisfaction. Research has demonstrated that the accuracy of an individual's perception of his or her partner is generally positively related to the individual's romantic relationship satisfaction. However, when perceiving negative or conflictual messages from a partner, an individual's accuracy of perception is negatively associated with his or her romantic relationship satisfaction. Researchers have suggested that poor accuracy in perceiving negative messages might diffuse the negative intention in a way that is less impactful to the relationship. The present study was designed to investigate accuracy in the perception of sexual topics, specifically masturbatory habits. A sample of 93 married couples (186 individuals) responded to questions about (a) their own masturbatory behaviors and (b) their perception of their partners' masturbatory behaviors to determine the accuracy of each partner's perception of his or her partner. The association between accuracy and romantic and sexual relationship satisfaction was explored, along with one potential moderating variable: attitudes toward masturbation. Perceived reason for masturbating, perceived target of arousal during masturbation, and partner's actual reason for masturbating all positively predicted an individual's relationship satisfaction. Partner's actual openness about masturbatory behaviors moderated the association between accuracy of partner perception of openness about masturbation and both relationship and sexual satisfaction. When partners were more open about masturbation, accuracy was a stronger positive predictor of relationship and sexual satisfaction than when partners were less open about masturbation. Results, limitations, areas for future research, and clinical implications are discussed.
Accuracy of Three Assessments of Sleep Timing, Duration and Efficiency Compared to a Single-Channel EEG Device
Poor sleep measured across many dimensions has been linked to adverse physical and mental health outcomes including cardiovascular disease, diabetes, cancer, increased mortality, depression, and anxiety. Current research typically relies upon brief, subjective, inadequately validated methods to assess limited dimensions of sleep, resulting in inaccurate measurements and possibly faulty conclusions. Specifically, research validating objective (e.g., actigraphy) and subjective (e.g., sleep diaries, retrospective surveys) measurement methods against the gold standard of polysomnography (PSG, an overnight sleep study) is primarily limited by a) a lack of reliability based on too short (e.g., 24 or 48 hours) of an assessment period to capture night-to-night variability, b) a lack of ecological validity (e.g., full PSG in a laboratory setting), and c) a lack of generalizability due to limited or special populations (e.g., individuals with insomnia). Barriers such as prohibitive cost, extensive setup time, and personnel training requirements diminish the ability of researchers to conduct measurement comparison studies using gold standard measures like traditional PSG. These barriers can be circumvented with the use of low-cost, minimally invasive single-channel EEG devices (e.g., Zmachine), but to date few studies have employed these devices. The current study evaluated the accuracy of retrospective surveys, sleep diaries, and actigraphy compared to a single-channel EEG device for assessment of sleep timing, duration, and efficiency in participants' homes over one week using a broad community sample (N = 80). Actigraphy generally demonstrated the best agreement with Zmachine across sleep variables, followed by diary and then survey. Circadian midpoint was the most consistent across measures, followed by sleep duration and then sleep efficiency. Implications and future directions are discussed.
Accurate and Reliable Prediction of Energetic and Spectroscopic Properties Via Electronic Structure Methods
Computational chemistry has led to the greater understanding of the molecular world, from the interaction of molecules, to the composition of molecular species and materials. Of the families of computational chemistry approaches available, the main families of electronic structure methods that are capable of accurate and/or reliable predictions of energetic, structural, and spectroscopic properties are ab initio methods and density functional theory (DFT). The focus of this dissertation is to improve the accuracy of predictions and computational efficiency (with respect to memory, disk space, and computer processing time) of some computational chemistry methods, which, in turn, can extend the size of molecule that can be addressed, and, for other methods, DFT, in particular, gain greater insight into which DFT methods are more reliable than others. Much, though not all, of the focus of this dissertation is upon transition metal species – species for which much less method development has been targeted or insight about method performance has been well established. The ab initio approach that has been targeted in this work is the correlation consistent composite approach (ccCA), which has proven to be a robust, ab initio computational method for main group and first row transition metal-containing molecules yielding, on average, accurate thermodynamic properties, i.e., within 1 kcal/mol of experiment for main group species and within 3 kcal/mol of experiment for first row transition metal molecules. In order to make ccCA applicable to systems containing any element from the periodic table, development of the method for second row transition metals and heavier elements, including lower p-block (5p and 6p) elements was pursued. The resulting method, the relativistic pseudopotential variant of ccCA (rp-ccCA), and its application are detailed for second row transition metals and lower p-block elements. Because of the computational cost of ab initio methods, DFT is a popular choice …
Accurate Empathy and Rorschach Interpretation
Although the Rorschach is one of the most widely used psychological assessment techniques, its empirical support has been equivocal. One possible explanation for this lack of empirical support is the tendency for researchers to study only the assessment tool with little regard for the clinician using it. The current study examined one clinician variable (empathy) and its relationship to accuracy of interpretation of the Rorschach. The literature regarding Rorschach theory and research and empathy theory and research was reviewed in an attempt to clarify the similarities between empathy as an important factor in psychotherapy and its importance in the assessment process. The present study measured empathy by using the Davis Empathy Questionnaire and a Taped Excerpt Response Measure.
Back to Top of Screen