Evaluation of Alternate Stainless Steel Surface Passivation Methods

PDF Version Also Available for Download.

Description

Stainless steel containers were assembled from parts passivated by four commercial vendors using three passivation methods. The performance of these containers in storing hydrogen isotope mixtures was evaluated by monitoring the composition of initially 50% H{sub 2} 50% D{sub 2} gas with time using mass spectroscopy. Commercial passivation by electropolishing appears to result in surfaces that do not catalyze hydrogen isotope exchange. This method of surface passivation shows promise for tritium service, and should be studied further and considered for use. On the other hand, nitric acid passivation and citric acid passivation may not result in surfaces that do not ... continued below

Creation Information

Clark, Elliot A. May 31, 2005.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

Stainless steel containers were assembled from parts passivated by four commercial vendors using three passivation methods. The performance of these containers in storing hydrogen isotope mixtures was evaluated by monitoring the composition of initially 50% H{sub 2} 50% D{sub 2} gas with time using mass spectroscopy. Commercial passivation by electropolishing appears to result in surfaces that do not catalyze hydrogen isotope exchange. This method of surface passivation shows promise for tritium service, and should be studied further and considered for use. On the other hand, nitric acid passivation and citric acid passivation may not result in surfaces that do not catalyze the isotope exchange reaction H{sub 2} + D{sub 2} {yields} 2HD. These methods should not be considered to replace the proprietary passivation processes of the two current vendors used at the Savannah River Site Tritium Facility.

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Report No.: WSRC-TR-2005-00246
  • Grant Number: DE-AC09-96SR18500
  • DOI: 10.2172/881451 | External Link
  • Office of Scientific & Technical Information Report Number: 881451
  • Archival Resource Key: ark:/67531/metadc874603

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • May 31, 2005

Added to The UNT Digital Library

  • Sept. 21, 2016, 2:29 a.m.

Description Last Updated

  • Nov. 28, 2016, 1:26 p.m.

Usage Statistics

When was this report last used?

Congratulations! It looks like you are the first person to view this item online.

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Clark, Elliot A. Evaluation of Alternate Stainless Steel Surface Passivation Methods, report, May 31, 2005; Aiken, South Carolina. (digital.library.unt.edu/ark:/67531/metadc874603/: accessed August 22, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.