PROTON-CONDUCTING DENSE CERAMIC MEMBRANES FOR HYDROGEN SEPARATION

PDF Version Also Available for Download.

Description

Dense perovskite-type structured ceramic membranes, SrCe{sub 0.95}Tm{sub 0.05}O{sub 3} (SCTm), of different thickness, were prepared by the dry-press method. Membrane thickness was varied from 3 mm to 150 {micro}m. The hydrogen permeation flux was found to be inversely proportional to the thickness of the dense films, indicating that the bulk diffusion rather than the surface reaction played a dominant role in the H{sub 2} transport through these dense membranes within the studied thickness range. Hydrogen permeation flux increases with increasing upstream hydrogen partial pressure and decreasing downstream hydrogen partial pressure. The activation energy for hydrogen permeation through the SCTm membrane ... continued below

Physical Description

13 pages

Creation Information

Lin, Jerry Y. S.; Cheng, Scott & Gupta, Vineet December 1, 2003.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 17 times . More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Sponsor

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

Dense perovskite-type structured ceramic membranes, SrCe{sub 0.95}Tm{sub 0.05}O{sub 3} (SCTm), of different thickness, were prepared by the dry-press method. Membrane thickness was varied from 3 mm to 150 {micro}m. The hydrogen permeation flux was found to be inversely proportional to the thickness of the dense films, indicating that the bulk diffusion rather than the surface reaction played a dominant role in the H{sub 2} transport through these dense membranes within the studied thickness range. Hydrogen permeation flux increases with increasing upstream hydrogen partial pressure and decreasing downstream hydrogen partial pressure. The activation energy for hydrogen permeation through the SCTm membrane is about 116 kJ/mol in 600-700 C and 16 kJ/mol in 750-950 C. This indicates a change in the electrical and protonic conduction mechanism at around 700 C. Pd-Cu thin films were synthesized with elemental palladium and copper targets by the sequential R.F. sputter deposition on porous substrates. Pd-Cu alloy films could be formed after proper annealing. The deposited Pd-Cu films were gas-tight. This result demonstrated the feasibility of obtaining an ultrathin SCTm film by the sequential sputter deposition of Sr, Ce and Tm metals followed by proper annealing and oxidation. Such ultrathin SCTm membranes will offer sufficiently high hydrogen permeance for practical applications.

Physical Description

13 pages

Notes

OSTI as DE00822716

Source

  • Other Information: PBD: 1 Dec 2003

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Report No.: NONE
  • Grant Number: FG26-00NT40818
  • DOI: 10.2172/822716 | External Link
  • Office of Scientific & Technical Information Report Number: 822716
  • Archival Resource Key: ark:/67531/metadc782441

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • December 1, 2003

Added to The UNT Digital Library

  • Dec. 3, 2015, 9:30 a.m.

Description Last Updated

  • Jan. 3, 2017, 5:07 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 17

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

International Image Interoperability Framework

IIF Logo

We support the IIIF Presentation API

Lin, Jerry Y. S.; Cheng, Scott & Gupta, Vineet. PROTON-CONDUCTING DENSE CERAMIC MEMBRANES FOR HYDROGEN SEPARATION, report, December 1, 2003; United States. (digital.library.unt.edu/ark:/67531/metadc782441/: accessed September 23, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.