Progress in the Fluorox program is reported. The chemical reaction of primary interest in the Fluorox program is the oxidation of UF/sub 4/ with O/sub 2/, 2UF/sub 4/ + O/sub 2/ = UO/sub 2/F/sub 2/ + UF/sub 6/; however, to study this process at higher temperatures, the thermal decomposition of UO/sub 2/F/sub 2/, 3UO/sub 2/F/sub 2/ = 2/3 U/sub 3 /O/sub 8/ + UF/sub 6/ + 1/3 O/sub 2/, is being investigated by thermogravimetric methods in the temperature range 750 to 900 deg C. A fluidized bed reactor and a flame reactor have been used successfully to perform the continuous …
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Progress in the Fluorox program is reported. The chemical reaction of primary interest in the Fluorox program is the oxidation of UF/sub 4/ with O/sub 2/, 2UF/sub 4/ + O/sub 2/ = UO/sub 2/F/sub 2/ + UF/sub 6/; however, to study this process at higher temperatures, the thermal decomposition of UO/sub 2/F/sub 2/, 3UO/sub 2/F/sub 2/ = 2/3 U/sub 3 /O/sub 8/ + UF/sub 6/ + 1/3 O/sub 2/, is being investigated by thermogravimetric methods in the temperature range 750 to 900 deg C. A fluidized bed reactor and a flame reactor have been used successfully to perform the continuous oxidation of UF/sub 4/ with O/sub 2/. The 3-in. fluidized bed reactor was operated up to 825 deg C on both a continuous and batch basis while the flame reactor was used to continuously react finely divided UF/sub 4/ with O/sub 2/ in a CO-O/sub 2/ flame at temperatures greater than 1200 deg C. (auth)
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Adams, J. B.; Ferris, L. M. & Scott, C. D.Progress Report on the Fluorox Process for April 30, 1957-January 14, 1958,
report,
September 10, 1958;
Tennessee.
(https://digital.library.unt.edu/ark:/67531/metadc878187/:
accessed July 14, 2026),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT Libraries Government Documents Department.
