Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes

PDF Version Also Available for Download.

Description

Nickel hexacyanoferrate is a polynuclear inorganic ion intercalation material that loads (intercalates) and elutes (deintercalates) alkali cations from its structure when electrochemically reduced and oxidized, respectively. Nickel hexacyanoferrate (NiHCF) is known to preferentially intercalate cesium over all other alkali cations, thus providing a basis for a separation scheme that can tackle DOE's radiocesium contamination problem. This program studied fundamental issues in alkali cation intercalation and deintercalation in nickel hexacyanoferrate compounds, with the goal of (1) quantifying the ion exchange selectivity properties for cation mixtures, (2) enhancing ion exchange capacities, and (3) and understanding the electrochemically-switched ion exchange process (ESIX).

Physical Description

vp.

Creation Information

Schwartz, Daniel T. June 1, 2001.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Sponsor

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

Nickel hexacyanoferrate is a polynuclear inorganic ion intercalation material that loads (intercalates) and elutes (deintercalates) alkali cations from its structure when electrochemically reduced and oxidized, respectively. Nickel hexacyanoferrate (NiHCF) is known to preferentially intercalate cesium over all other alkali cations, thus providing a basis for a separation scheme that can tackle DOE's radiocesium contamination problem. This program studied fundamental issues in alkali cation intercalation and deintercalation in nickel hexacyanoferrate compounds, with the goal of (1) quantifying the ion exchange selectivity properties for cation mixtures, (2) enhancing ion exchange capacities, and (3) and understanding the electrochemically-switched ion exchange process (ESIX).

Physical Description

vp.

Source

  • Other Information: PBD: 1 Jun 2001

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Report No.: EMSP-60123--2001
  • Grant Number: FG07-97ER14819
  • DOI: 10.2172/828574 | External Link
  • Office of Scientific & Technical Information Report Number: 828574
  • Archival Resource Key: ark:/67531/metadc781390

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • June 1, 2001

Added to The UNT Digital Library

  • Dec. 3, 2015, 9:30 a.m.

Description Last Updated

  • April 21, 2016, 7:41 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 3

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Schwartz, Daniel T. Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes, report, June 1, 2001; United States. (digital.library.unt.edu/ark:/67531/metadc781390/: accessed November 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.