SUBSTITUTED IRON OXIDES FOR THE GRANT ENTITLED LASER PROCESSING OF ADVANCED MAGNETIC MATERIALS

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Structural and morphological characteristics of (1-x){alpha}-Fe{sub 2}O{sub 3}-xSnO{sub 2} (x = 0.0-1.0) nanoparticles obtained under hydrothermal conditions have been investigated by X-ray diffraction (XRD), transmission Moessbauer spectroscopy, scanning (SEM) and transmission electron microscopy (TEM) as well as energy dispersive X-ray analysis (EDX). On the basis of the Rietveld structure refinements of the XRD spectra at low tin concentrations, it was found that Sn{sup 4+} ions partially substitute for Fe{sup 3+} at the octahedral sites and also occupy the interstitial octahedral sites which are vacant in {alpha}-Fe{sub 2}O{sub 3} corundum structure. A phase separation of {alpha}-Fe{sub 2}O{sub 3} and SnO{sub 2} ... continued below

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32 pages

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Sorescu, Monica March 1, 2004.

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Description

Structural and morphological characteristics of (1-x){alpha}-Fe{sub 2}O{sub 3}-xSnO{sub 2} (x = 0.0-1.0) nanoparticles obtained under hydrothermal conditions have been investigated by X-ray diffraction (XRD), transmission Moessbauer spectroscopy, scanning (SEM) and transmission electron microscopy (TEM) as well as energy dispersive X-ray analysis (EDX). On the basis of the Rietveld structure refinements of the XRD spectra at low tin concentrations, it was found that Sn{sup 4+} ions partially substitute for Fe{sup 3+} at the octahedral sites and also occupy the interstitial octahedral sites which are vacant in {alpha}-Fe{sub 2}O{sub 3} corundum structure. A phase separation of {alpha}-Fe{sub 2}O{sub 3} and SnO{sub 2} was observed for x {ge} 0.4: the {alpha}-Fe{sub 2}O{sub 3} structure containing tin decreases simultaneously with the increase of the SnO{sub 2} phase containing substitutional iron ions. The mean particle dimension decreases from 70 nm to 6 nm, as the molar fraction x increases up to x = 1.0. The estimated solubility limits in the nanoparticle system (1-x){alpha}-Fe{sub 2}O{sub 3}-xSnO{sub 2} synthesized under hydrothermal conditions are: x {le} 0.2 for Sn{sup 4+} in {alpha}-Fe{sub 2}O{sub 3} and x {ge} 0.7 for Fe{sup 3+} in SnO{sub 2}. These findings are in press in the Journal of Physics and Chemistry of Solids.

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32 pages

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INIS; OSTI as DE00822034

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  • Other Information: PBD: 1 Mar 2004

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  • Report No.: NONE
  • Grant Number: FG26-02NT41595
  • DOI: 10.2172/822034 | External Link
  • Office of Scientific & Technical Information Report Number: 822034
  • Archival Resource Key: ark:/67531/metadc786879

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  • March 1, 2004

Added to The UNT Digital Library

  • Dec. 3, 2015, 9:30 a.m.

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  • Jan. 3, 2017, 1:29 p.m.

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Sorescu, Monica. SUBSTITUTED IRON OXIDES FOR THE GRANT ENTITLED LASER PROCESSING OF ADVANCED MAGNETIC MATERIALS, report, March 1, 2004; United States. (digital.library.unt.edu/ark:/67531/metadc786879/: accessed June 23, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.