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Design, Synthesis and Study of Supramolecular Donor – Acceptor Systems Mimicking Natural Photosynthesis Processes

Description: This dissertation investigates the chemical ingenuity into the development of various photoactive supramolecular donor – acceptor systems to produce clean and carbon free energy for the next generation. The process is inspired by the principles learned from nature’s approach where the solar energy is converted into the chemical energy through the natural photosynthesis process. Owing to the importance and complexity of natural photosynthesis process, we have designed ideal donor-acceptor system… more
Date: December 2015
Creator: KC, Chandra Bikram
Partner: UNT Libraries
open access

Molecules and Materials for Excitonic Solar Cells Using P-type Metal Oxide Semiconductors

Description: This dissertation has two intersecting foci; firstly, the discovery of a new methodology for the growth of high surface area cuprous oxide (Cu2O) substrates. Secondly, the synthesis and characterization of electron-accepting molecules, and their incorporation into excitonic solar cells (XSCs) using the Cu2O substrates as electrodes. Increasing the surface area of the semiconductor creates more locations for charge transfer to occur thus increasing the overall efficiency of the device. Zinc oxid… more
Date: August 2015
Creator: Haynes, Keith M.
Partner: UNT Libraries
open access

Self-assembly Polymeric Nanoparticles Composed of Polymers Crosslinked with Transition Metals for Use in Drug Delivery

Description: A major drawback of chemotherapy is the lack of selectively leading to damage in healthy tissue, which results in severe acute side effects to cancer patients. The use of nanoparticles as a drug delivery system has emerged as novel strategy to overcome the barriers of immunogenic response, controlled release of therapeutic, and targeting the toxicity only to cancerous cells. In this study, polymeric nanoparticles composed of transition metals and particles derived from natural biopolymers hav… more
Date: December 2015
Creator: Nguyen, Duong Thuy
Partner: UNT Libraries
open access

Synthesis of Peropyrene and Tetracene Derivatives for Photochemical Applications

Description: A novel route for the synthesis of the polycyclic aromatic hydrocarbon peropyrene (Pp) is reported along with the efforts to synthesize derivatives of Pp, 2,2′- and 5,5′-linked tetracene dimers as candidates for study as singlet fission materials in photovoltaic devices. Peropyrene was synthesized by the McMurry coupling conditions from phenalenone and low-valent titanium species. The crystal structure of Pp is formed by π-stacked molecular pairs in a herringbone arrangement. The direct functio… more
Date: May 2015
Creator: Rodríguez López, Marco Tulio
Partner: UNT Libraries
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