A General Initial Decomposition Reaction for Complex Metal Hydrides

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Description

The initial thermally activated decomposition of several complex metal hydride compounds, to a binary alkali or alkaline hydride and a group IIIb metal hydride, appears to share a first step in their decomposition mechanisms. The application of this initial thermochemical decomposition step to several alanate compounds illustrates the generality of this approach. For LiAlH4, the decomposition data fall on the derived distribution plot calculated for NaAlH4.

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6 pages

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WALTERS, R November 23, 2004.

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Description

The initial thermally activated decomposition of several complex metal hydride compounds, to a binary alkali or alkaline hydride and a group IIIb metal hydride, appears to share a first step in their decomposition mechanisms. The application of this initial thermochemical decomposition step to several alanate compounds illustrates the generality of this approach. For LiAlH4, the decomposition data fall on the derived distribution plot calculated for NaAlH4.

Physical Description

6 pages

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  • Other Information: PBD: 23 Nov 2004

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  • Report No.: WSRC-MS-2004-00629
  • Grant Number: AC09-96SR18500
  • DOI: 10.2172/836748 | External Link
  • Office of Scientific & Technical Information Report Number: 836748
  • Archival Resource Key: ark:/67531/metadc788243

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  • November 23, 2004

Added to The UNT Digital Library

  • Dec. 3, 2015, 9:30 a.m.

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  • May 5, 2016, 1:56 p.m.

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WALTERS, R. A General Initial Decomposition Reaction for Complex Metal Hydrides, report, November 23, 2004; South Carolina. (digital.library.unt.edu/ark:/67531/metadc788243/: accessed September 22, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.