Selective extraction of copper, mercury, silver and palladium ionsfrom water using hydrophobic ionic liquids.

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Extraction of dilute metal ions from water was performed near room temperature with a variety of ionic liquids. Distribution coefficients are reported for fourteen metal ions extracted with ionic liquids containing cations 1-octyl-4-methylpyridinium [4MOPYR]{sup +}, 1-methyl-1-octylpyrrolidinium [MOPYRRO]{sup +} or 1-methyl-1-octylpiperidinium [MOPIP]{sup +}, and anions tetrafluoroborate [BF{sub 4}]{sup +}, trifluoromethyl sulfonate [TfO]{sup +} or nonafluorobutyl sulfonate [NfO]{sup +}. Ionic liquids containing octylpyridinium cations are very good for extracting mercury ions. However, other metal ions were not significantly extracted by any of these ionic liquids. Extractions were also performed with four new task-specific ionic liquids. Such liquids containing a disulfide functional group ... continued below

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Papaiconomou, Nicolas; Lee, Jong-Min; Salminen, Justin; VonStosch, Moritz & Prausnitz, John M. June 25, 2007.

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Extraction of dilute metal ions from water was performed near room temperature with a variety of ionic liquids. Distribution coefficients are reported for fourteen metal ions extracted with ionic liquids containing cations 1-octyl-4-methylpyridinium [4MOPYR]{sup +}, 1-methyl-1-octylpyrrolidinium [MOPYRRO]{sup +} or 1-methyl-1-octylpiperidinium [MOPIP]{sup +}, and anions tetrafluoroborate [BF{sub 4}]{sup +}, trifluoromethyl sulfonate [TfO]{sup +} or nonafluorobutyl sulfonate [NfO]{sup +}. Ionic liquids containing octylpyridinium cations are very good for extracting mercury ions. However, other metal ions were not significantly extracted by any of these ionic liquids. Extractions were also performed with four new task-specific ionic liquids. Such liquids containing a disulfide functional group are efficient and selective for mercury and copper, whereas those containing a nitrile functional group are efficient and selective for silver and palladium.

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  • Journal Name: Industrial&Engineering ChemistryResearch; Journal Volume: 0; Journal Issue: 0; Related Information: Journal Publication Date: 09/12/2007

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  • Report No.: LBNL--62914
  • Grant Number: DE-AC02-05CH11231
  • DOI: 10.1021/ie0706562 | External Link
  • Office of Scientific & Technical Information Report Number: 932482
  • Archival Resource Key: ark:/67531/metadc900725

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  • June 25, 2007

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  • Sept. 27, 2016, 1:39 a.m.

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  • Dec. 7, 2016, 9:09 p.m.

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Papaiconomou, Nicolas; Lee, Jong-Min; Salminen, Justin; VonStosch, Moritz & Prausnitz, John M. Selective extraction of copper, mercury, silver and palladium ionsfrom water using hydrophobic ionic liquids., article, June 25, 2007; Berkeley, California. (digital.library.unt.edu/ark:/67531/metadc900725/: accessed October 23, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.