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Article discussing evidence for the net addition of Arene C-H bonds across a Ru(II)-Hydroxide bond.
Physical Description
2 p.
Notes
Reprinted with permission from the Journal of the American Chemical Society. Copyright 2005 American Chemical Society.
Abstract: TpRu(PMe3)2(OH) (1) reacts with C6D6 to initiate H/D exchange between the hydroxide ligand and the deuterated benzene. In addition, complex 1 catalyzes H/D exchange between H2O and C6D6. Mechanistic and computational studies suggest that a likely reaction pathway for the H/D exchange involves loss of PMe3 to produce {TpRu(PMe3)(OH)}, followed by the net addition of a benzene C-H(D) bond across the Ru-OH bond to form the putative complex TpRu(PMe3)(OH2)(Ph).
Publication Title:
Journal of the American Chemical Society
Volume:
127
Page Start:
14174
Page End:
14175
Pages:
2
Peer Reviewed:
Yes
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Feng, Yuee; Lail, Marty; Barakat, Khaldoon A.; Cundari, Thomas R., 1964-; Gunnoe, T. Brent & Petersen, Jeffrey L.Evidence for the Net Addition of Arene C-H Bonds across a Ru(II)-Hydroxide Bond,
article,
September 27, 2005;
[Washington, D.C.].
(https://digital.library.unt.edu/ark:/67531/metadc77138/:
accessed June 10, 2023),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT College of Arts and Sciences.
