A T-Shaped Three-Coordinate Nickel(l) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes

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This article discusses a T-shaped three-coordinate nickel(l) carbonyl complex and the geometric preferences of three-coordinate d9 complexes.

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3 p.

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Eckert, Nathan A.; Dinescu, Adriana; Cundari, Thomas R., 1964- & Holland, Patrick L. October 5, 2005.

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This article discusses a T-shaped three-coordinate nickel(l) carbonyl complex and the geometric preferences of three-coordinate d9 complexes.

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3 p.

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Reprinted with permission from Inorganic Chemistry. Copyright 2005 American Chemical Society.

Abstract: A three-coordinate diketiminate-nickel(l) complex with a carbonyl ligand has been characterized using EPR and IR spectroscopies and X-ray crystallography. The T geometry (bending from the sterically favored C2v structure) contrasts with that of isosteric d9 copper(ll) complexes. DFT calculations on a truncated model reproduce experimental geometries, implying that the geometric differences are electronic in nature. Analysis of the charge distribution in the complexes shows that the geometry of the three-coordinate d9 complexes is affected by differential charge donation of the ligands to the metal center.

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  • Inorganic Chemistry, 2005, Washington D.C.: American Chemical Society, pp. 7702-7704

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  • Publication Title: Inorganic Chemistry
  • Volume: 44
  • Issue: 22
  • Page Start: 7702
  • Page End: 7704
  • Pages: 3
  • Peer Reviewed: Yes

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  • October 5, 2005

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  • March 2, 2012, 11:47 a.m.

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  • Jan. 9, 2015, 3:32 p.m.

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Eckert, Nathan A.; Dinescu, Adriana; Cundari, Thomas R., 1964- & Holland, Patrick L. A T-Shaped Three-Coordinate Nickel(l) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes, article, October 5, 2005; [Washington, D.C.]. (digital.library.unt.edu/ark:/67531/metadc77127/: accessed July 26, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.