Oxygen Transport Ceramic Membranes Metadata

Title

• Main Title Oxygen Transport Ceramic Membranes

Creator

• Author: Bandopadhyay, S.
  Creator Type: Personal
• Author: Nagabhushana, N.
  Creator Type: Personal
• Author: Nithyanantham, T.
  Creator Type: Personal
• Author: Zhou, X.-D
  Creator Type: Personal
• Author: Sin, Y-W.
  Creator Type: Personal
• Author: Anderson, H.U.
  Creator Type: Personal
• Author: Jacobson, Alan
  Creator Type: Personal
• Author: Mims, C.A.
  Creator Type: Personal

Contributor

• Sponsor: United States. Department of Energy.
  Contributor Type: Organization

Publisher

• Name: University of Alaska
  Place of Publication: United States

Date

• Creation: 2005-02-01

Language

• English

Description

• Content Description: The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

Subject

• Keyword: Membranes
• Keyword: Oxygen
• Keyword: Strontium Oxides
• Keyword: Titanium Oxides
• STI Subject Categories: 36 Materials Science
• Keyword: Seebeck Effect
• Keyword: Membrane Transport
• Keyword: Lanthanum Oxides
• Keyword: Microstructure
• Keyword: Iron Oxides
• Keyword: Ceramics
• Keyword: Hardness

Collection

• Name: Office of Scientific & Technical Information Technical Reports
  Code: OSTI

Institution

• Name: UNT Libraries Government Documents Department
  Code: UNTGD

Resource Type

• Report

Format

• Text

Identifier

• Grant Number: FC26-99FT40054
• DOI: 10.2172/883075
• Office of Scientific & Technical Information Report Number: 883075
• Archival Resource Key: ark:/67531/metadc891900