Molecular Architecture for Polyphosphazene Electrolytes for Seawater Batteries

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In this work, a series of polyphosphazenes were designed to function as water resistant, yet ionically conductive membranes for application to lithium/seawater batteries. In membranes of this nature, various molecular architectures are possible and representatives from each possible type were chosen. These polymers were synthesized and their performance as solid polymer electrolytes was evaluated in terms of both lithium ion conductivity and water permeability. The impact that this molecular architecture has on total performance of the membranes for seawater batteries is discussed. Further implications of this molecular architecture on the mechanisms of lithium ion transport through polyphosphazenes are also discussed.

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Harrup, Mason K.; Harrup, Mason K.; Luther, Thomas A.; Orme, Christopher J. & Peterson, Eric S. August 1, 2005.

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In this work, a series of polyphosphazenes were designed to function as water resistant, yet ionically conductive membranes for application to lithium/seawater batteries. In membranes of this nature, various molecular architectures are possible and representatives from each possible type were chosen. These polymers were synthesized and their performance as solid polymer electrolytes was evaluated in terms of both lithium ion conductivity and water permeability. The impact that this molecular architecture has on total performance of the membranes for seawater batteries is discussed. Further implications of this molecular architecture on the mechanisms of lithium ion transport through polyphosphazenes are also discussed.

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  • American Chemical Society National Meeting,Washington, D.C.,08/28/2005,09/01/2005

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  • Report No.: INL/CON-05-00234
  • Grant Number: DE-AC07-99ID-13727
  • Office of Scientific & Technical Information Report Number: 911614
  • Archival Resource Key: ark:/67531/metadc885351

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  • August 1, 2005

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  • Sept. 22, 2016, 2:13 a.m.

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  • Nov. 7, 2016, 6:13 p.m.

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Harrup, Mason K.; Harrup, Mason K.; Luther, Thomas A.; Orme, Christopher J. & Peterson, Eric S. Molecular Architecture for Polyphosphazene Electrolytes for Seawater Batteries, article, August 1, 2005; [Idaho Falls, Idaho]. (digital.library.unt.edu/ark:/67531/metadc885351/: accessed December 10, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.