Microwave Spectra of ¹³C Isotopic Species of Methyl Cyanide in the Ground, v₈=1 and v₈=2 Vibrational States
Description:
The problem of the quadrupole interaction occurring in a vibrating-rotating C₃v symmetric top molecule has been studied in detail. The quadrupole interaction has been treated as another perturbation term to a general frequency expression accounting for the vibrating-rotating interaction of the molecule so that a complete frequency formula is obtained for both interactions, and from which hyperfine spectral components are predicted and measured. The hyperfine transitions in the ground, and v₈=1 …
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Date:
May 1988
Creator:
Tam, Hungsze
Partner:
UNT Libraries