Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands

PDF Version Also Available for Download.

Description

Article discussing the redox activation of alkene ligands in platinum complexes with non-innocent ligands.

Physical Description

8 p.

Creation Information

Boyer, Julie L.; Cundari, Thomas R., 1964-; DeYonker, Nathan J.; Rauchfuss, Thomas B. & Wilson, Scott R. December 19, 2009.

Context

This article is part of the collection entitled: UNT Scholarly Works and was provided by UNT College of Arts and Sciences to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 439 times , with 4 in the last month . More information about this article can be viewed below.

Who

People and organizations associated with either the creation of this article or its content.

Authors

Publisher

Provided By

UNT College of Arts and Sciences

The UNT College of Arts and Sciences educates students in traditional liberal arts, performing arts, sciences, professional, and technical academic programs. In addition to its departments, the college includes academic centers, institutes, programs, and offices providing diverse courses of study.

Contact Us

What

Descriptive information to help identify this article. Follow the links below to find similar items on the Digital Library.

Degree Information

Description

Article discussing the redox activation of alkene ligands in platinum complexes with non-innocent ligands.

Physical Description

8 p.

Notes

Reprinted with permission from Inorganic Chemistry. Copyright 2009 American Chemical Society.

Abstract: The reactivity of metal olefin complexes with non-innocent ligands (NILs) was examined. Treatment of PtCl2(diene) with the deprotonated catechol or aminophenol ligands afforded the corresponding Pt(NIL)(diene) complexes. The Pt(ͭBAfPh)(COD), Pt(tBAfPh)(nbd), and Pt(O2C6H2tBu2)(COD) (H2tBAfPh = 2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol, H2O2C6H2tBu2 = 3,5-di-tert-butylcatechol) complexes were examined by cyclic voltammetry. Treatment of Pt(tBAfPh)(COD) or Pt(tBAfPh)(ndb) with AgPF6 afforded the imino-semiquinones [Pt(tBAfPh)(COD)] PF6 or [Pt(tBAfPh)(nbd)]PF6 respectively. The [Pt(tBAfPh)(COD)] complex was unreactive toward nucleophiles, whereas the oxidized derivative, [Pt(tBAfPh)(COD)]PF6, rapidly and stereospecifically added alkoxides at the carbon trans to the phenolate. The Pt(tBAfPh)(COD), [Pt(tBAfPh)(COD)]PF6, Pt(tBAfPh)(C8H12OMe), and [Cp2Co][Pt-(tBAfPh)(C8H12OMe)] complexes were characterized crystallographically.

Source

  • Inorganic Chemistry, 2009, Washington D.C.: American Chemical Society, pp. 638-645

Language

Item Type

Identifier

Unique identifying numbers for this article in the Digital Library or other systems.

Publication Information

  • Publication Title: Inorganic Chemistry
  • Volume: 48
  • Issue: 2
  • Page Start: 638
  • Page End: 645
  • Peer Reviewed: Yes

Collections

This article is part of the following collection of related materials.

UNT Scholarly Works

Materials from the UNT community's research, creative, and scholarly activities and UNT's Open Access Repository. Access to some items in this collection may be restricted.

What responsibilities do I have when using this article?

When

Dates and time periods associated with this article.

Creation Date

  • December 19, 2009

Added to The UNT Digital Library

  • March 2, 2012, 11:47 a.m.

Description Last Updated

  • Jan. 9, 2015, 5:05 p.m.

Usage Statistics

When was this article last used?

Yesterday: 0
Past 30 days: 4
Total Uses: 439

Interact With This Article

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Boyer, Julie L.; Cundari, Thomas R., 1964-; DeYonker, Nathan J.; Rauchfuss, Thomas B. & Wilson, Scott R. Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands, article, December 19, 2009; [Washington, D.C.]. (digital.library.unt.edu/ark:/67531/metadc77133/: accessed December 12, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.