Fundamental Chemistry, Characterization, and Separation of Technetium Complexes in Hanford Waste

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Description

The ultimate goal of this project is to separate technetium from Hanford tank waste. Our prior work with Hanford Site tank waste indicates that the presence of complexants has produced unidentified, reduced technetium species not amenable to current separation technologies, or readily oxidized to pertechnetate. Consequently, we are synthesizing and characterizing some of the major classes of technetium complexes that may be formed under tank waste conditions. These complexes will be used as standards to characterize the nonpertechnetate species in actual wastes and to develop efficient oxidation or separation methods.

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Schroeder, Norman C.; Ashley, Kenneth R. & Blanchard, David L. June 2000.

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This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

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Description

The ultimate goal of this project is to separate technetium from Hanford tank waste. Our prior work with Hanford Site tank waste indicates that the presence of complexants has produced unidentified, reduced technetium species not amenable to current separation technologies, or readily oxidized to pertechnetate. Consequently, we are synthesizing and characterizing some of the major classes of technetium complexes that may be formed under tank waste conditions. These complexes will be used as standards to characterize the nonpertechnetate species in actual wastes and to develop efficient oxidation or separation methods.

Physical Description

vp.

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  • Other Information: PBD: 1 Jun 2000

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  • Report No.: EMSP-59990--2000
  • DOI: 10.2172/828438 | External Link
  • Office of Scientific & Technical Information Report Number: 828438
  • Archival Resource Key: ark:/67531/metadc786484

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  • June 2000

Added to The UNT Digital Library

  • Dec. 3, 2015, 9:30 a.m.

Description Last Updated

  • May 6, 2016, 2:23 p.m.

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Schroeder, Norman C.; Ashley, Kenneth R. & Blanchard, David L. Fundamental Chemistry, Characterization, and Separation of Technetium Complexes in Hanford Waste, report, June 2000; Los Alamos, New Mexico. (digital.library.unt.edu/ark:/67531/metadc786484/: accessed September 21, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.