Quantifying exchange coupling in f-ion pairs using the diamagnetic substitution method

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One of the challenges in the chemistry of actinide and lanthanide (f-ion) is quantifying exchange coupling between f-ions. While qualitative information about exchange coupling may be readily obtained using the diamagnetic substitution approach, obtaining quantitative information is much more difficult. This article describes how exchange coupling may be quantified using the susceptibility of a magnetically isolated analog, as in the diamagnetic substitution approach, along with the anisotropy of the ground state as determined by EPR spectroscopy. Several examples are used to illustrate and test this approach.

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Lukens, Wayne W. & Walter, Marc D. April 1, 2010.

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One of the challenges in the chemistry of actinide and lanthanide (f-ion) is quantifying exchange coupling between f-ions. While qualitative information about exchange coupling may be readily obtained using the diamagnetic substitution approach, obtaining quantitative information is much more difficult. This article describes how exchange coupling may be quantified using the susceptibility of a magnetically isolated analog, as in the diamagnetic substitution approach, along with the anisotropy of the ground state as determined by EPR spectroscopy. Several examples are used to illustrate and test this approach.

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26

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  • Journal Name: Inorganic Chemistry

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  • Report No.: LBNL-3303E
  • Grant Number: DE-AC02-05CH11231
  • Office of Scientific & Technical Information Report Number: 1010536
  • Archival Resource Key: ark:/67531/metadc836279

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  • April 1, 2010

Added to The UNT Digital Library

  • May 19, 2016, 3:16 p.m.

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  • July 26, 2016, 5:46 p.m.

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Lukens, Wayne W. & Walter, Marc D. Quantifying exchange coupling in f-ion pairs using the diamagnetic substitution method, article, April 1, 2010; Berkeley, California. (digital.library.unt.edu/ark:/67531/metadc836279/: accessed November 16, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.