Evidence for the Net Addition of Arene C-H Bonds across a Ru(II)-Hydroxide Bond

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Article discussing evidence for the net addition of Arene C-H bonds across a Ru(II)-Hydroxide bond.

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2 p.

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Feng, Yuee; Lail, Marty; Barakat, Khaldoon A.; Cundari, Thomas R., 1964-; Gunnoe, T. Brent & Petersen, Jeffrey L. September 27, 2005.

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Article discussing evidence for the net addition of Arene C-H bonds across a Ru(II)-Hydroxide bond.

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2 p.

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Reprinted with permission from the Journal of the American Chemical Society. Copyright 2005 American Chemical Society.

Abstract: TpRu(PMe3)2(OH) (1) reacts with C6D6 to initiate H/D exchange between the hydroxide ligand and the deuterated benzene. In addition, complex 1 catalyzes H/D exchange between H2O and C6D6. Mechanistic and computational studies suggest that a likely reaction pathway for the H/D exchange involves loss of PMe3 to produce {TpRu(PMe3)(OH)}, followed by the net addition of a benzene C-H(D) bond across the Ru-OH bond to form the putative complex TpRu(PMe3)(OH2)(Ph).

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  • Journal of the American Chemical Society, 2005, Washington D.C.: American Chemical Society, pp. 14174-14175

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  • Publication Title: Journal of the American Chemical Society
  • Volume: 127
  • Page Start: 14174
  • Page End: 14175
  • Pages: 2
  • Peer Reviewed: Yes

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  • September 27, 2005

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  • March 2, 2012, 11:47 a.m.

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  • Jan. 9, 2015, 3:27 p.m.

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Feng, Yuee; Lail, Marty; Barakat, Khaldoon A.; Cundari, Thomas R., 1964-; Gunnoe, T. Brent & Petersen, Jeffrey L. Evidence for the Net Addition of Arene C-H Bonds across a Ru(II)-Hydroxide Bond, article, September 27, 2005; [Washington, D.C.]. (digital.library.unt.edu/ark:/67531/metadc77138/: accessed October 22, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.