[(eta5-PentamethylcyclopentadienylYb(III)(5,5'-dimethyl-2,2-bipyridyl)mu-OH)2(mu 2-trifluoromethylsulfanato-O,O')][tetraphenylborate](5,5'-dimethyl-2,2-bipyridyl)

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The title compound C{sub 81}H{sub 88}BF{sub 3}N{sub 6}O{sub 5}SYb{sub 2}, crystallizes as a half-sandwich complex with a bridging inner-sphere trifluoro-methane sulfonate as well as two bridging hydroxide groups. there is uncoordinated 5,5{prime}-dimethyl-2,2{prime}-bipyridine in the crystal structure. The bound bipyridine ligands have N-C-C{prime}-n{prime} torsion angles of 12-13{sup o}. The triply bridged Yb centers are 3.5990(4) Angstroms apart. The Yb-N bonds range from 2.389(6)-2.424(5) Angstroms.

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Kazhdan, Daniel January 23, 2008.

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The title compound C{sub 81}H{sub 88}BF{sub 3}N{sub 6}O{sub 5}SYb{sub 2}, crystallizes as a half-sandwich complex with a bridging inner-sphere trifluoro-methane sulfonate as well as two bridging hydroxide groups. there is uncoordinated 5,5{prime}-dimethyl-2,2{prime}-bipyridine in the crystal structure. The bound bipyridine ligands have N-C-C{prime}-n{prime} torsion angles of 12-13{sup o}. The triply bridged Yb centers are 3.5990(4) Angstroms apart. The Yb-N bonds range from 2.389(6)-2.424(5) Angstroms.

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  • Journal Name: Acta Crystallographica Volume E; Journal Volume: 64; Journal Issue: pt2; Related Information: Journal Publication Date: 02/2008

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  • Report No.: LBNL--63775
  • Grant Number: DE-AC02-05CH11231
  • Office of Scientific & Technical Information Report Number: 929506
  • Archival Resource Key: ark:/67531/metadc898329

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  • January 23, 2008

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  • Sept. 27, 2016, 1:39 a.m.

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  • Oct. 31, 2016, 3:50 p.m.

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Kazhdan, Daniel. [(eta5-PentamethylcyclopentadienylYb(III)(5,5'-dimethyl-2,2-bipyridyl)mu-OH)2(mu 2-trifluoromethylsulfanato-O,O')][tetraphenylborate](5,5'-dimethyl-2,2-bipyridyl), article, January 23, 2008; Berkeley, California. (digital.library.unt.edu/ark:/67531/metadc898329/: accessed October 18, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.