CSSX Radiolytic H2 Generation ("Thermolysis") -- Final Report

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The purpose of this work was to determine the radiolytic hydrogen gas yield of irradiated CSSX solvent at several temperatures. The active ingredient of this solvent is calix[4]arene-bis-(t-octylbenzo) crown-6, a calixarene crown ether used for cesium complexation. The solvent also contains 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol, a fluorinated alcoholic solvent modifer used to improve the solubility of the calixarene and its cesium complex in the Isopar L diluent. Isopar L is a branch-chain alkane and comprises most of the mixture. Samples of this solution were irradiated to various absorbed ?-ray doses in gas-tight sample containers, which were then sampled for hydrogen gas content. The ... continued below

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Mincher, Bruce J. January 1, 2009.

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Description

The purpose of this work was to determine the radiolytic hydrogen gas yield of irradiated CSSX solvent at several temperatures. The active ingredient of this solvent is calix[4]arene-bis-(t-octylbenzo) crown-6, a calixarene crown ether used for cesium complexation. The solvent also contains 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol, a fluorinated alcoholic solvent modifer used to improve the solubility of the calixarene and its cesium complex in the Isopar L diluent. Isopar L is a branch-chain alkane and comprises most of the mixture. Samples of this solution were irradiated to various absorbed ?-ray doses in gas-tight sample containers, which were then sampled for hydrogen gas content. The methods are described below.

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  • Report No.: INL/EXT-09-15302
  • Grant Number: DE-AC07-99ID-13727
  • DOI: 10.2172/950999 | External Link
  • Office of Scientific & Technical Information Report Number: 950999
  • Archival Resource Key: ark:/67531/metadc933149

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  • January 1, 2009

Added to The UNT Digital Library

  • Nov. 13, 2016, 7:26 p.m.

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  • Nov. 23, 2016, 12:09 p.m.

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Mincher, Bruce J. CSSX Radiolytic H2 Generation ("Thermolysis") -- Final Report, report, January 1, 2009; [Idaho]. (digital.library.unt.edu/ark:/67531/metadc933149/: accessed October 23, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.