Descriptors for Pentane-2,4-dione and Its Derivatives

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Description

This article uses equations for partition coefficients of compounds from water and the gas phase to various solvents to obtain descriptors for pentane-2,4-dione and 21 of its derivatives.

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14 p.

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Abraham, M. H. (Michael H.) & Acree, William E. (William Eugene) August 19, 2017.

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This article is part of the collection entitled: UNT Scholarly Works and was provided by UNT College of Arts and Sciences to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 20 times . More information about this article can be viewed below.

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This article uses equations for partition coefficients of compounds from water and the gas phase to various solvents to obtain descriptors for pentane-2,4-dione and 21 of its derivatives.

Physical Description

14 p.

Notes

Abstract: We have used equations for partition coefficients of compounds from water and the gas phase to various solvents to obtain descriptors for pentane-2,4-dione and 21 of its derivatives. These descriptors can then be used to estimate further partition coefficients into a wide variety of solvents. The descriptors also yield information about the properties of pentane-2,4-dione and its derivatives. Pentane-2,4-dione and its alkyl derivatives are quite polar, with substantial hydrogen bond basicity but with no hydrogen bond acidity. In contrast 1,1,1-trifluoropentane-2,4-dione and hexafluoropentan-2,4-dione have significant hydrogen bond acidities.

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  • Journal of Solution Chemistry, 2017. New York, NY: Springer

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Publication Information

  • Publication Title: Journal of Solution Chemistry
  • Volume: 46
  • Issue: 8
  • Pages: 1625-1638
  • Peer Reviewed: Yes

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  • April 17, 2017

Accepted Date

  • June 3, 2017

Creation Date

  • August 19, 2017

Added to The UNT Digital Library

  • Sept. 17, 2017, 6:24 p.m.

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Abraham, M. H. (Michael H.) & Acree, William E. (William Eugene). Descriptors for Pentane-2,4-dione and Its Derivatives, article, August 19, 2017; New York, New York. (digital.library.unt.edu/ark:/67531/metadc993396/: accessed December 15, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.