A NOVEL APPROACH TO CATALYTIC DESULFURIZATION OF COAL

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Description

A gas chromatographic method has been developed for the quantitation of sulfur removed from coal as tributyl phosphine sulfide (SPBu{sub 3}). This method also works very well for speciating and quantitating the products of sulfur removal from organosulfur removal from organosulfur compounds such as dibenzothiophene. Remarkably mild conditions have been discovered for quantitative sulfur removal from dibenzothiophene and other organosulfur systems using relatively cheap elemental sodium.

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10 pages

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Verkade, John G. October 1, 2000.

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Description

A gas chromatographic method has been developed for the quantitation of sulfur removed from coal as tributyl phosphine sulfide (SPBu{sub 3}). This method also works very well for speciating and quantitating the products of sulfur removal from organosulfur removal from organosulfur compounds such as dibenzothiophene. Remarkably mild conditions have been discovered for quantitative sulfur removal from dibenzothiophene and other organosulfur systems using relatively cheap elemental sodium.

Physical Description

10 pages

Notes

OSTI as DE00800759

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  • Other Information: PBD: 1 Oct 2000

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  • Report No.: FG22-95PC95208--15
  • Grant Number: FG22-95PC95208
  • DOI: 10.2172/800759 | External Link
  • Office of Scientific & Technical Information Report Number: 800759
  • Archival Resource Key: ark:/67531/metadc741151

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Creation Date

  • October 1, 2000

Added to The UNT Digital Library

  • Oct. 19, 2015, 7:39 p.m.

Description Last Updated

  • March 23, 2016, 10:36 a.m.

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Verkade, John G. A NOVEL APPROACH TO CATALYTIC DESULFURIZATION OF COAL, report, October 1, 2000; Pittsburgh, Pennsylvania. (digital.library.unt.edu/ark:/67531/metadc741151/: accessed August 23, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.