RATE CONSTANT FOR THE REACTION NO2 + O->NO + O2

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By use of tunable laser flash photolysis and resonance fluorescence to detect primary products, the rate constant for the reaction 0({sup 3}P{sub J}) + NO{sub 2} {yields} O{sub 2} + NO has been measured. A value of k = 1.03 {+-} .01 x 10{sup -11} cm{sup 3} molecules{sup -1} sec{sup -1} was obtained at 296 K, which is a factor of 1.1 faster than the currently recommended value. The present work utilized in situ measurement of NO{sub 2} via laser induced fluorescence and generated oxygen atoms from five sources.

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16 p.

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Magnotta, Frank & Johnston, Harold S. January 1, 1980.

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Description

By use of tunable laser flash photolysis and resonance fluorescence to detect primary products, the rate constant for the reaction 0({sup 3}P{sub J}) + NO{sub 2} {yields} O{sub 2} + NO has been measured. A value of k = 1.03 {+-} .01 x 10{sup -11} cm{sup 3} molecules{sup -1} sec{sup -1} was obtained at 296 K, which is a factor of 1.1 faster than the currently recommended value. The present work utilized in situ measurement of NO{sub 2} via laser induced fluorescence and generated oxygen atoms from five sources.

Physical Description

16 p.

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  • Journal Name: Journal of Physical Chemistry

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  • Report No.: LBL-10424
  • Grant Number: DE-AC02-05CH11231
  • Office of Scientific & Technical Information Report Number: 1030575
  • Archival Resource Key: ark:/67531/metadc829237

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  • January 1, 1980

Added to The UNT Digital Library

  • May 19, 2016, 3:16 p.m.

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  • June 16, 2016, 12:55 p.m.

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Magnotta, Frank & Johnston, Harold S. RATE CONSTANT FOR THE REACTION NO2 + O->NO + O2, article, January 1, 1980; Berkeley, California. (digital.library.unt.edu/ark:/67531/metadc829237/: accessed September 26, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.