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Characteristics of Primary Cilia and Centrosomes in Neuronal and Glial Lineages of the Adult Brain

Description: Primary cilia are sensory organelles that are important for initiating cell division in the brain, especially through sonic hedgehog (Shh) signaling. Several lines of evidence suggest that the mitogenic effect of Shh requires primary cilia. Proliferation initiated by Shh signaling plays key roles in brain development, in neurogenesis in the adult hippocampus, and in the generation of glial cells in response to cortical injury. In spite of the likely involvement of cilia in these events, little is known about their characteristics. Centrosomes, which are associated with primary cilia, also have multiple influences on the cell cycle, and they are important in assembling microtubules for the maintenance of the cell’s cytoskeleton and cilia. The cilia of terminally differentiated neurons have been previously examined with respect to length, incidence, and receptors present. However, almost nothing is known about primary cilia in stem cells, progenitors, or differentiated glial cells. Moreover, it is not known how the properties of cilia and centrosomes may vary with cell cycle or proliferative potential, in brain or other tissues. This dissertation focuses first on neurogenesis in the hippocampal subgranular zone (SGZ). The SGZ is one of the few brain regions in mammals that gives rise to a substantial number of new neurons throughout adulthood. The neuron lineage contains a progression of identifiable precursor cell types with different proliferation rates. This present study found that primary cilia were present in every cell type in the neuronal lineage in SGZ. Cilium length and incidence were positively correlated among these cell types. Ciliary levels of adenylyl cyclase type III (ACIII) levels relative to ADP-ribosylation factor-like protein 13b (Arl13b) was higher in neurons than in precursor cells and glia, and also changed with the cell cycle. G-protein coupled receptors, SstR3, MCHR1, and Gpr161 receptors were only found in neuronal cilia. The levels ...
Date: May 2015
Creator: Bhattarai, Samip Ram
Partner: UNT Libraries

Child Rescue As Survival Resistance: Hidden Children in Nazi-occupied Western Europe

Description: The phenomenon of rescue organizations that devoted themselves specifically to hiding and saving Jewish children appeared throughout Nazi-occupied Western Europe (France, Belgium, and the Netherlands). Jewish and non-Jewish rescuers risked their lives to save thousands of children from extermination. This dissertation adds to the historiographical understanding of Holocaust resistance by analyzing the efforts of these child rescue organizations as a form of “survival resistance.” Researching the key aspects of traditional resistance (conscious intent, extensive organization, and effective turn-out) demonstrates that, while child rescue did not present armed resistance, it still was a form of active resistance against the Nazi Final Solution. By looking at rescuers’ testimonies and archival sources (from Yad Vashem, United States Holocaust Memorial Museum, Centre de documentation juive contemporaine, and Kazerne Dossin), this dissertation first outlines the extensive organization and intent of Jewish rescue groups, such as the Oeuvre de Secours aux Enfants (OSE) and Comité de défense des Juifs (CDJ), in France, Belgium, and the Netherlands. The second part looks at rescue organization and intent by Catholic, Protestant, and humanitarian groups. The dissertation concludes by discussing the effectiveness of organized child rescue. In the end, the rescue groups saved thousands of children and proofs that Child rescue in Nazi-occupied Western Europe was a valid--not to mention heroic--form of survival resistance.
Date: August 2012
Creator: Decoster, Charlotte Marie-Cecile Marguerite
Partner: UNT Libraries

El Cine De Terror Español Como Espejo De La Cultura Española

Description: This study traces the history and culture of Spain as seen through the lens of the nation´s production of horror cinema. Starting from the boom of Spanish horror film in the early 1960s, the thesis compares and contrasts the political and social aspects of Spanish society throughout three distinct eras of the 20th century: 1962 – 1975 (the boom of Spanish horror film through the Franco dictatorship), 1975 – 1999 (the transition to democracy through the end of the 20th century) and 2000 – present (the 21st century). Movies as diverse as Gritos en la noche (1962, Jesús Franco), ¿Quién puede matar a un niño? (1976, Narciso Ibáñez Serrador) and Angustia (1987, Bigas Luna) are framed by culturally-related anectodes as well as correlations to their respective social environments. Special attention has been paid to the production and release of each film, especially in regards to censorship during the Franco dictatorship. The results show that Spanish horror cinema has acted as a true mirror to culture, society and politics in its native country throughout the 20th century and that this trend will likely extend in to the future.
Date: May 2014
Creator: Donahue, Tyler
Partner: UNT Libraries

Clocks and Mirrors

Description: The essays featured in this collection highlight the gaps, as well as parallels, between mental illness and the human condition. In "Appearances," the narrator struggles with her own visual identity especially after reflecting on her Mom's own lengthy history with the mirror. In "Migrations," the lyrical voice of the narrator carries the reader through the typical day of a clinically depressed female character. Lastly, "Attempting the Fall," addresses the issues society has with mental illness by following the narrator from her suicide attempt to the mental ward.
Date: December 2016
Creator: Thies, Jaclyn Michele
Partner: UNT Libraries

Community-based Logistics and Supply Chain Management: Developing, Testing and Validating Conceptual Models

Description: The field of Logistics and Supply Chain Management (LSCM) suggests that transactions, collaboration, and value are important in the supply and delivery of products and services to meet the need of impoverished end-consumers. In many cases, the application of LSCM is paramount in most strategic decision-making efforts. Therefore, this research explores the applications of LSCM processes and activities within the community-based context. The methodology used to address the research questions consisted of a hybrid of mixed methods. This mixed methodology provides three essays that investigate the application and development of LSCM in the community-based context. The essays address the flow of charitable products and services through supply chains. The dissertation does not pay close attention to the first-tier suppliers’ suppliers, which is looking at the originating flow of goods and services (raw materials, manufacturing, etc.). However, the dissertation puts a focus on products and services supplied to focal organizations and how these products are then passed on to end-consumers. Essay I looks at the transaction (costs) that ensue from the supply of charitable products. Essay II analyzes a social service ecosystem and investigates how the network of organizations enable the distribution of charitable products and services. Lastly, Essay III examines the delivery of valuable services to the end-consumers, and what tools Community-Based Enterprises (CBEs) should focus on to develop and retain end-consumers in impoverished communities. The research provides conceptual models that review some fundamental LSCM achievement gaps in supplying, delivering and providing social services to end users within impoverished communities. The dissertation draws upon literature from the fields of economics, marketing, social science, and logistics and supply chain management. The dissertation uses the primary research method of unstructured and semi-structured interviews, case studies, written survey instruments and system dynamics within three studies. The studies resolve to look into the term ...
Date: May 2016
Creator: Obaze, Yolanda
Partner: UNT Libraries

A Comparative Analysis of Digital and Paper Restaurant Menus Based on Customer Perception and Nutritional Labeling

Description: The restaurant industry is a highly customer-driven field. Therefore, it is imperative that restaurateurs consider customer expectations with regard to restaurant menus. The purpose of this experimental study is to examine the effects of menu format (i.e., paper or digital) and amount of nutritional information (i.e., extensive, brief, or none) on customer perceptions of the effectiveness, perceived ease of use, and information quality of the menu. Furthermore, this research intends to test the effect of these three menu attributes on the outcomes of value and satisfaction in order to assess the competitive advantage of one format over the other. The Cognitive Appraisal and Information Processing Theories provide structure to the proposed conceptual framework and give credence to the findings. This study also fills gaps in the present research by not only ameliorating weaknesses of extant studies, but also by examining several different aspects of restaurant menus simultaneously within a single study.
Date: December 2016
Creator: Moody, Bailey
Partner: UNT Libraries

Competing Models of Hegemonic Masculinity in English Civil War Memoirs by Women

Description: This thesis examines the descriptions of Royalist and Parliamentarian masculinity in English Civil War memoirs by women through a close reading of three biographical memoirs written by Margaret Cavendish, duchess of Newcastle; Lady Ann Fanshawe; and Lucy Hutchinson. Descriptions of masculinity are evaluated through the lens of Raewyn Connell's theory of hegemonic masculinity to understand the impact two competing models of masculinity had on the social and political culture of the period. The prevailing Parliamentarian hegemonic masculinity in English Civil War memoirs is traced to its origins before the English Civil War to demonstrate how hegemonic masculinity changes over time. The thesis argues that these memoirs provide evidence of two competing models of Royalist and Parliamentarian masculinities during the Civil War that date back to changes in the Puritan meaning of the phrase “man of merit”, which influenced the development of a Parliamentarian model of masculinity.
Date: December 2015
Creator: Du Bon-Atmai, Evelyn
Partner: UNT Libraries

Compostable Soy-Based Polyurethane Foam with Kenaf Core Modifiers

Description: Building waste and disposable packaging are a major component in today's landfills. Most of these are structural or thermally insulative polymer foams that do not degrade over a long period of time. Currently, there is a push to replace these foams with thermoplastic or biodegradable foams that can either be recycled or composted. We propose the use of compostable soy-based polyurethane foams (PU) with kenaf core modifiers that will offer the desired properties with the ability to choose responsible end-of-life decisions. The effect of fillers is a critical parameter in investigating the thermal and mechanical properties along with its effect on biodegradability. In this work, foams with 5%, 10%, and 15% kenaf core content were created. Two manufacturing approaches were used: the free foaming used by spray techniques and the constrained expansion complementary to a mold cavity. Structure-property relations were examined using differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), thermal conductivity, compression values, scanning electron microscopy (SEM), x-ray micro-computed tomography (micro-CT), and automated multiunit composting system (AMCS). The results show that mechanical properties are reduced with the introduction of kenaf core reinforcement while thermal conductivity and biodegradability display a noticeable improvement. This shows that in application properties can be improved while establishing a responsible end-of-life choice.
Date: August 2016
Creator: Hoyt, Zachary
Partner: UNT Libraries

A Comprehensive Modeling Framework for Airborne Mobility

Description: Mobility models serve as the foundation for evaluating and designing airborne networks. Due to the significant impact of mobility models on the network performance, mobility models for airborne networks (ANs) must realistically capture the attributes of ANs. In this paper, I develop a comprehensive modeling framework for ANs. The work I have done is concluded as the following three parts. First, I perform a comprehensive and comparative analysis of AN mobility models and evaluate the models based on several metrics: 1) networking performance, 2) ability to capture the mobility attributes of ANs, 3) randomness levels and 4) associated applications. Second, I develop two 3D mobility models and realistic boundary models. The mobility models follow physical laws behind aircraft maneuvering and therefore capture the characteristics of aircraft trajectories. Third, I suggest an estimation procedure to extract parameters in one of the models that I developed from real flight test data. The good match between the estimated trajectories and real flight trajectories also validate the suitability of the model. The mobility models and the estimation procedure lead to the creation of “realistic” simulation and evaluation environment for airborne networks.
Date: December 2013
Creator: Xie, Junfei
Partner: UNT Libraries

The Contribution of Mira Behn and Sarala Behn to Social and Environmental Transformation in the Indian State of Uttarakhand

Description: The influence of Mohandas K. Gandhi on social and environmental movements in post-colonial India has been widely acknowledged. Yet, the contributions of two European associates of Gandhi, Madeleine Slade and Catherine Mary Heilemann, better known in India as Mira Behn and Sarala Behn, have not received the due attention of the academic community. This dissertation is an examination of the philosophy and social activism of Mira Behn and Sarala Behn and their roles in the evolution of Gandhian philosophy of socioeconomic reconstruction and environmental conservation in the present Indian state of Uttarakhand. Instead of just being acolytes of Gandhi, I argue that these women developed ideas and practices that drew upon from an extensive intellectual terrain that cannot be limited to Gandhi’s work. I delineate the directions in which Gandhian thought and experiments in rural development work evolved through the lives, activism, and written contributions of these two women. Particularly, I examine their influence on social and environmental movements, such as the Chipko and the Anti-Tehri Dam movements, and their roles in promoting grassroots social development and environmental sustainability in the mountain communities of Uttarakhand. Mira Behn and Sarala Behn’s integrative philosophical worldviews present epistemological, sociopolitical, ethical, and metaphysical principles and practices that have local and global significance for understanding interfaith dialog, social justice, and environmental sustainability and thus constitute a useful contribution to the theory and practice of human emancipation in our times.
Date: May 2014
Creator: Mallik, Bidisha
Partner: UNT Libraries

Control and Automation of a Heat Shrink Tubing Process

Description: Heat shrink tubing is used to insulate wire conductors, protect wires, and to create cable entry seals in wire harnessing industries. Performing this sensitive process manually is time consuming, the results are strongly dependent on the operator’s expertise, and the process presents safety concerns. Alternatively, automating the process minimizes the operators’ direct interaction, decreases the production cost over the long term, and improves quantitative and qualitative production indicators dramatically. This thesis introduces the automation of a heat shrink tubing prototype machine that benefits the wire harnessing industry. The prototype consists of an instrumented heat chamber on a linear positioning system, and is fitted with two heat guns. The chamber design allows for the directing of hot air from the heat guns onto the wire harness uniformly through radially-distributed channels. The linear positioning system is designed to move the heat chamber along the wire harness as the proper shrinkage temperature level is reached. Heat exposure time as a major factor in the heat shrink tubing process can be governed by controlling the linear speed of the heat chamber. A control unit manages the actuator position continuously by measuring the chamber’s speed and temperature. A model-based design approach is followed to design and test the controller, and MATLAB/Simulink is used as the simulation environment. A programmable logic controller is selected as the controller implementation platform. The control unit performance is examined and its responses follow the simulation results with adequate accuracy.
Date: August 2014
Creator: Yousefi Darani, Shahrokh
Partner: UNT Libraries

Cooperative Strategy and Sources of Knowledge Integration Capability and Innovation: A Relational View

Description: Faced with the challenges to addressing the novelties of the changing business environments (e.g., new customer requirement, changes in customers taste and preferences, the introduction of new products or services by competitors), organizations seek to build collaboration among their employees who possess complementary knowledge. Integrating complementary knowledge enhances employees' ability to address environmental challenges and foster innovation. Despite the importance of knowledge integration for innovation, integration of such knowledge becomes difficult when employees lack a shared understanding of knowledge, and when the knowledge is newly generated. Because new knowledge is tacit in nature and highly personal to a particular individual, it is difficult to articulate, making knowledge integration (KI) an arduous task. Lack of shared understanding, the presence of new knowledge, and lack of common interests in employees creates three types of knowledge boundaries – syntactic (information processing) boundaries, semantic (interpretive) boundaries, and pragmatic (political) boundaries. The presence of knowledge boundaries makes it difficult for employees to share and access their knowledge with each other. To overcome the challenges related to the knowledge boundaries, employees use boundary-spanning objects, which are common lexicons, common meaning, and common interests, to share and access their knowledge across the boundaries. Although prior studies have emphasized the importance of knowledge integration of various knowledge sources for innovations, examinations of what enhances KI capability of employees for organizational innovation remain limited. In addition, apart from Carlile, (2004) and Franco (2013), which are both case studies, other studies that examine the role of boundary spanning objects for knowledge integration are missing. The knowledge management literature also fails to measures (the success of common lexicons, common meaning, and common interests for achieving KI capability) boundary spanning objects. Therefore, in this study, new measurement items of boundary spanning objects and novelty are developed to test the hypotheses. A survey-based ...
Date: August 2016
Creator: Acharya, Chandan
Partner: UNT Libraries

"Counting Out The Harvest"

Description: "Counting Out The Harvest" is a collection of poems exploring intimate encounters. The poems reflect on encounters with memories, family, and the natural and cosmic worlds. In one of the poems, "Red-Throated Anole," the speaker works desperately to save a small dying lizard. In "Ice Storm, Post-Divorce," the speaker attempts to decipher a cluster of ladybugs taking refuge in her room. In the title poem, a couple wonders patiently if their crop will eventually grow. In each of these poems there is a present longing for the construction of a meaningful identity by means of the encounter, but the intersection between speaker and world falls short of satisfaction, whether the faultiness lies in the body's inability to find full sustenance, or in the ever-changing fluidity of memory to find stability. But the poems progress from pressing against this difficulty toward finding a contented resignation to the world's cyclical order. The final line of the manuscript, "disrobe a layer to begin again," indicates an arrival at satisfaction, which is found ultimately in continuation.
Date: August 2016
Creator: Lischau, Carol
Partner: UNT Libraries

Customers' Attitudes toward Mobile Banking Applications in Saudi Arabia

Description: Mobile banking services have changed the design and delivery of financial services and the whole banking sector. Financial service companies employ mobile banking applications as new alternative channels to increase customers' convenience and to reduce costs and maintain profitability. The primary focus of this study was to explore the Saudi bank customers' perceptions about the adoption of mobile banking applications and to test the relationships between the factors that influence mobile banking adoption as independent variables and the action to adopt them as the dependent variable. Saudi customers' perceptions were tested based on the extended versions of IDT, TAM and other diffusion of innovation theories and frameworks to generate a model of constructs that can be used to study the use and the adoption of mobile technology by users. Koenig-Lewis, Palmer, & Moll's (2010) model was used to test its constructs of (1) perceived usefulness, (2) perceived ease of use, (3) perceived compatibility, (4) perceived credibility, (5) perceived trust, (6) perceived risk, and (7) perceived cost, and these were the independent variables in current study. This study revealed a high level of adoption that 82.7% of Saudis had adopted mobile banking applications. Also, the findings of this study identified a statistically significant relationship between all of demographic differences: gender, education level, monthly income, and profession and mobile banking services among adopters and non-adopters. Seven attributes relating to the adoption of mobile banking applications were evaluated in this study to assess which variables affected Saudi banks customers in their adoption of mobile banking services. The findings indicated that the attributes that significantly affected the adoption of mobile banking applications among Saudis were perceived trust, perceived cost, and perceived risk. These three predictors, as a result, explained more than 60% of variance in intention to adopt mobile banking technology in Saudi Arabia. ...
Date: August 2016
Creator: Alshara, Mohammed Ali
Partner: UNT Libraries

Daily-collected Sleep Diaries Compared to Weekly-collected Sleep Diaries Via Actigraph Concordance

Description: Both sleep diaries and actigraphy have been recommended to assess sleep in research and clinical settings. Investigators have traditionally used sleep diaries that were completed daily by participants and collected weekly but have recently begun using sleep diaries that are both completed and collected daily. No research had previously assessed the agreement between daily-collected sleep diaries and actigraph data over one week. Undergraduate students were randomly assigned to use daily- or weekly-collected sleep diaries. Sleep parameters obtained from these measures were compared to each other via concordance with concurrent actigraph data. It was hypothesized that daily-collected sleep diaries would have greater concordance with actigraphy than weekly-collected sleep diaries. Results indicated that daily-collected sleep diaries provided more reliable data than weekly-collected sleep diaries, but the differences were not statistically significant. Additional aims examined self-reported sleep diary adherence, the participation day number, and day of the week. There were trends for the Daily group to have better adherence. Overall concordance did not change based on the day number or day of the week. Both sleep diaries yield comparable sleep parameter data, suggesting that clinicians and researchers can use either method to estimate sleep parameters.
Date: May 2014
Creator: Francetich, Jade M.
Partner: UNT Libraries

Data Compression Using a Multi-residue System (Mrs)

Description: This work presents a novel technique for data compression based on multi-residue number systems. The basic theorem is that an under-determined system of congruences could be solved to accomplish data compression for a signal satisfying continuity of its information content and bounded in peak-to -peak amplitude by the product of relatively prime moduli,. This thesis investigates this property and presents quantitative results along with MATLAB codes. Chapter 1 is introductory in nature and Chapter 2 deals in more detail with the basic theorem. Chapter 3 explicitly mentions the assumptions made and chapter 4 shows alternative solutions to the Chinese remainder theorem. Chapter 5 explains the experiments in detail whose results are mentioned in chapter 6. Chapter 7 concludes with a summary and suggestions for future work.
Date: August 2012
Creator: Melaedavattil Jaganathan, Jyothy
Partner: UNT Libraries

Data-Driven Decision-Making Framework for Large-Scale Dynamical Systems under Uncertainty

Description: Managing large-scale dynamical systems (e.g., transportation systems, complex information systems, and power networks, etc.) in real-time is very challenging considering their complicated system dynamics, intricate network interactions, large scale, and especially the existence of various uncertainties. To address this issue, intelligent techniques which can quickly design decision-making strategies that are robust to uncertainties are needed. This dissertation aims to conquer these challenges by exploring a data-driven decision-making framework, which leverages big-data techniques and scalable uncertainty evaluation approaches to quickly solve optimal control problems. In particular, following techniques have been developed along this direction: 1) system modeling approaches to simplify the system analysis and design procedures for multiple applications; 2) effective simulation and analytical based approaches to efficiently evaluate system performance and design control strategies under uncertainty; and 3) big-data techniques that allow some computations of control strategies to be completed offline. These techniques and tools for analysis, design and control contribute to a wide range of applications including air traffic flow management, complex information systems, and airborne networks.
Date: August 2016
Creator: Xie, Junfei
Partner: UNT Libraries

Decision Makers’ Cognitive Biases in Operations Management: An Experimental Study

Description: Behavioral operations management (BOM) has gained popularity in the last two decades. The main theme in this new stream of research is to include the human behavior in Operations Management (OM) models to increase the effectiveness of such models. BOM is classified into 4 areas: cognitive psychology, social psychology, group dynamics and system dynamics (Bendoly et al. 2010). This dissertation will focus on the first class, namely cognitive psychology. Cognitive psychology is further classified into heuristics and biases. Tversky and Kahneman (1974) discussed 3 heuristics and 13 cognitive biases that usually face decision makers. This dissertation is going to study 6 cognitive biases under the representativeness heuristic. The model in this dissertation states that cognitive reflection of the individual (Frederick 2005) and training about cognitive biases in the form of warning (Kaufmann and Michel 2009) will help decisions’ makers make less biased decisions. The 6 cognitive biases investigated in this dissertation are insensitivity to prior probability, insensitivity to sample size, misconception of chance, insensitivity to predictability, the illusion of validity and misconception of regression. 6 scenarios in OM contexts have been used in this study. Each scenario corresponds to one cognitive bias. Experimental design has been used as the research tool. To see the impact of training, one group of the participants received the scenarios without training and the other group received them with training. The training consists of a brief description of the cognitive bias as well as an example of the cognitive bias. Cognitive reflection is operationalized using cognitive reflection test (CRT). The survey was distributed to students at University of North Texas (UNT). Logistic regression has been employed to analyze data. The research shows that participants show the cognitive biases proposed by Tversky and Kahneman. Moreover, CRT is significant factor to predict the cognitive bias in two ...
Date: May 2016
Creator: Alkhars, Mohammed
Partner: UNT Libraries

Decision-Making with Big Information: The Relationship between Decision Context, Stopping Rules, and Decision Performance

Description: Ubiquitous computing results in access to vast amounts of data, which is changing the way humans interact with each other, with computers, and with their environments. Information is literally at our fingertips with touchscreen technology, but it is not valuable until it is understood. As a result, selecting which information to use in a decision process is a challenge in the current information environment (Lu & Yuan, 2011). The purpose of this dissertation was to investigate how individual decision makers, in different decision contexts, determine when to stop collecting information given the availability of virtually unlimited information. Decision makers must make an ultimate decision, but also must make a decision that he or she has enough information to make the final decision (Browne, Pitts, & Wetherbe, 2007). In determining how much information to collect, researchers found that people engage in ‘satisficing' in order to make decisions, particularly when there is more information than it is possible to manage (Simon, 1957). A more recent elucidation of information use relies on the idea of stopping rules, identifying five common stopping rules information seekers use: mental list, representational stability, difference threshold, magnitude threshold, and single criterion (Browne et al., 2007). Prior research indicates a lack of understanding in the areas of information use (Prabha, Connaway, Olszewski, & Jenkins, 2007) and information overload (Eppler & Mengis, 2004) in Information Systems literature. Moreover, research indicates a lack of clarity in what information should be used in different decision contexts (Kowalczyk & Buxmann, 2014). The increase in the availability of information further complicates and necessitates research in this area. This dissertation seeks to fill these gaps in the literature by determining how information use changes across decision contexts and the relationships between stopping rules. Two unique methodologies were used to test the hypotheses in the conceptual ...
Date: August 2016
Creator: Gerhart, Natalie
Partner: UNT Libraries

Derivation: Excerpts From a Novel

Description: The dissertation consists of a critical preface and excerpts from the novel Derivation. The preface details how the novel Derivation explores the tension between the artist and the academy in the university, as well as the role memory plays in the construction of fictional narratives. The preface also details how narrative voice is used to expand the scope of Derivation, and ends with a discussion of masculine tropes in the novel. Derivation traces the path of a woman trying to rebuild her life in the wake of the 2008 financial crisis, returning first to her blue collar roots before pursuing a career as an academic.
Date: August 2015
Creator: Davis, Matthew
Partner: UNT Libraries

Design and Manufacture of Molding Compounds for High Reliability Microelectronics in Extreme Conditions

Description: The widespread use of electronics in more avenues of consumer use is increasing. Applications range from medical instrumentation that directly can affect someone's life, down hole sensors for oil and gas, aerospace, aeronautics, and automotive electronics. The increased power density and harsh environment makes the reliability of the packaging a vital part of the reliability of the device. The increased importance of analog devices in these applications, their high voltage and high temperature resilience is resulting in challenges that have not been dealt with before. In particular packaging where insulative properties are vital use polymer resins modified by ceramic fillers. The distinct dielectric properties of the resin and the filler result in charge storage and release of the polarization currents in the composite that have had unpredictable consequences on reliability. The objective of this effort is therefore to investigate a technique that can be used to measure the polarization in filled polymer resins and evaluate reliable molding compounds. A valuable approach to measure polarization in polymers where charge release is tied to the glass transition in the polymer is referred to as thermally stimulated depolarization current (TSDC) technique. In this dissertation a new TSDC measurement system was designed and fabricated. The instrument is an assembly of several components that are automated via a LabVIEW program that gives the user flexibility to test different dielectric compounds at high temperatures and high voltage. The temperature control is enabled through the use of dry air convection heating at a very slow rate enabling controlled heating and cooling. Charge trapping and de-trapping processes were investigated in order to obtain information on insulating polymeric composites and how to optimize it. A number of material properties were investigated. First, polarization due to charges on the filer were investigated using composites containing charged and uncharged particles using ...
Date: December 2016
Creator: Garcia, Andres
Partner: UNT Libraries

Design of New Monodentate Ligands for Regioselectivity and Enantioselectivity Tuning in Late Transition Metal Catalysis

Description: The ability of gold(I) to activate many types of unsaturated bonds toward nucleophilic attack was not widely recognized until the early 2000s. One major challenge in gold catalysis is the control over regioselectivity when there are two or more possible products as a result of complicated mechanistic pathways. It is well know that the choice of ligand can have dramatic effects on which pathway is being followed but very rarely are the reasons for this selectivity understood. The synthesis of new acyclic diaminocarbenes was developed and a study of the ligand effects on the regioselectivity of a gold-catalyzed domino enyne cyclization hydroarylation reaction and a Nazarov cyclization was undertaken. New chiral acyclic diaminocarbenes were also developed and tested along side new C3-symmetric phosphite ligands in an asymmetric intramolecular hydroamination of allenes. Structure activity correlations were developed for the potential use in further rational ligand design. The synthesis of 6a,7-dihydro-5-amino-dibenzo[c,g]chromene derivatives via a gold-catalyzed domino reaction of alkynylbenzaldehydes in the presence of secondary amines was developed. These were sent to be screened for biological activity.
Date: May 2016
Creator: Ruch, Aaron Anthony
Partner: UNT Libraries

Design, Synthesis and Screening of Homoleptic and Heteroleptic Platinum(ii) Pyridylazolate Complexes for N-type Semiconducting and Light-emitting Devices

Description: A series of heteroleptic and homoleptic platinum(II) complexes has been synthesized and characterized towards their use in thin film devices such as organic light-emitting diodes (OLEDs) and organic thin film transistors (OTFTs). Pyridylpyrazolate- and pyridyltetrazolate-containing ligands were selected due to their structural rigidity and ease of functionalization. Single-crystal x-ray diffraction studies of two selected heteroleptic complexes show strong aggregation with preferential stacking into vertical columns with a varying degree of overlap of the neighboring square planar molecular units. It is shown that the close proximity of the molecules to one another in the stack increases semiconducting character, phosphorescence quantum yields, and shorter radiative lifetimes. The potential for these materials towards incorporation into high-efficiency doping free white OLEDs (DFW-OLEDs) for solid-state lighting and display applications has been realized and will be expanded upon by present and future embodiments of materials in this thesis.
Date: August 2012
Creator: Oswald, Iain William Herbert
Partner: UNT Libraries

Design, Synthesis and Study of Supramolecular Donor – Acceptor Systems Mimicking Natural Photosynthesis Processes

Description: This dissertation investigates the chemical ingenuity into the development of various photoactive supramolecular donor – acceptor systems to produce clean and carbon free energy for the next generation. The process is inspired by the principles learned from nature’s approach where the solar energy is converted into the chemical energy through the natural photosynthesis process. Owing to the importance and complexity of natural photosynthesis process, we have designed ideal donor-acceptor systems to investigate their light energy harvesting properties. This process involves two major steps: the first step is the absorption of light energy by antenna or donor systems to promote them to an excited electronic state. The second step involves, the transfer of excitation energy to the reaction center, which triggers an electron transfer process within the system. Based on this principle, the research is focused into the development of artificial photosynthesis systems to investigate dynamics of photo induced energy and electron transfer events. The derivatives of Porphyrins, Phthalocyanines, BODIPY, and SubPhthalocyanines etc have been widely used as the primary building blocks for designing photoactive and electroactive ensembles in this area because of their excellent and unique photophysical and photochemical properties. Meanwhile, the fullerene, mainly its readily available version C60 is typicaly used as an electron acceptor component because of its unique redox potential, symmetrical shape and low reorganization energy appropriate for improved charge separation behavior. The primary research motivation of the study is to achieve fast charge separation and slow charge recombination of the system by stabilizing the radical ion pairs which are formed from photo excitation, for maximum utility of solar energy. Besides Fullerene C60, this dissertation has also investigated the potential application of carbon nanomaterials (Carbon nanotubes and graphene) as primary building blocks for the study of the artificial photosynthesis process.
Date: December 2015
Creator: KC, Chandra Bikram
Partner: UNT Libraries