Evaluation of Oxidation and Hydrogen Permeation of Al Containing Duplex Stainless Steels

PDF Version Also Available for Download.

Description

As the National Hydrogen Economy continues to develop and evolve the need for structural materials that can resist hydrogen assisted degradation will become critical. To date austenitic stainless steel materials have been shown to be mildly susceptible to hydrogen attack which results in lower mechanical and fracture strengths. As a result, hydrogen permeation barrier coatings are typically applied to these steel to retard hydrogen ingress. The focal point of the reported work was to evaluate the potential for intentional alloying of commercial 300-series stainless steels to promote hydrogen permeation resistant oxide scales. Previous research on the Cr- and Fe-oxide scales ... continued below

Creation Information

Adams, Thad M.; Korinko, Paul & Duncan, Andrew June 17, 2005.

Context

This article is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this article can be viewed below.

Who

People and organizations associated with either the creation of this article or its content.

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this article. Follow the links below to find similar items on the Digital Library.

Description

As the National Hydrogen Economy continues to develop and evolve the need for structural materials that can resist hydrogen assisted degradation will become critical. To date austenitic stainless steel materials have been shown to be mildly susceptible to hydrogen attack which results in lower mechanical and fracture strengths. As a result, hydrogen permeation barrier coatings are typically applied to these steel to retard hydrogen ingress. The focal point of the reported work was to evaluate the potential for intentional alloying of commercial 300-series stainless steels to promote hydrogen permeation resistant oxide scales. Previous research on the Cr- and Fe-oxide scales inherent to 300-series stainless steels has proven to be inconsistent in effecting permeation resistance. The approach undertaken in this research was to add aluminum to the 300-series stainless steels in an attempt to promote a pure Al-oxide or and Al-rich oxide scale. Aloxide had been previously demonstrated to be an effective hydrogen permeation barrier. Results for 304L and 347H alloys doped with Al in concentration from 0.5-3.0 wt% with respect to oxidation kinetic studies, cyclic oxidation and characterization of the oxide scale chemistry are reported herein. Gaseous hydrogen permeation testing of the Al-doped alloys in both the unoxidized and oxidized (600 C, 30 mins) conditions are reported. A critical finding from this work is that at concentration as low as 0.5 wt% Al, the Al stabilizes the ferrite phase in these steels thus producing duplex austenitic-ferritic microstructures. As the Al-content increases the amount of measured ferrite increases thus resulting in hydrogen permeabilities more closely resembling ferritic steels.

Source

  • Journal Name: Materials Science and Engineering

Language

Item Type

Identifier

Unique identifying numbers for this article in the Digital Library or other systems.

  • Report No.: WSRC-MS-2005-00393
  • Grant Number: DE-AC09-96SR18500
  • Office of Scientific & Technical Information Report Number: 881456
  • Archival Resource Key: ark:/67531/metadc874255

Collections

This article is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

What responsibilities do I have when using this article?

When

Dates and time periods associated with this article.

Creation Date

  • June 17, 2005

Added to The UNT Digital Library

  • Sept. 21, 2016, 2:29 a.m.

Description Last Updated

  • Dec. 5, 2016, 3:23 p.m.

Usage Statistics

When was this article last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 1

Interact With This Article

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Adams, Thad M.; Korinko, Paul & Duncan, Andrew. Evaluation of Oxidation and Hydrogen Permeation of Al Containing Duplex Stainless Steels, article, June 17, 2005; Aiken, South Carolina. (digital.library.unt.edu/ark:/67531/metadc874255/: accessed August 17, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.