Elucidation of Photoinduced Energy and Electron Transfer Mechanisms in Multimodular Artificial Photosynthetic Systems

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Multimodular designs of electron donor-acceptor systems are the ultimate strategy in fabricating antenna-reaction center mimics for artificial photosynthetic applications. The studied photosystems clearly demonstrated efficient energy transfer from the antenna system to the primary electron donor, and charge stabilization of the radical ion pair achieved with the utilization of secondary electron donors that permits either electron migration or hole transfer. Moreover, the molecular arrangement of the photoactive components also influences the route of energy and electron transfer as observed from the aluminum(III) porphyrin-based photosystems. Furthermore, modulation of the photophysical and electronic properties of these photoactive units were illustrated from the ... continued below

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Lim, Gary Lloyd Nogra May 2017.

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  • Lim, Gary Lloyd Nogra

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Multimodular designs of electron donor-acceptor systems are the ultimate strategy in fabricating antenna-reaction center mimics for artificial photosynthetic applications. The studied photosystems clearly demonstrated efficient energy transfer from the antenna system to the primary electron donor, and charge stabilization of the radical ion pair achieved with the utilization of secondary electron donors that permits either electron migration or hole transfer. Moreover, the molecular arrangement of the photoactive components also influences the route of energy and electron transfer as observed from the aluminum(III) porphyrin-based photosystems. Furthermore, modulation of the photophysical and electronic properties of these photoactive units were illustrated from the thio-aryl substitution of subphthalocyanines yielding red-shifted Q bands of the said chromophore; hence, regulating the rate of charge separation and recombination in the subphthalocyanine-fullerene conjugates.
These multicomponent photosystems has the potential to absorb the entire UV-visible-NIR spectrum of the light energy allowing maximum light-harvesting capability. Furthermore, it permits charge stabilization of the radical ion pair enabling the utilization of the transferred electron/s to be used by water oxidizing and proton reducing catalysts in full-scale artificial photosynthetic apparatuses.

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  • May 2017

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  • July 12, 2017, 3:17 a.m.

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Lim, Gary Lloyd Nogra. Elucidation of Photoinduced Energy and Electron Transfer Mechanisms in Multimodular Artificial Photosynthetic Systems, dissertation, May 2017; Denton, Texas. (digital.library.unt.edu/ark:/67531/metadc984185/: accessed December 15, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; .