Sintering behavior of mullite-containing powders was studied over a range of chemical compositions (Al{sub 2}O{sub 3}/SiO{sub 2} ratio). Densification measurements were made for both liquid phase-containing and solid state systems. Small amounts of liquid phase were observed to have a significant effect on densification rate. A linear relationship was obtained between the percent of theoretical density and the logarithm of time for compositions in the range 73-75 wt% Al{sub 2}O{sub 3}. Currently available models for intermediate stage sintering kinetics were considered to be inadequate for these systems. Grain boundary transport 0r diffusion appeared to be the primary mechanism of densification.
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Ernest Orlando Lawrence Berkeley National Laboratory, Berkeley, CA (United States)
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Berkeley, California
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Sintering behavior of mullite-containing powders was studied over a range of chemical compositions (Al{sub 2}O{sub 3}/SiO{sub 2} ratio). Densification measurements were made for both liquid phase-containing and solid state systems. Small amounts of liquid phase were observed to have a significant effect on densification rate. A linear relationship was obtained between the percent of theoretical density and the logarithm of time for compositions in the range 73-75 wt% Al{sub 2}O{sub 3}. Currently available models for intermediate stage sintering kinetics were considered to be inadequate for these systems. Grain boundary transport 0r diffusion appeared to be the primary mechanism of densification.
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Sacks, Michael D. & Pask, Joseph A.1/2 Sintering of Mullite-Containing Materials: I. Effect of Composition,
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December 1, 1981;
Berkeley, California.
(https://digital.library.unt.edu/ark:/67531/metadc870305/:
accessed March 19, 2024),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
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