Aromatic C-H Activation and Catalytic Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt} (NCMe)Ph

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Article discussing aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)3CEt} (NCMe)Ph.

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11 p.

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Foley, Nicholas A.; Ke, Zhuofeng; Gunnoe, T. Brent; Cundari, Thomas R., 1964- & Petersen, Jeffrey L. June 5, 2008.

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Article discussing aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)3CEt} (NCMe)Ph.

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11 p.

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Reprinted with permission from Organometallics. Copyright 2008 American Chemical Society.

Abstract: The complexes TpRu{P(OCH2)3CEt}(L)R {L = PPh3 or NCMe; R = Cl, OTf (OTf = trifluoromethane-sulfonate), or Ph; Tp = hydridotris(pyrazolyl)borate} and TpRu{P(OCH2)3CEt} (ɳ3-C3H4Me) were synthesized and isolated. TpRu{P(OCH2)3CEt} (NCMe)Ph was found to initiate C-H activation of benzene and to catalyze the hydrophenylation of ethylene to produce ethylbenzene. Ethylene C-H activation to ultimately produce TpRu{P(OCH2)3CEt} (ɳ3-C3H4Me) kinetically competes with the catalytic hydrophenylation of ethylene. Computational studies were undertaken on reactions in the proposed catalytic ethylene hydrophenylation cycle as well as key side reactions.

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  • Organometallics, 2008, Washington DC: American Chemical Society, pp. 3007-3017

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  • Publication Title: Organometallics
  • Volume: 27
  • Page Start: 3007
  • Page End: 3017
  • Pages: 11
  • Peer Reviewed: Yes

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  • June 5, 2008

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  • March 9, 2012, 2:17 p.m.

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  • Oct. 21, 2014, 9:49 a.m.

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Foley, Nicholas A.; Ke, Zhuofeng; Gunnoe, T. Brent; Cundari, Thomas R., 1964- & Petersen, Jeffrey L. Aromatic C-H Activation and Catalytic Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt} (NCMe)Ph, article, June 5, 2008; [Washington, DC]. (digital.library.unt.edu/ark:/67531/metadc77190/: accessed December 16, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.