Experimentally characterizing the electronic structures of f-electron systems using advanced high resolution Fourier transform microwave spectroscopies

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We aim to (i) provide data that directly addresses the fundamental roles of actinide valence electrons in chemical bonding, and (ii) serve to provide prototypical data for the heavy element computational chemistry community. These goals will be achieved through the first pure rotational spectroscopic measurements on prototypical systems at ultra-high resolution. These systems encompass low oxidation state uranium and thorium compounds including, but not limited to, UX and ThX, X = F, Cl, Br, I, and UY and ThY, Y = O, S, and other simple U and Th-containing compounds. Our primary experimental tools involve time-domain rotational spectroscopy achieving line ... continued below

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Cooke, Stephen, A February 3, 2013.

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Description

We aim to (i) provide data that directly addresses the fundamental roles of actinide valence electrons in chemical bonding, and (ii) serve to provide prototypical data for the heavy element computational chemistry community. These goals will be achieved through the first pure rotational spectroscopic measurements on prototypical systems at ultra-high resolution. These systems encompass low oxidation state uranium and thorium compounds including, but not limited to, UX and ThX, X = F, Cl, Br, I, and UY and ThY, Y = O, S, and other simple U and Th-containing compounds. Our primary experimental tools involve time-domain rotational spectroscopy achieving line widths and resolutions of a few kHz.

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  • Report No.: DOE/SC0003934-1
  • Grant Number: SC0003934
  • DOI: 10.2172/1061478 | External Link
  • Office of Scientific & Technical Information Report Number: 1061478
  • Archival Resource Key: ark:/67531/metadc842166

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  • February 3, 2013

Added to The UNT Digital Library

  • May 19, 2016, 9:45 a.m.

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  • Dec. 5, 2016, 3:31 p.m.

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Cooke, Stephen, A. Experimentally characterizing the electronic structures of f-electron systems using advanced high resolution Fourier transform microwave spectroscopies, report, February 3, 2013; United States. (digital.library.unt.edu/ark:/67531/metadc842166/: accessed October 22, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.