Mesoscale Biotransformation of Uranium: Influences of Organic Carbon Supply Rates and Sediment Oxides
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Description
Remediation and long-term stewardship of uranium-contaminated sediments and groundwaters are critical problems at a number of DOE facilities and mining sites. Some remediation strategies based on in-situ bioreduction of U are potentially effective in significantly decreasing U concentrations in groundwaters. However, a number of basic processes require understanding in order to identify conditions more conducive to success of reduction-based U stabilization. Our current research targets several of these issues including: (1) effects of organic carbon (OC) forms and supply rates on stability of bioreduced U, (2) the roles of Fe(III)- and Mn(III,IV)-oxides as potential U oxidants in sediments, and (3) …
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Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA
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Berkeley, California
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Description
Remediation and long-term stewardship of uranium-contaminated sediments and groundwaters are critical problems at a number of DOE facilities and mining sites. Some remediation strategies based on in-situ bioreduction of U are potentially effective in significantly decreasing U concentrations in groundwaters. However, a number of basic processes require understanding in order to identify conditions more conducive to success of reduction-based U stabilization. Our current research targets several of these issues including: (1) effects of organic carbon (OC) forms and supply rates on stability of bioreduced U, (2) the roles of Fe(III)- and Mn(III,IV)-oxides as potential U oxidants in sediments, and (3) microbial community changes in relation to U redox changes. These issues were identified in our previous study on U bioreduction and reoxidation (Wan et al., 2005). Most of our studies are being conducted on historically U-contaminated sediments from Area 2 of the Field Research Center, Oak Ridge National Laboratory, in flow-through columns simulating in-situ field remediation.
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Tokunaga, Tetsu; Wan, Jiamin; Kim, Yongman; Daly, Rebecca; Brodie, Eoin; Firestone, Mary et al.Mesoscale Biotransformation of Uranium: Influences of Organic Carbon Supply Rates and Sediment Oxides,
poster,
April 19, 2007;
Berkeley, California.
(https://digital.library.unt.edu/ark:/67531/metadc902611/:
accessed March 21, 2023),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT Libraries Government Documents Department.