UNT Scholarly Works - 6 Matching Results
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- The Reaction Kinetics of Amino Radicals with Sulfur Dioxide
- Abstract: Application of the laser photolysis–laser-induced fluorescence method to the reaction NH2 + SO2 in argon bath gas yields pressure-dependent, third-order kinetics which may be summarized as 𝑘 = (1.49 ± 0.15) × 10^−31 (𝑇/298 K) − 0.83 cm^6 molecule^−2 s^−1 over 292 – 555 K, where the uncertainty is the 95% confidence interval and includes possible systematic errors.The quenching of vibrationally excited NH2 is consistent with a high-pressure limit for NH2 + SO2 of (1.62 ± 0.25) × 10^−11 cm^3 molecule^−1 s^−1 over the temperature range 295–505 K, where again the 95% confidence interval is shown. Abinitio analysis yields a H2N – SO2 dissociation enthalpy of 73.5 kJmol−1, and comparison with RRKM theory and the exponential down model for energy transfer yields ⟨Δ𝐸⟩down = 350 cm^−1 for Ar at room temperature.
- Making German Greater: Advocating for Strong Programs at All Levels
- Article on making German greater and advocating for strong programs at all levels.
- Supporting Material for: Thermochemical Investigations of Solute Transfer into Ionic Liquid Solvents: Updated Abraham Model Equation Coefficients for Solute Activity Coefficient and Partition Coefficient Predictions
- This document includes supplemental material to an article titled "Thermochemical Investigations of Solute Transfer into Ionic Liquid Solvents: Updated Abraham Model Equation Coefficients for Solute Activity Coefficient and Partition Coefficient Predictions," published in Physics and Chemistry of Liquids.
- Eighteenth-Century Women Novelists at the Dawn of the Twenty-First Century - Part 2
- This bibliography forms the sequel to the author's 'Eighteenth-Century Women Novelists at the Dawn of the Twenty-First Century: A Selected Bibliography,' which appeared in this Newsletter in the spring of 2007. The author provides an overview of the most important French women writers of the eighteenth century who did not write novels primarily.
- Supporting information for Abraham model correlations for solute partitioning into o-xylene, m-xylene and p-xylene from both water and the gas phase
- This document includes supporting information and figures for an article on the Abraham model correlations for solute partitioning into o-xylene, m-xylene and p-xylene from both water and the gas phase.
- Publisher's Note: Beyond the Death of Linear Response: 1/f Optimal Information Transport [Phys. Rev. Lett. 105,040601 (2010)]
- This is a Publisher's Note for the article 'Beyond the Death of Linear Response: 1/f Optimal Information Transport' [Phys. Rev. Lett. 105, 040601 (2010)].