Characterization of a mixed salt of 1-hydroxy-pyridin-2-one Pu(IV)complexes

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Most expert analyses of the projected world energy needs show utilization of nuclear energy will be essential for the next few decades, and hence the need to support this technology grows. But as one measure of the supporting science base of this field, as of December 2006, only 25 Pu containing structures were in the Cambridge Structural Database, as compared to 21,807 for Fe. A comparison of the rate of addition to this knowledge base reveals that approximately 500 Fe structures are registered with the Cambridge Structural Database every year, while in the same period only two or three Pu ... continued below

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Gorden, Anne E.V.; Xu, Jide; Szigethy, Geza; Oliver, Allen; Shuh,David K. & Raymond, Kenneth N. January 9, 2007.

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Most expert analyses of the projected world energy needs show utilization of nuclear energy will be essential for the next few decades, and hence the need to support this technology grows. But as one measure of the supporting science base of this field, as of December 2006, only 25 Pu containing structures were in the Cambridge Structural Database, as compared to 21,807 for Fe. A comparison of the rate of addition to this knowledge base reveals that approximately 500 Fe structures are registered with the Cambridge Structural Database every year, while in the same period only two or three Pu crystal structures are published. A continuing objective of this laboratory has been the development of new sequestering agents for actinide decorporation and selective extractions. This effort has been based on similarities in the properties of Pu(IV) and Fe(III), and the chelating groups in microbial Fe(III) sequestering agents, siderophores. The HOPO ligands (Figure 1) are one such class of chelating group which have been investigated as selective actinide extractants.

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  • Journal Name: Journal of the American Chemical Society; Journal Volume: 129; Journal Issue: 21; Related Information: Journal Publication Date: 05/08/2007

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  • Report No.: LBNL--62249
  • Grant Number: DE-AC02-05CH11231
  • DOI: 10.1021/ja070168l | External Link
  • Office of Scientific & Technical Information Report Number: 923286
  • Archival Resource Key: ark:/67531/metadc896931

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Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

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  • January 9, 2007

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  • Sept. 27, 2016, 1:39 a.m.

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  • Oct. 31, 2016, 3:49 p.m.

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Gorden, Anne E.V.; Xu, Jide; Szigethy, Geza; Oliver, Allen; Shuh,David K. & Raymond, Kenneth N. Characterization of a mixed salt of 1-hydroxy-pyridin-2-one Pu(IV)complexes, article, January 9, 2007; Berkeley, California. (digital.library.unt.edu/ark:/67531/metadc896931/: accessed October 22, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.