The Resolution of Chiral, Tetrahedral M4L6 Metal-LigandHosts Page: 2 of 9
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Figure 2. Crystal structures of [Fe416]12- and [Ga426].10, 21 The C2 axis is perpendicular to the ligand
backbone of 1 but is in the plane of the ligand backbone of 2.
H
N
s-nie
Figure 3. Chiral (S)-N-methyl-nicotinium (S-nic+) cation used in [M416] l2- resolution.t
Figure 4. Space filling (left) and cylinder (right) representations of the crystal structure of AA-K(s-
nic)[Ga233]. For simplicity, only one S-nice counter ion is included. 14
2J. Am Chem. Soc. 2007, 129, 15354-15363
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Davis, Anna V.; Fiedler, Dorothea; Ziegler, Marco; Terpin,Andreas & Raymond, Kenneth N. The Resolution of Chiral, Tetrahedral M4L6 Metal-LigandHosts, article, August 28, 2007; Berkeley, California. (https://digital.library.unt.edu/ark:/67531/metadc894163/m1/2/: accessed April 24, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.