A T-Shaped Three-Coordinate Nickel(l) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes Metadata
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- Main Title A T-Shaped Three-Coordinate Nickel(l) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes
Author: Eckert, Nathan A.Creator Type: PersonalCreator Info: University of Rochester
Author: Dinescu, AdrianaCreator Type: PersonalCreator Info: University of North Texas
Author: Cundari, Thomas R., 1964-Creator Type: PersonalCreator Info: University of North Texas
Author: Holland, Patrick L.Creator Type: PersonalCreator Info: University of Rochester
Name: American Chemical SocietyPlace of Publication: [Washington, D.C.]
- Creation: 2005-10-05
- Content Description: This article discusses a T-shaped three-coordinate nickel(l) carbonyl complex and the geometric preferences of three-coordinate d9 complexes.
- Physical Description: 3 p.
- Keyword: three-coordinate complexes
- Keyword: transition metals
- Journal: Inorganic Chemistry, 2005, Washington D.C.: American Chemical Society, pp. 7702-7704
- Publication Title: Inorganic Chemistry
- Volume: 44
- Issue: 22
- Page Start: 7702
- Page End: 7704
- Pages: 3
- Peer Reviewed: True
Name: UNT Scholarly WorksCode: UNTSW
Name: UNT College of Arts and SciencesCode: UNTCAS
- Rights Access: public
- DOI: 10.1021/ic0510213
- Archival Resource Key: ark:/67531/metadc77127
- Academic Department: Chemistry
- Academic Department: Center for Advanced Scientific Computing and Modeling
- Display Note: Reprinted with permission from Inorganic Chemistry. Copyright 2005 American Chemical Society.
- Display Note: Abstract: A three-coordinate diketiminate-nickel(l) complex with a carbonyl ligand has been characterized using EPR and IR spectroscopies and X-ray crystallography. The T geometry (bending from the sterically favored C2v structure) contrasts with that of isosteric d9 copper(ll) complexes. DFT calculations on a truncated model reproduce experimental geometries, implying that the geometric differences are electronic in nature. Analysis of the charge distribution in the complexes shows that the geometry of the three-coordinate d9 complexes is affected by differential charge donation of the ligands to the metal center.