Excited State Processes in Transition Metal Complexes, Redox Splitting in Soluble Polymers

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The photochemical and photophysical properties of polypyridyl complexes of Ru, Os, and Re have been investigated by transient absorption, emission, resonance raman and infrared spectroscopies. The latter technique has been especially useful in defining the acceptor ligand in metal-to-ligand charge transfer (MLCT) excited states and probing the details of excited state electronic and molecular structure. Derivatives of these complexes have been attached to soluble polystyrene polymers. In the resulting metal complex polymer composites it has been possible to demonstrate long range energy transfer and the existence of an antenna effect and create a mimic for the active site in the ... continued below

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Meyer, T.J. & Papanikolas, J.M. August 8, 2002.

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The photochemical and photophysical properties of polypyridyl complexes of Ru, Os, and Re have been investigated by transient absorption, emission, resonance raman and infrared spectroscopies. The latter technique has been especially useful in defining the acceptor ligand in metal-to-ligand charge transfer (MLCT) excited states and probing the details of excited state electronic and molecular structure. Derivatives of these complexes have been attached to soluble polystyrene polymers. In the resulting metal complex polymer composites it has been possible to demonstrate long range energy transfer and the existence of an antenna effect and create a mimic for the active site in the photosynthetic membrane.

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OSTI as DE00830013

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  • Other Information: PBD: 8 Aug 2002

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  • Report No.: DOE/ER/14607-1
  • Grant Number: FG02-96ER14607
  • DOI: 10.2172/830013 | External Link
  • Office of Scientific & Technical Information Report Number: 830013
  • Archival Resource Key: ark:/67531/metadc785620

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  • August 8, 2002

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  • Dec. 3, 2015, 9:30 a.m.

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  • Aug. 4, 2016, 7:43 p.m.

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Meyer, T.J. & Papanikolas, J.M. Excited State Processes in Transition Metal Complexes, Redox Splitting in Soluble Polymers, report, August 8, 2002; United States. (digital.library.unt.edu/ark:/67531/metadc785620/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.