Reactions of sigma-bonded organochromium(III)complexes

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Three projects were carried out, each dealing with the kinetics and mechanism of reactions of sigma-bonded organochromium(III) complexes of the form (H$sub 2$O)$sub 5$CrR$sup 2+$. Part I describes the kinetics of the reaction of dichloromethylchromium(III) ion with chromium(II) ion in aqueous acid. Part II deals with the radioexchange of 4-pyridinomethylchromium(III) ion with $sup 51$Cr$sup 2+$ and the kinetics of formation of the organochromium species at 55$sup 0$ in 1 M H$sup +$. Part III deals with the reactions of Hg$sup 2+$ and CH$sub 3$Hg$sup +$ with a series of (H$sub 2$O)$sub 5$CrR$sup 2+$ complexes, in which R is an aliphatic ... continued below

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Pages: 205

Creation Information

Leslie, J.P. II December 1, 1975.

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  • Ames Laboratory
    Publisher Info: Ames Lab., Iowa (USA)
    Place of Publication: [Ames,] Iowa

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Description

Three projects were carried out, each dealing with the kinetics and mechanism of reactions of sigma-bonded organochromium(III) complexes of the form (H$sub 2$O)$sub 5$CrR$sup 2+$. Part I describes the kinetics of the reaction of dichloromethylchromium(III) ion with chromium(II) ion in aqueous acid. Part II deals with the radioexchange of 4-pyridinomethylchromium(III) ion with $sup 51$Cr$sup 2+$ and the kinetics of formation of the organochromium species at 55$sup 0$ in 1 M H$sup +$. Part III deals with the reactions of Hg$sup 2+$ and CH$sub 3$Hg$sup +$ with a series of (H$sub 2$O)$sub 5$CrR$sup 2+$ complexes, in which R is an aliphatic alkyl group, a haloalkyl group, or an aralkyl group. (LK)

Physical Description

Pages: 205

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Dep. NTIS

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  • Other Information: Thesis. Orig. Receipt Date: 30-JUN-76

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  • Report No.: IS-T--704
  • Grant Number: W-7405-ENG-82
  • DOI: 10.2172/4153863 | External Link
  • Office of Scientific & Technical Information Report Number: 4153863
  • Archival Resource Key: ark:/67531/metadc867799

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Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

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  • December 1, 1975

Added to The UNT Digital Library

  • Sept. 16, 2016, 12:32 a.m.

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  • Oct. 26, 2017, 7:30 p.m.

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Leslie, J.P. II. Reactions of sigma-bonded organochromium(III)complexes, thesis or dissertation, December 1, 1975; [Ames,] Iowa. (digital.library.unt.edu/ark:/67531/metadc867799/: accessed November 17, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.