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Interfacial Characterization of Chemical Vapor Deposition (Cvd) Grown Graphene and Electrodeposited Bismuth on Ruthenium Surface

Description: Graphene receives enormous attention owing to its distinctive physical and chemical prosperities. Growing and transferring graphene to different substrates have been investigated. The graphene growing on the copper substrate has an advantage of low solubility of carbon on the copper which allow us to grow mostly monolayer graphene. Graphene sheet of few centimeters can be transferred to 300nm silicon oxide and quartz crystal pre-deposited with metal like Cu and Ru. Characterization of the graphene has been done with Raman and contact angle measurement and recently quartz crystal microbalance (QCM) has been employed. The underpotential deposition (UPD) process of Bi on Ru metal surface is studied using electrochemical quartz crystal microbalance (EQCM) and XPS techniques. Both Bi UPD and Bi bulk deposition are clearly observed on Ru in 1mM Bi (NO3)3/0.5M H2SO4. Bi monolayer coverage calculated from mass (MLMass) and from charge (MLCharge) were compared with respect to the potential scanning rates, anions and ambient controls. EQCM results indicate that Bi UPD on Ru is mostly scan rate independent but exhibits interesting difference at the slower scan. Bi UPD monolayer coverage calculated from cathodic frequency change (ΔfCathodic) is significantly smaller than the monolayer coverage derived from integrated charge under the cathodic Bi UPD peak when scan rate is at least 5 mV/s. XPS is utilized to explore the detailed chemical composition of the observed interfacial process of Bi UPD on Ru.
Date: May 2014
Creator: Abdelghani, Jafar
Partner: UNT Libraries

Derivation of the Thematic Material and Intervallic Gestures From the Main Theme in Fantasia Carioca By Sérgio Assad

Description: The quantity of classical guitar literature reached a new peak late in the twentieth century with many famous guitarists publishing their own works for solo classical guitar. This increase in the published guitar literature resulted in a decline of the relative analytical discussions of contemporary guitar works. Sérgio Assad is a perfect example of an active guitarist/composer whose works are frequently performed in guitar recitals and yet very little discussion has been provided attempting to gain a deeper understanding of his compositional language. The purpose of this study is to two-fold: first, to show that Fantasia Carioca (1994) is a very carefully organized work and includes an intricate network of thematic material developed through a spectrum of intervallic gestures, of which all derive from the main theme of the piece; second, to provide a deeper insight into the compositional language of Sérgio Assad through a demonstration of different compositional procedures to which the composer resorts. This one-movement piece reveals a high level of organization present in Sérgio Assad's style. The entire thematic material is carefully derived from the main theme. Each thematic unit shows a set of predetermined characteristics that allow these units to react to particular textures and situations. The thematic organization is interwoven with important intervallic gestures and relationships, which lead the development of the thematic material. The insight into the applied techniques and structural elements provides a highly beneficial pool of information for anybody who decides to perform this piece. The offered arguments also serve as a good starting point for further analytical approaches and examinations of the growing oeuvre of Assad's classical guitar music.
Date: May 2013
Creator: Abdihodži?, Armin
Partner: UNT Libraries

An Analysis of Corporate Accounting and Reporting Practices in Bahrain

Description: The primary objective of this dissertation is to determine the factors that have shaped the corporate financial reporting practices in Bahrain. Prior researchers have offered two explanations, environmental factors and cultural importation, for the emergence of financial reporting practices in developing countries. The environmental explanation suggests that a nation's financial reporting practices will be shaped by its socioeconomic structure. The cultural importation explanation states that the desire for international legitimacy creates incentives for developing nation to adopt Western financial reporting practices. Bahrain provided an excellent environment in which to examine the two explanations since its public and closed corporations have similar economic characteristics. Only public corporations are legally required to publish financial reports. I posited that public corporations would try to gain legitimacy for their published reports by adopting Western standards, while closed corporations would not have a similar incentive. I used an interpretive framework to analyze the Bahrain socioeconomic environment and to examine the general financial reporting practices of Bahraini corporations. I found that closed corporations provided data responsive to the Bahraini environment. Public corporations, however, adopted International Accounting Standards. My analysis supported prior researchers7 findings that colonialism, the need for international legitimacy, and international audit firms were important factors in gaining acceptance for Western accounting practices. The adoption of Western financial reporting practices may be dysfunctional to a developing nation like Bahrain if these practices do not provide relevant information about corporate performance. Therefore, Bahrain, as well as other developing countries, needs to proceed cautiously before adopting Western corporate reporting practices.
Date: December 1993
Creator: Abdul-Rahim, Hassan M.
Partner: UNT Libraries

University-industry Alliances : A Study of Faculty Attitudes Toward the Effects of Alliances on the Governance and Operations of Institutions of Higher Education

Description: The central purpose of this study was to compare the attitudes of faculty in applied sciences to the attitudes of faculty in liberal arts and other selected fields to determine if they differ significantly from each other in their perceptions of the effects of university-industry alliances on campus governance and operations. Secondary purposes were (a) to appraise the debate on alliances and the effects of alliances on academic values and (b) to contribute to the literature concerning alliances and their potential for improving higher education.
Date: August 1992
Creator: Abegunde, Olufemi
Partner: UNT Libraries

Jacques-Antoine-Hippolyte, Comte De Guibert: Father of the Grande Armée

Description: Jacques-Antoine-Hippolyte, comte de Guibert (1743-1790) dedicated his life and career to creating a new doctrine for the French army. Little about this doctrine was revolutionary. Indeed, Guibert openly decried the anarchy of popular participation in government and looked askance at the early days of the Revolution. Rather, Guibert’s doctrine marked the culmination of an evolutionary process that commenced decades before his time and reached fruition in the Réglement of 1791, which remained in force until the 1830s. Not content with military reform, Guibert demanded a political and social constitution to match. His reforms required these changes, demanding a disciplined, service-oriented society and a functional, rational government to assist his reformed military. He delved deeply, like no other contemporary writer, into the linkages between society, politics, and the military throughout his career and his writings. Guibert exerted an overwhelming influence on military thought across Europe for the next fifty years. His military theories provided the foundation for military reform during the twilight of the Old Regime. The Revolution, which adopted most of Guibert’s doctrine in 1791, continued his work. A new army and way of war based on Guibert’s reforms emerged to defeat France’s major enemies. In Napoleon’s hands, Guibert’s army all but conquered Europe by 1807. As other nations adopted French methods, Guibert’s influence spread across the Continent, reigning supreme until the 1830s. This dissertation adopts a biographical approach to examine Guibert’s life and influence on the creation of the French military system that led to Napoleon’s conquest of Europe. As no such biography exists in Anglophone literature, such a work will fill a crucial gap in understanding French military success to 1807. It examines the period of French military reform from 1760 to the creation and use of Napoleon’s Grande Armée from 1803 to 1807, illustrating the importance of ...
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Date: August 2014
Creator: Abel, Jonathan, 1985-
Partner: UNT Libraries

Factors Affecting Academic Interest and Self Perception of Adolescent Hispanic Females

Description: This investigation identifies deterrents to the educational, social, and cultural success of Latina adolescent females. Across the nation, and especially in states such as Texas and California, the Hispanic population is fast becoming the largest minority in society. Because the adolescent Hispanic population within the United States today will comprise much of America's future economic and social base, identifying and addressing educational, cultural, and social deterrents to their success becomes important not only for personal well-being, but for the well-being of future society as a whole. A second purpose was that of determining the efficacy of group-centered psychoeducational therapy in improving self-esteem and decreasing anxiety and depression symptoms in adolescent female Hispanic high school students. The experimental groups consisted of one group of seven female Hispanic adolescents who received computer and internet training and psychoeducational group counseling twice a week for five weeks. and a second group of five female Hispanic adolescents who received computer and internet training and psychoeducational group counseling twice a week for five weeks. The control group consisted of fourteen female Hispanic students who received no treatments. The Beck Depression Inventory was used to measure pre and post test levels of depression, the Beck Anxiety Inventory was used to measure pre and post test levels of anxiety, and the Rosenberg Self-Esteem questionnaire and the Index of Self-Esteem were used to measure pre and post levels of self-esteem.
Date: August 2007
Creator: Abel, Karen
Partner: UNT Libraries

Forest Landscape Dynamics: a Semi-Markov Modeling Approach

Description: A transition model (MOSAIC) is used to describe forest dynamics at the landscape scale. The model uses a semi-Markov framework by considering transition probabilities and Erlang distributed holding times in each transition. Parameters for the transition model are derived from a gap model (ZELIG). This procedure ensures conceptual consistency of the landscape model with the fine scale ecological detail represented by the forest gap model. Spatial heterogeneity in the transition model is driven by maps of terrain with characteristics contained in a Geographic Information System (GIS) database. The results of the transition model simulations, percent cover forest type maps, are exported to grid-maps in the GIS. These cover type maps can be classified and used to describe forest dynamics using landscape statistics metrics. The linkage model-GIS enhances the transition model spatial analytical capabilities. A parameterization algorithm was developed that takes as input gap model tracer files which contain the percent occupation of each cover type through time. As output, the algorithm produces a file that contains the parameter values needed for MOSAIC for each one of the possible transitions. Parameters for the holding time distribution were found by calculating an empirical estimate of the cumulative probability function and using a non-linear least squares method to fit this estimate to an Erlang distribution. The algorithm provided good initial estimates of the transitions parameters that can be refined with few additional simulations. A method for deriving classification criteria to designate cover types is presented. The method uses cluster analysis to detect the number and type of forest classes and Classification and Regression Tree (CART) analysis to explain the forest classes in term of stand attributes. This method provided a precise and objective approach for forest cover type definition and classification. The H. J. Andrews forest in Oregon was used to demonstrate the ...
Date: August 1997
Creator: Ablan, Magdiel
Partner: UNT Libraries

Conglomerate Performance as Influenced by Selected Management Practices

Description: The latest surge of corporate mergers has been characterized by a steadily increasing rate of conglomerate combinations. It would appear that one of the prime motivating factors in conglomerate merger is a firm belief in the principle of "synergism," or the mutually cooperating action of separate substances taken together to produce an effect greater than that of any component taken alone. It would also appear that in such instances wherein there is no direct relationship in regard to raw material source, product development, production technology, or marketing channels, the principle of synergism is not automatic, but must be implemented by appropriate management action. The hypothesis of the study is that the goal of achieving synergism through centrality of management influence has not yet become a reality in conglomerate business organizations as a group. It is the purpose of the study to investigate the degree of centralized management development in a number of management functions and relate this development to success in selected performance areas.
Date: May 1973
Creator: Ablowich, Edgar Allen, 1913-
Partner: UNT Libraries

A Study of the Relationship Between the Levels of Self-Awareness within Students Enrolled in Counseling Practicum and the Measurements of Their Counseling Effectiveness

Description: Counselor self-awareness is considered an important aspect of counseling effectiveness according to the American Counseling Association and the American Psychological Association and in numerous studies and articles within the counseling literature. With the effort to improve the effectiveness of counseling practicum students comes the need to understand the relationship between effectiveness ratings and the levels of counselor self-awareness. Gestalt Therapy literature, and the development of the Personal Orientation Inventory (Shostrom, 1963) provided the working definition of self-awareness in this study. Research and evaluation are means for improving the correlation between students' characteristics in counselor training programs and their effectiveness as perceived by faculty and doctoral supervisors. The purpose of this study was to determine the effects of practicum students' ages and their levels of self-awareness upon counseling effectiveness as measured by faculty and doctoral supervisors in a university clinic setting. Twenty-nine students who were enrolled in four practicum classes were administered the Personal Orientation Instrument. Four faculty supervisors and eight doctoral supervisors were administered the Counselor Effectiveness Rating Scale (Myrick & Kelley, 1971). The instruments were administered in the tenth week of the counseling practicum semester. Analyses of the data revealed a statistically significant interaction between the older practicum students' levels of self-awareness and their counselor effectiveness as rated by the more experienced faculty supervisors. Further analyses of the data revealed that there was a statistically significant main effect between the practicum students' age groups and their counselor effectiveness as rated by the less experienced doctoral supervisors.
Date: August 2002
Creator: Abney, Paul C.
Partner: UNT Libraries

Boosting for Learning From Imbalanced, Multiclass Data Sets

Description: In many real-world applications, it is common to have uneven number of examples among multiple classes. The data imbalance, however, usually complicates the learning process, especially for the minority classes, and results in deteriorated performance. Boosting methods were proposed to handle the imbalance problem. These methods need elongated training time and require diversity among the classifiers of the ensemble to achieve improved performance. Additionally, extending the boosting method to handle multi-class data sets is not straightforward. Examples of applications that suffer from imbalanced multi-class data can be found in face recognition, where tens of classes exist, and in capsule endoscopy, which suffers massive imbalance between the classes. This dissertation introduces RegBoost, a new boosting framework to address the imbalanced, multi-class problems. This method applies a weighted stratified sampling technique and incorporates a regularization term that accommodates multi-class data sets and automatically determines the error bound of each base classifier. The regularization parameter penalizes the classifier when it misclassifies instances that were correctly classified in the previous iteration. The parameter additionally reduces the bias towards majority classes. Experiments are conducted using 12 diverse data sets with moderate to high imbalance ratios. The results demonstrate superior performance of the proposed method compared to several state-of-the-art algorithms for imbalanced, multi-class classification problems. More importantly, the sensitivity improvement of the minority classes using RegBoost is accompanied with the improvement of the overall accuracy for all classes. With unpredictability regularization, a diverse group of classifiers are created and the maximum accuracy improvement reaches above 24%. Using stratified undersampling, RegBoost exhibits the best efficiency. The reduction in computational cost is significant reaching above 50%. As the volume of training data increase, the gain of efficiency with the proposed method becomes more significant.
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Date: December 2013
Creator: Abouelenien, Mohamed
Partner: UNT Libraries

Proton-Induced L-shell X-Rays of Pr, Sm, Eu, Gd, and Dy

Description: Characteristic L-shell x rays of the five rare earths Pr, Sm, Eu, Gd, and Dy were studied in this work. The x rays were produced by ionization from 0.3 to 2.0 MeV protons from the 2.0 MV Van de Graaff at North Texas State University. Total L-shell ionization and x-ray production cross sections were measured for Sm and compared to the BEA, CBEA and PWBA theories. Total L-shell ionization cross sections were measured for Pr, Eu, Gd, and Dy and compared to the BEA, CBEA, and PWBA. The CBEA and PWBA fit the samarium data well for both ionization and x-ray production cross sections. The BEA was generally 40 per cent lower than the data. The CBEA and the PWBA also fit the ionization cross section data for Pr, Eu, Gd and Dy, while the BEA was generally 40 per cent lower than the data.
Date: August 1974
Creator: Abrath, Frederick G.
Partner: UNT Libraries

Application of Synthetic Peptides as Substrates for Reversible Phosphorylation

Description: Two highly homologous synthetic peptides MLC(3-13) (K-R-A-K-A-K-T-TK-K-R-G) and MLC(5-13) (A-K-A-K-T-T-K-K-R-G) corresponding to the amino terminal amino acid sequence of smooth muscle myosin light chain were utilized as substrates for protein kinase C purified from murine lymphosarcoma tumors to determine the role of the primary amino acid sequence of protein kinase C substrates in defining the lipid (phosphatidyl serine and diacylglycerol) requirements for the activation of the enzyme. Removal of the basic residues lysine and arginine from the amino terminus of MLC(3-13) did not have a significant effect on the Ka value of diacylglycerol. The binding of effector to calcium-protein kinase C appears to be random since binding of one effector did not block the binding of the other.
Date: August 1992
Creator: Abukhalaf, Imad Kazem
Partner: UNT Libraries

Corporate Christians and Terrible Turks: Economics, Aesthetics, and the Representation of Empire in the Early British Travel Narrative, 1630 - 1780

Description: This dissertation examines the evolution of the early English travel narrative as it relates to the development and application of mercantilist economic practices, theories of aesthetic representation, and discourses of gender and narrative authority. I attempt to redress an imbalance in critical work on pre-colonialism and colonialism, which has tended to focus either on the Renaissance, as exemplified by the works of critics such as Stephen Greenblatt and John Gillies, or on the later eighteenth and early nineteenth centuries, as in the work of scholars such as Srinivas Aravamudan and Edward Said. This critical gap has left early travel narratives by Sir Francis Moore, Jonathan Harris, Penelope Aubin, and others largely neglected. These early writers, I argue, adapted the conventions of the travel narrative while relying on the authority of contemporary commercial practices. The early English travelers modified contemporary conventions of aesthetic representation by formulating their descriptions of non-European cultures in terms of the economic and political conventions and rivalries of the early eighteenth century. Early English travel literature, I demonstrate, functioned as a politically motivated medium that served both as a marker of authenticity, justifying the colonial and imperial ventures that would flourish in the nineteenth century, and as a forum for experimentation with English notions of gender and narrative authority.
Date: December 2003
Creator: Abunasser, Rima Jamil
Partner: UNT Libraries

Exploratory Analysis of Social E-health Behavior

Description: Extant literature has documented well that people seek health information via the internet as patients and consumers. Much less, however, is known about interaction and creation behaviors in the development of new online health information and knowledge. More specifically, generalizable sociodemographic data on who engages in this online health behavior via social media is lacking in the sociological literature. The term “social e-health” is introduced to emphasize the difference between seeking behaviors and interaction and creation behaviors. A 2010 dataset of a large nationally representative and randomly sampled telephone survey made freely available from the Pew Research Center is used to examine social e-health behavior according to respondents’ sociodemographics. The dependent variable of social e-health behavior is measured by 13 survey questions from the survey. Gender, race, ethnicity, age, education, and income are used as independent variables. Logistic regression analysis was used to determine the odds of engagement in social e-health behavior based on the sociodemographic predictors. The social determinants of health and digital divide frameworks are used to help explain why socioeconomic variances exist in social e-health behavior. The findings of the current study suggest that predictable sociodemographic patterns along the dimensions of gender, race, age, education, and income exist for those who report engaging in social e-health behavior. This study is important because it underscores the fact that engagement in social e-health behavior is differentially distributed in the general U.S. population according to patterned sociodemographics.
Date: May 2014
Creator: Acadia, Spencer
Partner: UNT Libraries

Cooperative Strategy and Sources of Knowledge Integration Capability and Innovation: A Relational View

Description: Faced with the challenges to addressing the novelties of the changing business environments (e.g., new customer requirement, changes in customers taste and preferences, the introduction of new products or services by competitors), organizations seek to build collaboration among their employees who possess complementary knowledge. Integrating complementary knowledge enhances employees' ability to address environmental challenges and foster innovation. Despite the importance of knowledge integration for innovation, integration of such knowledge becomes difficult when employees lack a shared understanding of knowledge, and when the knowledge is newly generated. Because new knowledge is tacit in nature and highly personal to a particular individual, it is difficult to articulate, making knowledge integration (KI) an arduous task. Lack of shared understanding, the presence of new knowledge, and lack of common interests in employees creates three types of knowledge boundaries – syntactic (information processing) boundaries, semantic (interpretive) boundaries, and pragmatic (political) boundaries. The presence of knowledge boundaries makes it difficult for employees to share and access their knowledge with each other. To overcome the challenges related to the knowledge boundaries, employees use boundary-spanning objects, which are common lexicons, common meaning, and common interests, to share and access their knowledge across the boundaries. Although prior studies have emphasized the importance of knowledge integration of various knowledge sources for innovations, examinations of what enhances KI capability of employees for organizational innovation remain limited. In addition, apart from Carlile, (2004) and Franco (2013), which are both case studies, other studies that examine the role of boundary spanning objects for knowledge integration are missing. The knowledge management literature also fails to measures (the success of common lexicons, common meaning, and common interests for achieving KI capability) boundary spanning objects. Therefore, in this study, new measurement items of boundary spanning objects and novelty are developed to test the hypotheses. A survey-based ...
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Date: August 2016
Creator: Acharya, Chandan
Partner: UNT Libraries

Love Attitudes and Marital Adjustment Through Five Stages of the Marital Life-Cycle in Protestant Nigerian Society

Description: This study examined the relationship between love attitude and marital adjustment across five stages of the marital life-cycle in Nigerian society. The subjects for this study were 202 volunteers from six protestant churches representing six cities in the southern part of Nigeria. An average of 20 couples were representatives of each of the five marital life-cycles. Each of the subjects completed the Love Attitude Inventory (LAI), and the Marital Adjustment Test (short form) (MAT). Wilk's multivariate analysis revealed no significant differences between husbands' and wives' love attitude and marital adjustment across the five stages of the marital life cycle. Multivariate analysis split-plot 5.2 with repeated measures revealed no significant difference for the total sample among the groups, but indicated a significant difference between love attitude and marital adjustment for the total sample using sex as a factor. A univariate test of the MAT and LAI indicated that the MAT accounted for the difference. A canonical correlation indicated a significant positive relationship between husbands1 and wives' marital adjustment and love attitude within each of the five groups. The findings suggest that husbands and wives included in this study have a good understanding of their roles in the marriage relationship and that the partners have general agreement regarding those roles. The marriage partners apparently have strong influences on each other's perceptions of love attitude and marital adjustment.
Date: December 1988
Creator: Acho, Onyebuchi S. (Onyebuchi Sunday)
Partner: UNT Libraries

Haves, Halves, and Have-Nots: School Libraries and Student Achievement in California

Description: This descriptive, non-experimental study examines the strength of the relationship between California school library media programs and student achievement, using data from California criterion-referenced state-wide tests, publically available school and community demographic data, and a state survey of school library programs. Results indicate a substantial discrepancy in library staffing levels from the elementary grades through the high schools. Nevertheless, statistically significant correlations were found between certificated staffing levels and student achievement at each grade. Significant correlations persisted at the elementary and middle school when controlling for five of six school and community variables, and at the high school when controlling for all six of those variables. Bivariate correlations between total staffing and student achievement were significant at both the middle school and high school level when controlling for all school and community variables. Generally, the strength of the correlations between both certificated and total staffing tended to increase with grade level; at the high school level, correlations were among the strongest reported in any statewide study to date. There was a significant positive relationship between a majority of the 21 library services regularly provided and student achievement at all levels. Total library services were significantly related to student achievement at all levels when controlling for all school and community variables. In multiple regression analyses, there was an increasingly stronger relationship between total library programs and student achievement by grade level when controlling for all school and community variables. At every level, certificated and total staffing levels were associated with the strength of library program elements. The findings from this study confirm a host of prior research on the relationship between school libraries and student achievement and point to inequitable access to school library services in California. Results from this study might also provide a baseline of data for qualitative research ...
Date: December 2008
Creator: Achterman, Douglas L.
Partner: UNT Libraries