A T-Shaped Three-Coordinate Nickel(l) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes Metadata

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Title

  • Main Title A T-Shaped Three-Coordinate Nickel(l) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes

Creator

  • Author: Eckert, Nathan A.
    Creator Type: Personal
    Creator Info: University of Rochester
  • Author: Dinescu, Adriana
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Cundari, Thomas R., 1964-
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Holland, Patrick L.
    Creator Type: Personal
    Creator Info: University of Rochester

Publisher

  • Name: American Chemical Society
    Place of Publication: [Washington, D.C.]

Date

  • Creation: 2005-10-05

Language

  • English

Description

  • Content Description: This article discusses a T-shaped three-coordinate nickel(l) carbonyl complex and the geometric preferences of three-coordinate d9 complexes.
  • Physical Description: 3 p.

Subject

  • Keyword: three-coordinate complexes
  • Keyword: transition metals

Source

  • Journal: Inorganic Chemistry, 2005, Washington D.C.: American Chemical Society, pp. 7702-7704

Citation

  • Publication Title: Inorganic Chemistry
  • Volume: 44
  • Issue: 22
  • Page Start: 7702
  • Page End: 7704
  • Pages: 3
  • Peer Reviewed: True

Collection

  • Name: UNT Scholarly Works
    Code: UNTSW

Institution

  • Name: UNT College of Arts and Sciences
    Code: UNTCAS

Rights

  • Rights Access: public

Resource Type

  • Article

Format

  • Text

Identifier

  • DOI: 10.1021/ic0510213
  • Archival Resource Key: ark:/67531/metadc77127

Degree

  • Academic Department: Chemistry
  • Academic Department: Center for Advanced Scientific Computing and Modeling

Note

  • Display Note: Reprinted with permission from Inorganic Chemistry. Copyright 2005 American Chemical Society.
  • Display Note: Abstract: A three-coordinate diketiminate-nickel(l) complex with a carbonyl ligand has been characterized using EPR and IR spectroscopies and X-ray crystallography. The T geometry (bending from the sterically favored C2v structure) contrasts with that of isosteric d9 copper(ll) complexes. DFT calculations on a truncated model reproduce experimental geometries, implying that the geometric differences are electronic in nature. Analysis of the charge distribution in the complexes shows that the geometry of the three-coordinate d9 complexes is affected by differential charge donation of the ligands to the metal center.