Photogeneration of Hydride Donors and Their Use Toward CO2 Reduction

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Description

Despite substantial effort, no one has succeeded in efficiently producing methanol from CO2 using homogeneous photocatalytic systems. We are pursuing reaction schemes based on a sequence of hydride-ion transfers to carry out stepwise reduction of CO2 to methanol. We are using hydride-ion transfer from photoproduced C-H bonds in metal complexes with bio-inspired ligands (i.e., NADH-like ligands) that are known to store one proton and two electrons.

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233 - 238

Creation Information

Fujita,E.; Muckerman, J.T. & Polyansky, D.E. June 7, 2009.

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Description

Despite substantial effort, no one has succeeded in efficiently producing methanol from CO2 using homogeneous photocatalytic systems. We are pursuing reaction schemes based on a sequence of hydride-ion transfers to carry out stepwise reduction of CO2 to methanol. We are using hydride-ion transfer from photoproduced C-H bonds in metal complexes with bio-inspired ligands (i.e., NADH-like ligands) that are known to store one proton and two electrons.

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233 - 238

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  • The 31st DOE Solar Photochemistry Research Conference; Annapolis, MD; 20090607 through 20090610

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  • Report No.: BNL--90201-2009-CP
  • Grant Number: DE-AC02-98CH10886
  • Office of Scientific & Technical Information Report Number: 970419
  • Archival Resource Key: ark:/67531/metadc932077

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  • June 7, 2009

Added to The UNT Digital Library

  • Nov. 13, 2016, 7:26 p.m.

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  • Dec. 12, 2016, 8:40 p.m.

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Fujita,E.; Muckerman, J.T. & Polyansky, D.E. Photogeneration of Hydride Donors and Their Use Toward CO2 Reduction, article, June 7, 2009; United States. (digital.library.unt.edu/ark:/67531/metadc932077/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.