Activity Coefficient Derivatives of Ternary Systems Based on Scatchard's Neutral Electrolyte description

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Activity coefficient derivatives with respect to molality are presented for the Scatchard Neutral Electrolyte description of a ternary common-ion electrolyte system. These quantities are needed for the calculation of 'diffusion Onsager coefficients' and in turn for tests of the Onsager Reciprocal Relations in diffusion. The usually-omitted b{sub 23} term is included. The direct SNE binary approximations and a further approximation are discussed. Binary evaluation strategies other than constant ionic strength are considered.

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Miller, D G May 16, 2007.

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Activity coefficient derivatives with respect to molality are presented for the Scatchard Neutral Electrolyte description of a ternary common-ion electrolyte system. These quantities are needed for the calculation of 'diffusion Onsager coefficients' and in turn for tests of the Onsager Reciprocal Relations in diffusion. The usually-omitted b{sub 23} term is included. The direct SNE binary approximations and a further approximation are discussed. Binary evaluation strategies other than constant ionic strength are considered.

Physical Description

PDF-file: 16 pages; size: 0.2 Mbytes

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  • Journal Name: Journal of Solution Chemistry, vol. 37, no. 3, March 1, 2008, pp. 365-375; Journal Volume: 37; Journal Issue: 3

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  • Report No.: UCRL-JRNL-231060
  • Grant Number: W-7405-ENG-48
  • Office of Scientific & Technical Information Report Number: 942035
  • Archival Resource Key: ark:/67531/metadc898767

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  • May 16, 2007

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  • Sept. 27, 2016, 1:39 a.m.

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  • Dec. 6, 2016, 6:45 p.m.

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Miller, D G. Activity Coefficient Derivatives of Ternary Systems Based on Scatchard's Neutral Electrolyte description, article, May 16, 2007; Livermore, California. (digital.library.unt.edu/ark:/67531/metadc898767/: accessed September 26, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.