AMMONIA CONCENTRATION IN SALTSTONE HEADSPACE SUMMARY REPORT

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The Saltstone Facility Documented Safety Analysis (DSA) is under revision to accommodate changes in the Composite Lower Flammability Limit (CLFL) from the introduction of Isopar into Tank 50. Saltstone samples were prepared with an 'MCU' type salt solution spiked with ammonia. The ammonia released from the saltstone was captured and analyzed. The ammonia concentration found in the headspace of samples maintained at 95 C and 1 atm was, to 95% confidence, less than or equal to 3.9 mg/L. Tank 50 is fed by several influent streams. The salt solution from Tank 50 is pumped to the salt feed tank (SFT) ... continued below

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Zamecnik, J & Alex Cozzi, A September 26, 2008.

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Description

The Saltstone Facility Documented Safety Analysis (DSA) is under revision to accommodate changes in the Composite Lower Flammability Limit (CLFL) from the introduction of Isopar into Tank 50. Saltstone samples were prepared with an 'MCU' type salt solution spiked with ammonia. The ammonia released from the saltstone was captured and analyzed. The ammonia concentration found in the headspace of samples maintained at 95 C and 1 atm was, to 95% confidence, less than or equal to 3.9 mg/L. Tank 50 is fed by several influent streams. The salt solution from Tank 50 is pumped to the salt feed tank (SFT) in the Saltstone Production Facility (SPF). The premix materials cement, slag and fly ash are blended together prior to transfer to the grout mixer. The premix is fed to the grout mixer in the SPF and the salt solution is incorporated into the premix in the grout mixer, yielding saltstone slurry. The saltstone slurry drops into a hopper and then is pumped to the vault. The Saltstone Facility Documented Safety Analysis (DSA) is under revision to accommodate changes in the Composite Lower Flammability Limit (CLFL) from the introduction of Isopar{reg_sign} L into Tank 50. Waste Solidification-Engineering requested that the Savannah River National Laboratory (SRNL) perform testing to characterize the release of ammonia in curing saltstone at 95 C. The test temperature represents the maximum allowable temperature in the Saltstone Disposal Facility (SDF). Ammonia may be present in the salt solution and premix materials, or may be produced by chemical reactions when the premix and salt solution are combined. A final report (SRNS-STI-2008-00120, Rev. 0) will be issued that will cover in more depth the information presented in this report.

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  • Report No.: SRNS-STI-2008-00119
  • Grant Number: DE-AC09-08SR22470
  • DOI: 10.2172/941105 | External Link
  • Office of Scientific & Technical Information Report Number: 941105
  • Archival Resource Key: ark:/67531/metadc896553

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  • September 26, 2008

Added to The UNT Digital Library

  • Sept. 27, 2016, 1:39 a.m.

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  • Nov. 2, 2016, 5:14 p.m.

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Zamecnik, J & Alex Cozzi, A. AMMONIA CONCENTRATION IN SALTSTONE HEADSPACE SUMMARY REPORT, report, September 26, 2008; [Aiken, South Carolina]. (digital.library.unt.edu/ark:/67531/metadc896553/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.