Sorption Characteristics of Aqueous Co(II) on Preformed Iron Ferrite Impregnated into Phenolsulphonic Formaldehyde Resin

PDF Version Also Available for Download.

Description

A series of stepwise procedures to prepare a new organic-inorganic composite magnetic resin with phenolsulphonicformaldehyde and freshly formed iron ferrite was established, based upon wet-and-neutralization method for synthesizing iron ferrite and pearl-polymerization method for synthesizing rigid bead-type composite resin. The composite resin prepared by the above method shows stably high removal efficiency (maximally over 3.1 meq./gresin) to Co(II) species from wastewater in a wide range of solution pH. The wide range of applicable solution pH (i.e. pH 4.09 to 10.32) implies that the composite resin overcomes the limitations of the conventional ferrite process that is practically applicable only to alkaline ... continued below

Physical Description

14 pages

Creation Information

Lee, K. J. & Kim, Y. K. February 26, 2002.

Context

This article is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this article can be viewed below.

Who

People and organizations associated with either the creation of this article or its content.

Publishers

  • WM Symposia, Inc.
    Place of Publication: Tucson, Arizona
  • Hanʼguk Kwahak Kisurwŏn
    Publisher Info: Department of Nuclear Engineering, Korea Advanced Institute of Science and Technology 373-1 Kusong-Dong, Yusong-Gu, Taejon 305-701 (KR)
    Place of Publication: Korea
  • Han'guk Wŏnjaryŏk Anjŏn Kisurwŏn
    Publisher Info: Radiation and Waste Safety Evaluation Department, Korea Institute of Nuclear Safety 19 Kusong-Dong, Yusong-Gu, Taejon 305-338 (KR)
    Place of Publication: Korea

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this article. Follow the links below to find similar items on the Digital Library.

Description

A series of stepwise procedures to prepare a new organic-inorganic composite magnetic resin with phenolsulphonicformaldehyde and freshly formed iron ferrite was established, based upon wet-and-neutralization method for synthesizing iron ferrite and pearl-polymerization method for synthesizing rigid bead-type composite resin. The composite resin prepared by the above method shows stably high removal efficiency (maximally over 3.1 meq./gresin) to Co(II) species from wastewater in a wide range of solution pH. The wide range of applicable solution pH (i.e. pH 4.09 to 10.32) implies that the composite resin overcomes the limitations of the conventional ferrite process that is practically applicable only to alkaline conditions. It has been found that both ion exchange (by the organic resin constituent) and surface adsorption (by the inorganic adsorbent constituent) are major reaction mechanisms for removing Co(II) from wastewater, but surface precipitation results in the high sorption capacity to Co(II) beyond normal ion exchange capacity of the phenolsulphonic-formaldehyde resin. Standard enthalpy change derived from van't Hoff equation is 32.0 kJ{center_dot}mol-1 conforming to the typical range for chemisorption or ion exchange. In a wide range of equilibrium Co(II) concentration, the overall isotherm is qualitatively explained by the generalized adsorption isotherm concept proposed by McKinley. At the experimental conditions where the composite resin shows equivalent selectivity to Co(II) and other competing reagents (i.e. EDTA and Na), the ratios of Co(II) to other chemicals turn out to be 2:1 and 1:221, respectively. In addition, the selectivity of the PSF-F to Co(II) species is very high (about 72% of Co(II)-removal efficiency) even when the molar ratio of Co(II) to Ca(II) is 1:30. It is anticipated that the composite resin can also be used for column-operation with process-control by applying external magnetic field, since the rigid bead-type composite resin shows magnetic-susceptibility due to its paramagnetic inorganic constituent (i.e. iron ferrite).

Physical Description

14 pages

Source

  • Waste Management 2002 Symposium, Tucson, AZ (US), 02/24/2002--02/28/2002

Language

Item Type

Identifier

Unique identifying numbers for this article in the Digital Library or other systems.

  • Report No.: none
  • Office of Scientific & Technical Information Report Number: 828315
  • Archival Resource Key: ark:/67531/metadc781610

Collections

This article is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this article?

When

Dates and time periods associated with this article.

Creation Date

  • February 26, 2002

Added to The UNT Digital Library

  • Dec. 3, 2015, 9:30 a.m.

Description Last Updated

  • March 21, 2018, 11:45 p.m.

Usage Statistics

When was this article last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 2

Interact With This Article

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Lee, K. J. & Kim, Y. K. Sorption Characteristics of Aqueous Co(II) on Preformed Iron Ferrite Impregnated into Phenolsulphonic Formaldehyde Resin, article, February 26, 2002; Tucson, Arizona. (digital.library.unt.edu/ark:/67531/metadc781610/: accessed April 25, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.